保护环境,开发环保型能源,对人类和社会具有重要意义。质子交换膜燃料电池由于其能量转化率高,可实现零排放,近年来引起了电池领域研究者们的兴趣。质子交换膜是燃料电池的重要组成部分,离子型聚合物膜具有质子传导率高、稳定性能好等优点,作为质子交换膜具有良好的应用前景,主要综述了离子型聚合物在燃料电池质子交换膜方面的研究进展,详细介绍了此类质子交换膜的类型、结构和性能,同时对其应用前景做了评论和展望。
Environment protection and environment-friendly energy development are very important for human and society.Proton exchange membrane fuel cell (PEMFC) has attracted much interest from battery researchers due to its high energy conversion rate and zero emissions in recent years.Proton exchange membrane (PEM) as an ionic polymer is an important part of fuel cells.The ionic polymer membranes with high proton conductivity and good stability has good application prospects for proton exchange membranes.Some recent progresses in the application of ionic polymer membranes in PEMs for fuel cell were studied,introduced the types,structures and properties,and discussed the developmental trend.
[1] Yin C,Wang L,Li J,et al.Positron annihilation characteristics,water uptake and proton conductivity of composite Nafion membranes[J].Physical Chemistry Chemical Physics,2017,19:15953-15961.
[2] Yin C S,Li J J,Zhou Y W,et al.Phase separation and development of proton transport pathways in metal oxide nanoparticle/Nafion composite membranes during water uptake[J].The Journal of Physical Chemistry C,2018,122(17):9710-9717.
[3] Ito H,Maeda T,Nakano A,et al.Properties of Nafion membranes under PEM water electrolysis conditions[J].International Journal of Hydrogen Energy,2011,36(17):10527-10540.
[4] Elabd Y A,Napadensky E.Sulfonation and characterization of poly(styrene-isobutylene-styrene) triblock copolymers at high ion-exchange capacities[J].Polymer,2004,45(9):3037-3043.
[5] Li Z H,Xi J Y,Zhou P,et al.Preparation and characterization of sulfonated poly(ether ether ketone)/poly(vinylidene fluoride) blend membrane for vanadium redox flow battery application[J].Journal of Power Sources,2013,237:132-140.
[6] 朱星烨,钱汇东,蒋晶晶,等.咪唑接枝交联型磺化聚醚醚酮质子交换膜的制备及在直接甲醇燃料电池中的应用[J].高等学校化学学报,2018,39(9):2046-2053.
[7] Kazeroonian F K,Iranagh S A,Modarress H.Molecular dynamics simulation study of carboxylated and sulfonated poly(arylene ether sulfone) membranes for fuel cell applications[J].International Journal of Hydrogen Energy,2015,40(46):15690-15703.
[8] 刘闪闪,侯敬贺,肖振雨,等.SPTES-b-PI质子交换膜的制备及表征[J].化工进展,2018,37(9):3502-3507.
[9] Pan H Y,Chen S X,Zhang Y Y,et al.Preparation and properties of the cross-linked sulfonated polyimide containing benzimidazole as electrolyte membranes in fuel cells[J].Journal of Membrane Science,2015,476:87-94.
[10] Houchins C,Kleen G J,Spendelow J S,et al.US DOE progress towards developing low-cost,high performance,durable polymer electrolyte membranes for fuel cell applications[J].Membranes,2012,2(4):855-878.
[11] Venkatesan S V,Lim C,Rogers E,et al.Evolution of water sorption in catalyst coated membranes subjected to combined chemical and mechanical degradation[J].Physical Chemistry Chemical Physics,2015,17,13872-13881.
[12] Chang Y,Mohanty A D,Smedley S B,et al.Effect of superacidic side chain structures on high conductivity aromatic polymer fuel cell membranes[J].Macromolecules,2015,48,7117-7126.
[13] Narimani R,Holdcroft S,Frisken B J,et al.Controlling water content and proton conductivity through copolymer morphology[J].Macromolecules,2013,46(24):9676-9687.
[14] Tsang E M W,Shi Z Q,Holdcroft S,et al.Ionic purity and connectivity of proton-conducting channels in fluorous-ionic diblock copolymers[J].Macromolecules,2011,44(22):8845-8857.
