无机纳米材料由于其独特的结构,因而具有优异的物理化学性质,采用无机纳米材料增强聚合物材料,对聚合物基复合材料的力学性能、热性能和电性能等会有明显的提高,但单一无机纳米材料对聚合物性能的提升具有一定的局限性,且可能会同时引起其他性能下降。因此,使用两种或两种以上无机纳米材料对聚合物进行改性研究,从而达到协同增强的目的,是目前研究的热点。对近年来无机纳米材料协同增强聚合物基复合材料的研究进行概述,并对无机纳米材料协同作用方式进行归类总结。同时,对无机纳米材料协同增强热塑性和热固性树脂的研究进行了分析,并展望了无机纳米材料协同增强聚合物基复合材料的发展前景。
Inorganic nanomaterials have excellent physicochemical properties because of their unique structures.The mechanical,thermal and electrical properties of polymers matrix composites can be significantly improved by reinforcing with inorganic nanomaterials.However,the inorganic nanomaterials with one component have some limitations on the improvement of polymer properties.Furthermore,it may also cause degradation of other performance.Therefore,it is the current research hotspot to use inorganic nanomaterials with two or more components to modify the polymers for achieving the purpose of synergistic enhancement.The recent researches on polymer matrix composites synergistically enhanced by inorganic nanomaterials were reviewed,and the synergistic action modes of inorganic nanomaterials were classified.Meanwhile,the researches on thermoplastic and thermosetting resins synergistically enhanced by inorganic nanoparticles were analyzed.Finally,the development prospects of polymer matrix composites synergistically enhanced by inorganic nanomaterials were prospected.
[1] Kango S,Kalia S,Celli A,et al.Surface modification of inorganic nanoparticles for development of organic-inorganic nanocomposites-a review[J].Progress in Polymer Science,2013,38(8):1232-1261.
[2] Christopher G,Anbu Kulandainathan M,Harichandran G.Comparative study of effect of corrosion on mild steel with waterborne polyurethane dispersion containing graphene oxide versus carbon black nanocomposites[J].Progress in Organic Coatings,2015,89:199-211.
[3] Douba A,Genedy M,Matteo E N,et al.The significance of nanoparticles on bond strength of polymer concrete to steel[J].International Journal of Adhesion and Adhesives,2017,74(2017):77-85.
[4] Ilango K,Prabunathan P,Satheeshkumar E,et al.Design of low dielectric constant polybenzoxazine nanocomposite using mesoporous mullite[J].High Performance Polymers,2016,29(2):141-150.
[5] 李阳,任鹏刚,许勐璠.隔离结构石墨烯-多壁碳纳米管/超高分子量聚乙烯导电复合材料阻温特性[J].化工新型材料,2015,43(3):58-60.
[6] Li S S,Shi X L,Fang C Q,et al.Effect of graphite and Ag-plated graphite nanoplatelets on the thermal properties of polypropylene nanocomposites:experimental studies and modeling[J].Thermochimica Acta,2016,630:11-20.
[7] Liu J J,Yuen R K K,Hong N N,et al.The influence of mesoporous SiO2-graphene hybrid improved the flame retardancy of epoxy resins[J].Polymers for Advanced Technologies,2018,29(5):1478-1486.
[8] Nam W H,Lim Y S,Kim W,et al.A gigantically increased ratio of electrical to thermal conductivity and synergistically enhanced thermoelectric properties in interface-controlled TiO2-RGO nanocomposites[J].Nanoscale,2017,9(23):7830-7838.
[9] 李为民,彭超义,吴彬瑞.碳纤维颗粒增强CeO2/PMMA/PVDF超疏水复合涂层及其耐磨性能[J].材料导报,2017,31(29):334-337.
[10] Pan G,Yao Y,Zeng X,et al.Learning from natural nacre:constructing layered polymer composites with high thermal conductivity[J].ACS Appl Mater Interfaces,2017,9(38):33001-33010.
[11] Ren L L,Li Q,Lu J B,et al.Enhanced thermal conductivity for Ag-deposited alumina sphere/epoxy resin composites through manipulating interfacial thermal resistance[J].Composites Part A:Applied Science and Manufacturing,2018,107(2018):561-569.
[12] Sachau S M,Zaheer M,Lale A,et al.Micro-/mesoporous platinum-SiCN nanocomposite catalysts (Pt@SiCN):from design to catalytic applications[J].Chemistry,2016,22(43):15508-15512.
[13] Wang J,Qiao J,Wang J,et al.Bioinspired hierarchical alumina-graphene oxide-poly(vinyl alcohol) artificial nacre with optimized strength and toughness[J].ACS Appl Mater Interfaces,2015,7(17):9281-9286.
[14] Zuo L Z,Fan W,Zhang Y F,et al.Graphene/montmorillonite hybrid synergistically reinforced polyimide composite aerogels with enhanced flame-retardant performance[J].Composites Science and Technology,2017,139(2017):57-63.
