一种具有微纳米级粗糙度的超疏水保护性涂层的构建

靳晴1,2, 李金鑫1,2, 田光元1,2, 赵燕1,2, 晏泓1,2*

化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 104 -107.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (5) : 104-107.
新材料与新技术

一种具有微纳米级粗糙度的超疏水保护性涂层的构建

    靳晴1,2, 李金鑫1,2, 田光元1,2, 赵燕1,2, 晏泓1,2*
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Fabrication of a superhydrophobic protective coating with micro-nano roughness

  • Jin Qing1,2, Li Jinxin1,2, Tian Guangyuan1,2, Zhao Yan1,2, Yan Hong1,2
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摘要

采用简单、环保的水热处理方式结合低表面能物质1H,1H,2H,2H-全氟辛基三乙氧基硅烷(PTES)进行硅烷化处理在AZ31B镁合金表面构建具有微纳米级粗糙结构的超疏水保护性涂层。通过扫描电子显微镜(SEM)和傅里叶红外光谱仪(FT-IR)分别对所制备的超疏水涂层表面形貌和组成进行分析。并用接触角(CA)测试对其表面润湿性能进行分析。结果表明:CA值为164±2°。同时,所制备的超疏水涂层具有优异的耐腐蚀性能、耐久性以及附着力。

Abstract

A superhydrophobic protective coating with micro/nano-scale roughness was fabricated on the surface of AZ31B magnesium alloy using a simple and environmentally friendly hydrothermal treatment method combined with silanization treatment of low surface energy material 1H,1H,2H,2H-perfluorooctyltriethoxysilane(PTES).The scanning electron microscopy(SEM) and fourier transform infrared spectroscopy(FT-IR) were introduced to analyze the morphology and chemical structure of the prepared surface.The surface wetting properties were analyzed by water contact angle (CA) test showing a CA value up to 164±2°.At the same time,the prepared coating had excellent corrosion resistance,durability and adhesion.

关键词

超疏水 / 微纳米结构 / 耐腐蚀性 / 耐久性

Key words

super hydrophobicity / micro-nano structure / corrosion resistance / durability

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一种具有微纳米级粗糙度的超疏水保护性涂层的构建[J]. 化工新型材料, 2020, 48(5): 104-107 DOI:

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参考文献

[1] 钱志强,吴志坚,王世栋,等.镁合金超疏水表面的制备技术与应用研究进展[J].材料导报,2018,32(1):102-109.
[2] 康志新,张俊逸,刘秦.镁合金仿生超疏水表面的制备及展望[J].中国有色金属学报,2018,28(1):1-10.
[3] Atrens A,Song G L,Liu M,et al.Dargusch,review of recent developments in the field of magnesium corrosion[J].Advanced Engineering Materials,2015,17(4):400-453.
[4] Wan T T,Liu Z X,Bu M Z,et al.Effect of surface pretreatment on corrosion resistance and bond strength of magnesium AZ31 alloy[J].Corrosion Science,2013,66:33-42.
[5] 霍宏伟,李瑛,王赫男,等.镁合金的腐蚀与防护[J].材料导报,2001,16(7):25-27.
[6] 高志恒.镁合金的腐蚀特性及防护技术[J].表面技术,2016,45(3):169-177.
[7] 周婉秋,单大勇,曾荣昌,等.镁合金的腐蚀行为与表面防护方法[J].材料保护,2002,35(7):1-3.
[8] Gnedenkov S V,Sinebryukhov S L,Egorkin V S,et al.Wetting and electrochemical properties of hydrophobic and superhydrophobic coatings on titanium[J].Colloids Surfaces A,2011,383(1):61-66.
[9] Qiu R,Zhang D,Wang P,et al.Superhydrophobic-carbon fibre growth on a zinc surface for corrosion inhibition[J].Corrosion Science,2013,66:350-359.
[10] Zhang Y,Blawert C,Tang S,et al.Influence of surface pre-treatment on the deposition and corrosion properties of hydrophobic coatings on a magnesium alloy[J].Corrosion Science,2016,112:483-494.
[11] Zang D,Zhu R,Zhang W,et al.Stearic acid modified aluminum surfaces with controlled wetting properties and corrosion resistance[J].Corrosion Science,2014,83:86-93.
[12] Sun W,Wang L,Yang Z,et al.Fabrication of polydimethylsiloxane-derived superhydrophobic surface on aluminium via chemical vapour deposition technique for corrosion protection[J].Corrosion Science,2017,128:176-185.
[13] Wu L K,Zhang X F,Hu J M,Corrosion protection of mild steel by one-step electrodeposition of superhydrophobic silica film[J].Corrosion Science,2014,85:482-487.
[14] Zhang X F,Chen R J,Hu J M,Superhydrophobic surface constructed on electrodeposited silica films by two-step method for corrosion protection of mild steel[J].Corrosion Science,2016,104:336-343.
[15] Jie H,Xu Q,Wei L,et al.Etching and heating treatment combined approach for superhydrophobic surface on brass substrates and the consequent corrosion resistance[J].Corrosion Science,2016,102:251-258.
[16] Liu W,Xu Q,Han J,et al.A novel combination approach for the preparation of superhydrophobic surface on copper and the consequent corrosion resistance[J].Corrosion Science,2016,110:105-113.
[17] Lin J K,Jeng K L,Uan J Y,Crystallization of a chemical conversion layer that forms on AZ91D magnesium alloy in carbonic acid[J].Corrosion Science,2011,53:3832-3839.
[18] 李杰,郭浩正,石文天.镁合金超疏水表面制备技术的研究进展[J].表面技术,2016,45(12):15-22.
[19] 车彦慧,刘艳花,强小虎,等.硬脂酸醇水溶液浸泡法构建超疏水铝合金表面[J].化工新型材料,2013,41(6):30-32.

基金资助

国家青年科学基金(51703152);山西省自然科学基金(201701D121044)

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