掺杂改性NaTaO3光催化剂的研究进展

梁青青, 李泽雄, 刘崎峰*

化工新型材料 ›› 2019, Vol. 47 ›› Issue (11) : 36 -39.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (11) : 36-39.
综述与专论

掺杂改性NaTaO3光催化剂的研究进展

    梁青青, 李泽雄, 刘崎峰*
作者信息 +

Research progress of doping modified NaTaO3 photocatalyst

  • Liang Qingqing, Li Zexiong, Liu Qifeng
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文章历史 +
PDF (1178K)

摘要

钽酸钠(NaTaO3)光催化剂因其特殊的晶体结构和能带结构而具有高的光催化活性,成为新兴光催化领域中研究的热点。实践证明钽酸盐是一类高效的响应紫外光(UV)的光催化剂,但其结构特点限制了对可见光的响应,通过负载、掺杂、复合技术可有效增强钽酸钠光催化剂的活性。主要从NaTaO3的金属离子掺杂、非金属离子掺杂、金属-金属共掺杂、金属-非金属共掺杂、非金属-非金属共掺杂等方面总结了近年来国内外的最新研究进展,并对NaTaO3光催化剂的研究进行了展望。

Abstract

The tantalite photocatalyst(NaTaO3) has high photocatalytic activity due to its special crystal structure and energy band structure,and has become a hot spot in the field of emerging photocatalysis.It has been proved that tantalite is a kind of efficient UV corresponding photocatalyst,but its structural characteristics limit the response to visible light,and the activity of citrate photocatalyst can be effectively enhanced through loading,doping and compounding techniques.The latest research progress in recent years was summarized both from domestic and foreign sources of NaTaO3 metal ion doping,non-metal ion doping,metal-metal co-doping,metal-nonmetal co-doping,and non-metal-nonmetal co-doping,and made a perspective for the future work.

关键词

钽酸钠 / 掺杂 / 光催化 / 研究进展

Key words

NaTaO3 / doping / photocatalyst / research progress

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掺杂改性NaTaO3光催化剂的研究进展[J]. 化工新型材料, 2019, 47(11): 36-39 DOI:

