近些年,随着石墨烯及其衍生物的问世,利用氧化石墨烯(GO)改性增强水泥基材料已经成为了现代胶凝材料领域一个新的研究方向。针对现有的研究成果,综述了近年来GO在水泥基材料中的研究现状,主要包括GO制备与分散、GO改性水泥基材料性能及作用机理等。此外,还针对目前研究存在的问题进行了总结归纳,并对未来的研究方向进行了展望。
In recent years,the use of graphene oxide (GO) modified and reinforced cement-based materials has become a new research direction in the field of modern cement-based materials with the emergence of graphene and its derivatives.In view of the existing research results,the research status of GO in cement-based materials in recent years was summarized,including preparation and dispersion of GO,properties and mechanism of GO modified cement-based materials.In addition,the problems existing in the current research and the future research directions were summarized and prospected.
[1] 胡曙光.先进水泥基复合材料[M].北京:科学出版社,2009,1-384.
[2] 刘雪,郭远臣,王雪,等.混凝土裂缝成因研究进展[J].硅酸盐通报,2018,37(7):16.
[3] Juarez C A,Fajardo G,Monroy S,et al.Comparative study between natural and PVA fibers to reduce plastic shrinkage cracking in cement-based composite[J].Construction and Building Materials,2015,91:164-170.
[4] 王倩楠,顾春平,孙伟.水泥-粉煤灰-硅灰基超高性能混凝土水化过程微观结构的演变规律[J].材料导报,2018,31(23):85-89.
[5] Ghazizadeh S,Duffour P,Skipper N T,et al.Understanding the behaviour of graphene oxide in Portland cement paste[J].Cement and Concrete Research,2018,111:169-182.
[6] Chuah S,Pan Z,Sanjayan J G,et al.Nano reinforced cement and concrete composites and new perspective from graphene oxide[J].Construction & Building Materials,2014,73:113-124.
[7] Lin C,Wei W,Hu Y H.Catalytic behavior of graphene oxide for cement hydration process[J].Journal of Physics & Chemistry of Solids,2016,89(3):128-133.
[8] Ghazizadeh S,Duffour P,Skipper N T,et al.An investigation into the colloidal stability of graphene oxide nano-layers in alite paste[J].Cement and Concrete Research,2017,99:116-128.
[9] Wang H,Hu Y H.Electrolyte-induced precipitation of graphene oxide in its aqueous solution[J].Journal of Colloid and Interface Science,2013,391:21-27.
[10] Fan X,Peng W,Li Y,et al.Deoxygenation of exfoliated graphite oxide under alkaline conditions:a green route to graphene preparation[J].Advanced Materials,2008,20(23):4490-4493.
[11] Li X,Korayem A H,Li C,et al.Incorporation of graphene oxide and silica fume into cement paste:a study of dispersion and compressive strength[J].Natural Gas Geoscience,2016,123:327-335.
[12] Lu Z,Hanif A,Ning C,et al.Steric stabilization of graphene oxide in alkaline cementitious solutions:mechanical enhancement of cement composite[J].Materials & Design,2017,127:154-161.
[13] Chuah S,Li W,Chen S J,et al.Investigation on dispersion of graphene oxide in cement composite using different surfactant treatments[J].Construction & Building Materials,2018,161:519-527.
[14] 吕生华,李莹,赵浩然,等.氧化石墨烯在水泥基体中的分散性及对其结构和性能的影响[J].精细化工,2016,33(5):589-595.
[15] Li X,Liu Y M,Li W G,et al.Effects of graphene oxide agglomerates on workability,hydration,microstructure and compressive strength of cement paste[J].Construction and Building Materials,2017,145:402-410.
[16] Shang Y,Zhang D,Yang C,et al.Effect of graphene oxide on the rheological properties of cement pastes[J].Construction & Building Materials,2015,96:20-28.
[17] Wang Q,Cui X,Wang J,et al.Effect of fly ash on rheological properties of graphene oxide cement paste[J].Construction & Building Materials,2017,138:35-44.
[18] 高党国,马宇娟.氧化石墨烯与聚羧酸减水剂单体共聚物的制备与性能[J].精细化工,2015,32(1):130-107.
[19] 王琴,李时雨,潘硕,等.硅烷改性氧化石墨烯-聚羧酸复合物的合成及性能[J].新型炭材料,2018,33(2):131-139.
[20] Lv S,Ma Y,Qiu C,et al.Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites[J].Construction & Building Materials,2013,49(12):121-127.
[21] Wang Q,Wang J,Lu C X,et al.Influence of graphene oxide additions on the microstructure and mechanical strength of cement[J].New Carbon Materials,2015,30(4):349-356.
[22] Lu Z,Hou D,Meng L,et al.Mechanism of cement paste reinforced by graphene oxide/carbon nanotubes composites with enhanced mechanical properties[J].RSC Advances,2015,5(122):100598-100605.
[23] Abrishami M E,Zahabi V.Reinforcing graphene oxide/cement composite with NH2,functionalizing group[J].Bulletin of Materials Science,2016,39(4):1073-1078.
[24] 袁小亚,曾俊杰,高军,等.氧化石墨烯与石墨烯复掺对水泥砂浆性能影响研究[J].重庆交通大学学报(自然科学版),2019,38(9):45-50.
[25] 李显铭.氧化石墨烯-碳纤维水泥复合材料的制备及性能研究[J].功能材料,2018,49(6):158-162.
[26] Hassani A,Fakhim B,Rashidi A,et al.The influence of graphene oxide on mechanical properties and durability increase of concrete pavement[J].International Journal of Transportation Engineering,2014,2(2):119-130.
[27] Mohammed A,Sanjayan J G,Duan W H,et al.Incorporating graphene oxide in cement composites:a study of transport properties[J].Construction and Building Materials,2015,84:341-347.
[28] 李相国,任钊锋,徐朋辉,等.氧化石墨烯复合PVA纤维增强水泥基材料的力学性能及耐久性研究[J].硅酸盐通报,2018,37(1):245-250.
[29] 杨雅玲,袁小亚,沈旭,等.氧化石墨烯改性水泥砂浆耐腐蚀性能的研究[J].功能材料,2017,48(5):5144-5148.
[30] 雷斌,邹俊,饶春华,等.氧化石墨烯对再生混凝土改性试验研究[J].建筑结构学报,2016,37(s2):103-108.
[31] Wang L,Zhang S,Zheng D,et al.Effect of graphene oxide (GO) on the morphology and microstructure of cement hydration products[J].Nanomaterials,2017,7(12):429.
[32] Hou D,Lu Z,Li X,et al.Reactive molecular dynamics and experimental study of graphene-cement composites:structure,dynamics and reinforcement mechanisms[J].Carbon,2017,115:188-208.
[33] Mokhtar M M,Abo-El-Enein S A,Hassaan M Y,et al.Mechanical performance,pore structure and micro-structural characteristics of graphene oxide nano platelets reinforced cement[J].Construction and Building Materials,2017,138:333-339.
[34] Wang M,Wang R,Yao H,et al.Study on the three dimensional mechanism of graphene oxide nanosheets modified cement[J].Construction and Building Materials,2016,126:730-739.
基金资助
2017年河南省新型墙体材料专项基金(豫财建[2017]189号);河南省高等学校重点科研项目计划资助项目(15A560015)