卟啉和酞菁化合物在LiSOCl2电池中的应用研究进展

卢新生, 朱开礼, 祁小妮, 党金宁, 孙万军

化工新型材料 ›› 2019, Vol. 47 ›› Issue (11) : 67 -71.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (11) : 67-71.
综述与专论

卟啉和酞菁化合物在LiSOCl2电池中的应用研究进展

    卢新生, 朱开礼, 祁小妮, 党金宁, 孙万军
作者信息 +

Recent progress on porphyrin and phthalocyanine applied in LiSOCl2 battery

  • Lu Xinsheng, Zhu Kaili, Qi Xiaoni, Dang Jinning, Sun Wanjun
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文章历史 +
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摘要

锂/亚硫酰氯电池(Li/SOCl2)电池是目前实际应用的电池中比能量最高的一次电池,但其安全性和电压滞后性问题亟待解决。研究表明,通过加入酞菁或卟啉化合物的电解液能显著增强Li/SOCl2电池的放电电压和电池容量。基于此,综述了近年来酞菁配合物和卟啉配合物作为Li/SOCl2电池正极添加剂的研究进展,介绍了这些添加剂改善Li/SOCl2电池的效果和催化机理,并对其发展方向进行了展望。

Abstract

Li/SOCl2 battery,as a high energy density among the realized chemical power sources and high working voltage,has been extensively used for military and commercial applications.However,the Li/SOCl2 batteries suffer from two obvious problems in practical application-voltage delay and safety problem.Among these works,one promising method to obviously improve the performance of the battery is adding porphyrin compounds to the electrolyte.The research progress of phthalocyanine complexes and porphyrin complexes in the Li/SOCl2 battery were summarized.The catalytic mechanisms and effects of the reduction of SOCl2 by these additives were introduced.Future reseach goals were also presented.

关键词

Li/SOCl2电池 / 催化活性 / 酞菁配合物 / 卟啉配合物

Key words

Li/SOCl2 battery / catalytic activity / phthalocyanine / metalporphyrin

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卟啉和酞菁化合物在LiSOCl2电池中的应用研究进展[J]. 化工新型材料, 2019, 47(11): 67-71 DOI:

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基金资助

甘肃省高等学校科学研究项目(2018A-123);甘肃民族师范学院第八届教学科研双骨干项目(GSNU-SHGG-1805);甘肃民族师范学院教学成果培育项目(GNUNJXCGPY1808);甘肃民族师范学院校长科研基金项目(15-04,GSNUXM16-41)

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