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参考文献

[1] 刘永泽.高级氧化过程中OH·和SO4·-定量分析及溴代副产物生成规律研究[D].哈尔滨:哈尔滨工业大学,2015.
[2] Kato H,Aaskura K,Kudo A.Highly efficient water splitting into H2 and O2 over lanthanum-doped NaTaO3 photocatalysts with high crystallinity and surface nanostructure[J].J Am Chem Soc,2003,125(10):3082-3089.
[3] 李霞,刘艳.NaTaO3光催化剂的水热合成与催化性能研究[J].功能材料,2009,40(3):407-409,412.
[4] Hosogi Y,Shimodaira Y,Kato H,et al.Role of Sn2+ in the band structure of SnM2O6 and Sn2M2O7(M=Nb and Ta) and their photocatalytic properties[J].Chemistry of Materials,2008,20(4):1299-1307.
[5] Kato H,Kudo A.Energy structure and photocatalytic activity for water splitting of Sr2(Ta1-xNbx)2O7 solid solution[J].Journal of Photochemistry and Photobiology A(Chemistry),2001(145):129-132.
[6] Kato H,Kudo A.Water splitting into H2 and O2 on alkali tantalate photocatalysts ATaO3(A=Li,Na,and K)[J].Journal of Physical Chemistry B,2001,105(19):4285-4292.
[7] Kato H,Kudo A.Highly efficient decomposition of pure water into H2 and O2 over NaTaO3 photocatalysts[J].Catalysis Letters,1999,58(2/3):153-155.
[8] 王蒙.钽酸盐纳米材料的制备及光催化性能研究[D].北京:中国地质大学(北京),2017.
[9] Jana P,O'Shea V A D,Montero C M,et al.Mixed NaNbxTa1-xO3 perovskites as photocatalysts for H2 production[J].Green Chem,2015,17:1735-1743.
[10] Cui H N,Shi J Y,Liu H.Influence of Bi chemical state on the photocatalytic performance of Bi-doped NaTaO3[J].Chinese Journal of Catalysis,2015,36(7):969-974.
[11] Su Y G,Wang S W,Meng Y,et al.Dual substitutions of single dopant Cr3+ in perovskite NaTaO3:synthesis,structure,and photocatalytic performance[J].RSC Advances,2012,2:12932-12939.
[12] 张利国.掺杂对钽基半导体光学及磁学性能的调控研究[D].太原:山西师范大学,2016.
[13] Wu Z,Li G Q,Zhang F,et al.Photocatalytic activity of NaTaO3:La prepared under different atmospheres[J].Applied Surface Science,2014,319:372-375.
[14] Liu X,Sohlberg K.Role of effective carrier mass in the photocatalytic efficiency of La-doped NaTaO3[J].Computational Materials Science,2016,123:1-7.
[15] 周利影.La、Ce掺杂NaTaO3薄膜的制备及其水解性能研究[D].长春:吉林大学,2015.
[16] Jana P,Montero C M,Pizarro P,et al.Photocatalytic hydrogen production in the water/methanol system using Pt/RE:NaTaO3(RE=Y,La,Ce,Yb) catalysts[J].Internatonal Journal of Hydrogen Energy,2014,39:5283-5290.
[17] Su Y G,Peng L M,Guo J W,et al.Tunable optical and photocatalytic performance promoted by nonstoichiometric control and site-selective codoping of trivalent ions in NaTaO3[J].The Jonrnal of Physical Chemistry C,2014,118(20):10728-10739.
[18] Wang B C,Kanhere P D,Chen Z,et al.Anion-doped NaTaO3 for visible light photocatalysis[J].The Journal of Physical Chemistry C,2013,117(44):22518-22524.
[19] Hou J G,Cao S Y,Wu Y Z,et al.Perovskite-based nanocubes with simultaneously improved visible-light absorption and charge separation enabling efficient photocatalytic CO2 reduction[J].Nano Energy,2016,30:59-68.
[20] Wang Y,Lu H Q,Wang Y Y,et al.Facile synthesis of TaOxNy photocatalysts with enhanced visible photocatalytic activity[J].RSC Advances,2016,6:1860-1864.
[21] Hu C C,Huang H H,Huang Y C.N-doped NaTaO3 synthesized from a hydrothermal method for photocatalytic water splitting under visible light irradiation[J].Journal of Energy Chemistry,2017,26(3):515-521.
[22] 刘大锐.N掺杂NaTaO3的低温合成方法及光催化性能研究[J].环境工程,2014,32:951-956,960.
[23] 李文琪,李霞.可见光响应S掺杂NaTaO3的制备及其催化性能研究[J].硅酸盐通报,2017,36(11):3867-3872.
[24] 马婷婷.钽酸盐光催化剂的制备及改性研究[D].青岛:青岛科技大学,2017.
[25] Li F F,Liu D R,Gao G M,et al.Improved visible-light photocatalytic activity of NaTaO3 with perovskite-like structure via sulfur anion doping[J].Applied Catalysis B(Environmental),2015,166/167:104-111.
[26] Nisar J,Wang B C,Pathak B,et al.Mo- and N-doped BiNbO4 for photocatalysis applications[J].Appl Phys Lett,2011,99:051909-051912.
[27] 吴奇,苏钰丰,孙岚,等.Fe、N共掺杂TiO2纳米管阵列的制备及可见光光催化活性[J].物理化学学报,2012,28(3):635-640.
[28] 章薇.水热法制备钽酸盐粉体及光催化性能研究[D].西安:陕西科技大学,2012.
[29] Modak B,Ghosh S K.Improvement of photocatalytic activity of NaTaO3 under visible lightby N and F doping[J].Chemical Physics Letters,2014,613:54-58.
[30] 李灿.掺杂NaTaO3光催化剂的制备与光解水制氢性能研究[D].武汉:武汉理工大学,2011.
[31] 许蕾蕾,李灿,施伟东,等.NaTaO3∶Cu/W的结构和可见光催化制氢性能[J].高等学校化学学报,2012,33(11):2537-2543.
[32] Tian P L,Jiang Z Y,Zhang X D,et al.Visible light absorption of (Fe,C/N) co-doped NaTaO3∶DFT+U[J].Chin Phys B,2017,26(8):087102-087109.
[33] Wang S,Xu X W,Luo H.Enhanced organic dye removal of the W and N co-doped NaTaO3 under visible light irradiation[J].Journal of Alloys and Compounds,2016,681:225-232.
[34] Kanhere P,Shenai P,Chakraborty S,et al.Mono- and co-doped NaTaO3 for visiblelight photocatalysis[J].Phys Chem Chem Phys,2014,16:16085-16094.
[35] 赵艳茹,刘春辉,向天成.Fe-N共掺杂NaTaO3光催化材料制备和性能探究[J].化学试剂,2014,36(10):889-892,896.
[36] Zhou Y N,Wang Y G,Wen T,et al.Enhanced visible-light-driven photocatalytic activity in yellow and black orthorhombic NaTaO3 nanocubes by surface modification and simultaneous N/Ta4+ co-doping[J].Journal of Colloid and Interface Science,2016,461:185-194.
[37] Modak B,Srinivasu K,Ghosh S K.Photocatalytic activity of NaTaO3 doped with N,Mo,and (N,Mo):a hybrid density Functional Study[J].The Journal of Physical Chemistry C,2014,118(20):10711-10719.

基金资助

国家自然科学基金青年基金项目(51108225);内蒙古自然科学基金面上项目(2017MS0522);内蒙古“一湖两海”水污染控制与综合治理关键技术研发与集成示范(ZDZX2018054);国家自然科学基金地区基金(51868054);内蒙古自治区科技创新引导(KCBJ2018005)

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