生物吸附作为一种新兴的处理重金属污水方法,以其经济性和有效性的优势已经得到社会广泛关注。对近年来生物吸附剂吸附铜离子的研究进行了综述,总结了不同吸附剂对铜离子的吸附性能,并探讨了生物吸附剂吸附铜离子的机理,最后对生物吸附法处理含铜废水的发展进行了展望。
As an emerging method for treating heavy metal wastewater,biosorption has received extensive attention and attention in the society due to its economic and practical advantages.The research progress on the adsorption copper ions by biosorbents in recent years was reviewed.The adsorption performance of different adsorbents for copper ions were summarized.And the mechanism of adsorption of copper ions by biosorbents was discussed.Finally,the development of biological adsorption treatment of copper-containing wastewater was prospected.
[1] 邢素芳.我国工业水污染综合治理现状[J].旅游纵览(下半月),2014(9):156.
[2] 钱建平,李伟,张力,等.地下水中重金属污染来源及研究方法综析[J].地球与环境,2018,46(6):613-620.
[3] 姜娜.吸附法去除废水中重金属研究进展[J].江西化工,2014(1):81-83.
[4] 徐佳艳,张奎,谌志新.含铜废液处置及回收工艺综述[J].资源节约与环保,2019(1):72-73,75.
[5] Rocha C G,Zaia D A M,da Silva Alfaya R V,et al.Use of rice straw as biosorbent for removal of Cu(Ⅱ),Zn(Ⅱ),Cd(Ⅱ) and Hg(Ⅱ) ions in industrial effluents[J].Journal of Hazardous Materials,2009,166(1):383-388.
[6] 刘晓东,李沅,熊杰,等.改性玉米秸秆对铜离子的吸附性能[J].大连工业大学学报,2018,37(2):100-104.
[7] 吕阳丽,赵莲欢,陈琴,等.改性玉米秸秆对重金属Cu(Ⅱ)离子的吸附性能[J].清洗世界,2017,33(9):13-19.
[8] Pehlivan E,Altun T,Parlayici Ş.Modified barley straw as a potential biosorbent for removal of copper ions from aqueous solution[J].Food Chemistry,2012,135(4):2229-2234.
[9] Chao H P,Chang C C.Adsorption of copper(Ⅱ),cadmium(Ⅱ),nickel(Ⅱ) and lead(Ⅱ) from aqueous solution using biosorbents[J].Adsorption,2012,18(5-6):395-401.
[10] 薛美香,黄晓丹,阮黎珊,等.改性柚皮对水中Cu2+的吸附性能研究[J].化工新型材料,2015,43(12):213-215.
[11] Emenike P G C,Omole D O,Ngene B U,et al.Assessment of KOH-activated unripe Musa paradisiaca peel for adsorption of copper from aqueous solution[J].Cogent Engineering,2017,4(1).
[12] 王慧,刘玉宝,韩杰,等.橘子皮的皂化改性及其吸附铜离子的影响因素[J].山东化工,2016,45(12):22-24.
[13] Dos Santos V C G,De Souza J V T M,Tarley C R T,et al.Copper ions adsorption from aqueous medium using the biosorbent sugarcane bagasse in natura and chemically modified[J].Water,Air,& Soil Pollution,2011,216(1-4):351-359.
[14] 邢丹.茶叶渣对水溶液中铜离子的吸附及动力学研究[J].清洗世界,2017,33(2):10-15.
[15] 唐跃武,江勇,杨英,等.茶渣修饰磁性Fe3O4纳米粒子协同吸附铜铅离子的研究[J].环境污染与防治,2019(1):12.
[16] 余军霞,朱菁,奉丽媛,等.改性梧桐树叶对重金属离子的静态及动态吸附研究[J].“第四届重金属污染防治及风险评价研讨会”暨重金属污染防治专业委员会2014年学术年会论文集,2014.
[17] Ngah W S W,Hanafiah M A K M.Surface modification of rubber (Heveabrasiliensis) leaves for the adsorption of copper ions:kinetic,thermodynamic and binding mechanisms[J].Journal of Chemical Technology & Biotechnology:International Research in Process,Environmental & Clean Technology,2009,84(2):192-201.
[18] Chen H,Dai G,Zhao J,et al.Removal of copper(Ⅱ) ions by a biosorbent-cinnamomumcamphora leaves powder[J].Journal of Hazardous Materials,2010,177(1-3):228-236.
[19] 杨倩.生物吸附法处理水体中重金属离子的研究进展[J].云南化工,2018,45(7):76-78+81.
[20] 董新姣,俞林伟,朱聪.真菌对铜离子生物吸附的研究[J].城市环境与城市生态,2003(2):13-15.
[21] 银玉容.烟曲霉胞外聚合物与水中重金属Cu2+,Cd2+和Pb2+的相互作用及机制[D].广州:华南理工大学,2012.
[22] 马培,张庆甫,吴佳,等.NaOH预处理香菇废弃物对铜,锌吸附性能研究[J].工业安全与环保,2018,07:92-95.
[23] Yin X,Yu C,Zhang X,et al.Comparison of succinylation methods for bacterial cellulose and adsorption capacities of bacterial cellulose derivatives for Cu2+ion[J].Polymer Bulletin,2011,67(3):401-412.
[24] Chang J S,Law R,Chang C C.Biosorption of lead,copper and cadmium by biomass of Pseudomonas aeruginosa PU21[J].Water Research,1997,31(7):1651-1658.