[15] Zhang X,Sheng L,Ueda M,et al.Polymer electrolyte membranes based on poly(m-phenylene)s with sulfonic acid via long alkyl side chains[J].Polymer Chemistry,2013,4(4):1235-1242.
[16] Sheng L,Higashihara T,Ueda M,et al.Block copolystyrene derivatives having flexible alkylsulfonated side chains and hydrophobic alkoxy chains as a proton exchange membrane for fuel cell application[J].Journal of Polymer Science,Part A:Polymer Chemistry,2013,51:2216-2224.
[17] Sheng L,Higashihara T,Ueda M,et al.Polystyrenes containing flexible alkylsulfonated side chains as a proton exchange membrane for fuel cell application[J].Polymer Chemistry,2012,3(12):3289-3295.
[18] Jana K K,Prakash O,Shahi V K,et al.Poly(vinyliden fluoride-co-chlorotrifluoro ethylene) nanohybrid membrane for fuel cell[J].ACS Omega,2018,3:917-928.
[19] Kang K H,Kim D J.Comparison of proton conducting polymer electrolyte membranes prepared from multi-block and random copolymers based on poly(arylene ether ketone)[J].Journal of Power Sources,2015,281:146-157.
[20] Smith D W,Oladoyinbo F O,Hayes W,et al.A microblock ionomer in proton exchange membrane electrolysis for the production of high purity hydrogen[J].Macromolecules,2013,46(4):1504-1511.
[21] Kang K,Kim D.Comparison of proton conducting polymer electrolyte membranes prepared from multi-block and random copolymers based on poly(arylene ether ketone)[J].Journal of Power Sources,2015,281:146-157.
[22] Zhang L Y,Zhang G,Na H,et al.Cross-linked tri-side chains poly(arylene ether ketone)s containing pendant alkylsulfonic acid groups for proton exchange membranes[J].Journal of Power Sources,2012,201:142-150.
[23] Lee K H,Chu J Y,Kim A R,et al.Enhanced performance of a sulfonated poly(arylene ether ketone) block copolymer bearing pendant sulfonic acid groups for polymer electrolyte membrane fuel cells operating at 80% relative humidity[J].ACS Applied Materials & Interfaces,2018,10(24):20835-20844.
[24] Shin D W,Lee S Y,Lee Y M,et al.Sulfonated poly(arylene sulfide sulfone nitrile) multiblock copolymers with ordered morphology for proton exchange membranes[J].Macromolecules,2013,46(19):7797-7804.
[25] Weiber E A,Takamuku S,Jannasch P,et al.Highly proton conducting electrolyte membranes based on poly(arylene sulfone)s with tetrasulfonated segments[J].Macromolecules,2013,46(9):3476-3485.
[26] Wang C Y,Lee Y M,Guiver M D,et al.Fluorene-based poly(arylene ether sulfone)s containing clustered flexible pendant sulfonic acids as proton exchange membranes[J].Macromolecules,2011,44(18):7296-7306.
[27] Kim K,Heo P,Hwang W,et al.Cross-linked sulfonated poly(arylene ether sulfone) containing a flexible and hydrophobic bishydroxy perfluoropolyether cross-linker for high-performance proton exchange membrane[J].ACS Applied Materials & Interfaces,2018,10(26):21788-21793.
[28] Lee S W,Chen J C,Wu J A,et al.Synthesis and properties of poly(ether sulfone)s with clustered sulfonic groups for PEMFC applications under various relative humidity[J].ACS Applied Materials & Interfaces,2017,9(11):9805-9814.
[29] Fu F Y,Xu H L,Zhu C J,et al.Design of polyphosphazene-based graft copolystyrenes with alkylsulfonate branch chains for proton exchange membranes[J].Journal of Membrane Science,2015,489:119-128.
[30] Luo T W,Xu H L,Zhu C J,et al.Highly conductive proton exchange membranes from sulfonated polyphosphazene-graft-copolystyrenes doped with sulfonated single-walled carbon nanotubes[J].Journal of Membrane Science,2016,514:527-536.
基金资助
河北省科技计划项目(16214906);河北省高等学校科学研究项目(BJ2019206);衡水学院高层次人才科研启动基金项目(2018G10)