[15] 张亚婷,李景凯,周安宁,等.Fe2O3/煤基石墨烯纳米复合材料制备及其电化学性能研究[J].化工新型材料,2015,43(6):104-107.
[16] Yu W,Qi Y,Zhou Y,et al.Synergistic improvement of thermal transport properties for thermoplastic composites containing mixed alumina and graphene fillers[J].Journal of Applied Polymer Science,2016,133(13):43242-43247.
[17] Yu W,Xie H Q,Chen L F,et al.Synergistic thermal conductivity enhancement of PC/ABS composites containing alumina/magnesia/graphene nanoplatelets[J].Polymer Composites,2017,38(10):2221-2227.
[18] Kim Y K,Chung J Y,Lee J G,et al.Synergistic effect of spherical Al2O3 particles and BN nanoplates on the thermal transport properties of polymer composites[J].Composites Part A:Applied Science and Manufacturing,2017,98(2017):184-191.
[19] Zhang X L,Xu Y,Zhang X,et al.Progress on the layer-by-layer assembly of multilayered polymer composites:strategy,structural control and applications[J].Progress in Polymer Science,2018,DOI:10.1016/j.compscitech.2017.07.023.
[20] Zhang X M,Zhang J J,Xia L C,et al.Achieving high-efficiency and robust 3D thermally conductive while electrically insulating hybrid filler network with high orientation and ordered distribution[J].Chemical Engineering Journal,2018,334(2018):247-256.
[21] Azimi R,Hossein R M,Meysam G M.Grafting poly (amidoamine) dendrimer-modified silica nanoparticles to graphene oxide for preparation of a composite and curing agent for epoxy resin[J].Polymer,2017,126(2017):152-161.
[22] Xu Z L,Zhang B K,Kim J.Electrospun carbon nanofiber anodes containing monodispersed Si nanoparticles and graphene oxide with exceptional high rate capacities[J].Nano Energy,2014,6(3):27-35.
[23] Akhtar M W,Lee Y S,Yoo D J,et al.Alumina-graphene hybrid filled epoxy composite:quantitative validation and enhanced thermal conductivity[J].Composites Part B:Engineering,2017,131(2017):184-195.
[24] Nadeem Q A,Rizwan M,Gill R,et al.Fabrication of alumina based electrically conductive polymer composites[J].Journal of Applied Polymer Science,2016,133(5):1583-1586.
[25] Liu Z J,Zhang H M,Song S Q,et al.Improving thermal conductivity of styrene-butadiene rubber composites by incorporating mesoporous silica@solvothermal reduced graphene oxide hybrid nanosheets with low graphene content[J].Journal Citation Reports,2017,150(2017):174-180.
[26] Zhang H X,Ko E B,Park J H,et al.Preparation and properties of polyethylene/dodecanethiol-MoS2 nanocomposites with dodecanethiol-MoS2/MgCl2-supported Ziegler-Natta catalyst via an in situ polymerization method[J].Polymer,2017,108(2017):223-229.
[27] Zhang H X,Park J H,Moon Y K,et al.Preparation of polyethylene/graphene nanocomposites with octadecylamine-modified graphene oxide-MgCl-supported Ziegler-Natta catalyst[J].Journal of Polymer Science Part A:Polymer Chemistry,2017,55(5):855-860.
[28] Huang G B,Chen S Q,Song P G,et al.Combination effects of graphene and layered double hydroxides on intumescent flame-retardant poly(methyl methacrylate) nanocomposites[J].Applied Clay Science,2014,88-89:78-85.
[29] Xia Y,Zhu Y C,Zhou Y F,et al.Improved dispersion of attapulgite in polypropylene by grap oxide and the enhanced mechanical properties[J].Polymer Composites,2018,39(2):560-568.
[30] Wang C C,Zhao Y Y,Ge H Y,et al.Enhanced mechanical and thermal properties of short carbon fiber reinforced polypropylene composites by graphene oxide[J].Polymer Composites,2018,39(2):405-413.
[31] Li Z,González A J,Heeralal V B,et al.Covalent assembly of MCM-41 nanospheres on graphene oxide for improving fire retardancy and mechanical property of epoxy resin[J].Composites Part B:Engineering,2018,138:101-112.
[32] Haeri S Z,Asghari M,Ramezanzadeh B.Enhancement of the mechanical properties of an epoxy composite through inclusion of graphene oxide nanosheets functionalized with silica nanoparticles through one and two steps sol-gel routes[J].Progress in Organic Coatings,2017,111:1-12.
[33] Deng X,Huang J,Liu C H,et al.Coupling hybrid of graphene oxide and layered zirconium phosphonate to enhance phenolic resin-based friction materials[J].Journal of Applied Polymer Science,2018,135(32):1478-1486.
基金资助
国家自然科学基金(51563004);广西自然科学基金(2014GXNSFAA0118313)
PDF
(1169KB)