[25] Gunasundari E,Kumar S.Adsorption isotherm,kinetics and thermodynamic analysis of Cu(Ⅱ) ions onto the dried algal biomass (spirulina platensis)[J].Journal of Industrial and Engineering Chemistry,2017,56:129-144.
[26] Kłos A,Rajfur M.Influence of hydrogen cations on kinetics and equilibria of heavy-metal sorption by algae-sorption of copper cations by the alga palmariapalmata (linnaeus) weber & mohr (rhodophyta)[J].Journal of Applied Phycology,2013,25(5):1387-1394.
[27] 袁敏,黄小钟,王崇光,等.铜绿微囊藻对水中铜离子的吸附研究[J].当代化工研究,2017(4):11-12.
[28] 田薪成,刘珊,冯婷,等.SDS改性壳聚糖对Cu(Ⅱ)的吸附研究[J].应用化工,2019(1):3.
[29] Wan M W,Kan C C,Rogel B D,et al.Adsorption of copper(Ⅱ) and lead(Ⅱ) ions from aqueous solution on chitosan-coated sand[J].Carbohydrate Polymers,2010,80(3):891-899.
[30] Zheng L,Jiang F H,Dong P J,et al.Preparation of spherical silica-supported biosorbent for copper ions removal in wastewater based on sol-gel reaction and simple treatment with sodium hydroxide[J].Chemical Research in Chinese Universities,2010,26(3):355-359.
[31] Febrianto J,Kosasih A N,Sunarso J,et al.Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent:a summary of recent studies[J].Journal of Hazardous Materials,2009,162(2-3):616-645.
[32] Cheng Z,Liu X,Han M,et al.Adsorption kinetic character of copper ions onto a modified chitosan transparent thin membrane from aqueous solution[J].Journal of Hazardous Materials,2010,182(1-3):408-415.
[33] Zhao X T,Zeng T,Li X Y,et al.Modeling and mechanism of the adsorption of copper ion onto natural bamboo sawdust[J].Carbohydrate Polymers,2012,89(1):185-192.
[34] 王婧瑶.黑曲霉—稻草秸秆复合吸附剂吸附重金属离子特征及机制研究[D].哈尔滨:哈尔滨工业大学,2017.
[35] Izquierdo M,Gabaldn C,Marzal P.Modeling of the effect of EDTA on copper(Ⅱ) biosorption onto posidoniaoceanica waste in batch and fixed-bed systems[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(2):665-673.
[36] Izquierdo M,Marzal P,Gabaldón C,et al.Study of the interaction mechanism in the biosorption of copper(Ⅱ) Ions onto Posidonia oceanica and Peat[J].Clean-Soil,Air,Water,2012,40(4):428-437.
[37] 龙丹丹.产菌核米曲霉G15对铜、铅离子的抗性机制和吸附特性研究[D].太原:山西大学,2017.
[38] Hui H,Zhang J,Lu K,et al.Characterization of acidosasa edulis shoot shell and its biosorption of copper ions from aqueous solution[J].Journal of Environmental Chemical Engineering,2015,3(1):357-364.
[39] Ngah W S W,Hanafiah M A K M.Biosorption of copper ions from dilute aqueous solutions on base treatedrubber (Heveabrasiliensis) leaves powder:kinetics,isotherm,and biosorption mechanisms[J].Journal of Environmental Sciences,2008,20(10):1168-1176.
[40] Ofomaja A E,Naidoo E B,Modise S J.Biosorption of copper(Ⅱ) and lead(Ⅱ) onto potassium hydroxide treated pine cone powder[J].Journal of Environmental Management,2010,91(8):1674-1685.
[41] Sulaymon A H,Mohammed A A,Al-Musawi T J.Competitive biosorption of lead,cadmium,copper,and arsenic ions using algae[J].Environmental Science and Pollution Research,2013,20(5):3011-3023.
[42] 何环宇.重金属铜吸附优势菌株的筛选及其特性研究[D].成都:西南交通大学,2017.
[43] Liu X,Chen Z Q,Han B,et al.Biosorption of copper ions from aqueous solution using rape straw powders:optimization,equilibrium and kinetic studies[J].Ecotoxicology and Environmental Safety,2018,150:251-259.
[44] Dávila-Guzmán N E,de Jesús Cerino-Córdova F,Soto-Regalado E,et al.Copper biosorption by spent coffee ground:equilibrium,kinetics,and mechanism[J].Clean-Soil,Air,Water,2013,41(6):557-564.
[45] Tu C,Liu Y,Wei J,et al.Characterization and mechanism of copper biosorption by a highly copper-resistant fungal strain isolated from copper-polluted acidic orchard soil[J].Environmental Science and Pollution Research,2018,25(25):24965-24974.
[46] 安娜,梁运祥.阿维菌素发酵废菌丝体对Cu2+吸附机制的研究[J].环境科学与技术,2010,33(10):29-32.
[47] 宋慧平.趋磁细菌对贵金属离子的选择性吸附行为及溶液中金的回收研究[D].天津:天津大学,2007.
[48] Sayer J A,Gadd G M.Solubilization and transformation of insoluble inorganic metal compounds to insoluble metal oxalates by aspergillus niger[J].Mycological Research,1997,101(6):653-661.
[49] 秦玉春,关晓辉,王海涛,等.浮游球衣菌对Cu2+的吸附及生物吸附机理初探[J].环境科学学报,2008(5):892-896.
基金资助
国家自然科学基金资助项目(21666015)
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