云母/TiO2紫外屏蔽材料的制备、表面改性及其在防晒配方中的应用

陈晓宇1, 吴凤芹1,2, 左士祥1, 姚超1*, 李霞章1, 刘文杰1

化工新型材料 ›› 2020, Vol. 48 ›› Issue (4) : 250 -255.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (4) : 250-255.
开发与应用

云母/TiO2紫外屏蔽材料的制备、表面改性及其在防晒配方中的应用

    陈晓宇1, 吴凤芹1,2, 左士祥1, 姚超1*, 李霞章1, 刘文杰1
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Preparation,surface modification of mica/TiO2 UV shielding material and its application in sunscreen formulation

  • Chen Xiaoyu1, Wu Fengqin1,2, Zuo Shixiang1, Yao Chao1, Li Xiazhang1, Liu Wenjie1
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摘要

为提高纳米TiO2的紫外屏蔽能力,降低其光催化活性,将TiO2负载在云母表面,采用无机Al(OH)3和有机硬脂酰谷氨酸二钠(HS-21P)对其进行改性,制备云母/TiO2/Al(OH)3/HS-21P(MTAH)紫外屏蔽材料。透射电镜和扫描电镜分析结果表明,纳米TiO2均匀分布在云母表面。光催化性能测试表明,无机Al(OH)3的包覆有效地降低了纳米TiO2的光催化活性。红外光谱、热重和水接触角分析表明,有机HS-21P表面处理剂使复合粉体的水接触角达到121°,提高了其与有机溶剂的相容性。将MTAH复合粉体与市售TiO2以相同活性物添加量添加到防晒配方中,考察配方防晒性能、稳定性等。结果表明,MTAH具有更优异的稳定性及紫外屏蔽效果(配方中含TiO2为5%时,SPF值13.81,PA++)。

Abstract

In order to improve the ultraviolet shielding ability of nano TiO2,reduce its photocatalytic activity,rutile TiO2 was supported in-situ on the surface of mica and modified with inorganic Al(OH)3 and disodium stearyl glutamate (HS-21P).Mica/TiO2/Al(OH)3/HS-21P (MTAH) UV shielding material was prepared.TEM and SEM analysis showed that the nano-TiO2 was uniformly supported on the surface of the mica.Photocatalytic performance tests shown that the coating of inorganic Al(OH)3 effectively reduced the photocatalytic activity of nano-TiO2.The FT-IR,TG and water contact angle analysis showed that the organic HS-21P surface treatment agent made the water contact angle of the composite powder reached 121°,improving its compatibility with organic solvents.The MTAH composite powder and the commercially available TiO2 were added to the sunscreen formulation with the same amount of the active substance added,and the formula sunscreen performance,stability and the like were examined.The results showed that MTAH had better stability,UV shielding effect (SPF value of 13.81,PA++ when the formulation contained 5% TiO2).

关键词

TiO2 / 云母 / 硬脂酰谷氨酸二钠 / 防晒霜 / 稳定性

Key words

TiO2 / mica / disodium stearoyl glutamate / sunscreen / stability

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云母/TiO2紫外屏蔽材料的制备、表面改性及其在防晒配方中的应用[J]. 化工新型材料, 2020, 48(4): 250-255 DOI:

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基金资助

国家自然科学基金-青年基金(51702026);江苏省六大人才高峰”第十三批创新人才团队项目(XCL-CXTD-029);产业前瞻与共性关键技术——竞争项目(BE2017064)

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