相变微胶囊多采用有机高分子材料作为囊壁,微胶囊的包覆率高,且具有优异的稳定性,但该类材料导热性能较差,影响了微胶囊使用过程的导热率,为了改善微胶囊的导热性,许多研究者将导热材料引入囊壁,或者采用导热性能较好的无机材料进行改性,从而提高微胶囊的导热性能。对近年来提高微胶囊相变材料导热性的方法进行了综述,并介绍了导热增强型微胶囊相变材料的应用途径。
Organic polymer is used usually as shell material of phase change microcapsules due to its good thermal stability and encapsulation efficiency,but the thermal conductivity of organic polymer shell is poor which affects the heat transfer performance of microcapsules.Many researchers reported that added the thermal conductive material into the shell of microcapsule or used the inorganic material with better thermal conductivity to modify the shell which can improve the thermal conductivity of microcapsules.The preparation methods of thermal conductivity enhancement microcapsules in recent years were reviewed,and its applications were also introduced.
[1] 李志生,张姝婷.相变材料的研究进展与应用综述[J].建筑节能,2016,44(4):57-60.
[2] 史巍,王传涛.相变材料研究综述[J].硅酸盐通报,2015,34(12):3517-3522.
[3] 杨春晓,谢德龙,司徒粤,等.相变储能微/纳米胶囊的制备及其在建筑中的应用研究进展[J].化工进展,2012,31(9):1998-2005.
[4] Liu L K,Alav G,Huang X,et al.Preparation,heat transfer and flow properties of microencapsulated phase change materials for thermal energy storage[J].Renewable and Sustainable Energy Reviews,2016,66:399-414.
[5] Chalco-sandoval W,Fabra M J,Lopez-rubio A,et al.Use of phase change materials to develop electrospun coating of interest in food packaging applications[J].Journal of Food Engineering,2017,192:122-128.
[6] 杨小兰,袁娅,谭玉荣,等.纳米微胶囊技术在功能食品中的应用研究进展[J].食品科学,2013,34(21):359-368.
[7] Iqbal K,Sun D M.Development of thermo-regulating polypropylene fibre containing microencapsulated phase change materials[J].Renewable Energy,2014,71(11):473-479.
[8] Sarier N,Onder E.Organic phase change materials and their textile application:an overview[J].Thermochimica Acta,2012,540(14):7-60.
[9] 杨超,张东,李秀强.相变材料微胶囊研究现状及应用[J].储能科学与技术,2014,3(3):203-209.
[10] 吴晓森,张学骜,刘长利,等.微胶囊相变材料的研究进展[J].化学世界,2006,47(2):108-112.
[11] Jin Z G,Wang Y D,Liu J G,et al.Synthesis and properties of paraffin capsules as phase change materials[J].Polymer,2008,49(12):2903-2910.
[12] Krupa I,Nogellova Z,Spitalsky Z,et al.Phase change materials materials based on high-density polyethylene filled with microencapsulated paraffin wax[J].Energy Conversion and Management,2014,87(11):400-409.
[13] Al-shannaq R,Farid M,Al-muhtaser S,et al.Emulsion stability and cross-linking of PMMA microcapsules containing phase change materials[J].Solar Energy Materials and Solar Cells,2015,132:311-318.
[14] Jamekhorshid A,Sadramelis M,Bahramian A R.Process optimization and modeling of microencapsulated phase change materials using response surface methodology[J].Applied Thermal Engineering,2014,70(1):183-189.
[15] 陆少锋,邢建伟,吴钦,等.界面聚合聚脲/聚氨酯双层微胶囊相变材料的研制与性能[J].高分子材料科学与工程,2010,27(12):39-41.
[16] 詹建,邹得球,李乐园,等.高温相变石蜡-脲醛树脂微胶囊的制备及表征[J].复合材料学报,2017,34(2):284-290.
[17] 王建川.氧化石墨烯/密胺树脂相变储热微胶囊的制备及性能研究[D].广州:华南理工大学,2015.
[18] 谢鸿洲.新型无机-有机复合壳层纳米胶囊相变蓄冷流体的热物性及传热性能[D].广州:华南理工大学,2015.
[19] 魏德英,国术坤,赵永男.石墨烯的制备与应用研究进展[J].化工新型材料,2011,39(6):11-14.
[20] 于小雯,石高全.石墨烯/高分子复合薄膜的制备及应用[J].高分子学报,2014,(7):885-895.
[21] 张伟娜,何伟,张新荔.石墨烯的制备方法及其应用特性[J].化工新型材料,2010,38(4):15-18.
[22] 张丽,杨文彬,张凯,等.氧化石墨烯改性密胺树脂/石蜡相变微胶囊的制备及性能[J].高分子材料科学与工程,2017,33(5):147-151.
[23] 陈中华,王建川,余飞,等.氧化石墨烯/密胺树脂复合材料的制备及其热性能的研究[J].功能材料,2015,46(1):1125-1128.
[24] 吴炳洋,郑帼,孙玉,等.石墨烯/正十八烷微胶囊的制备与及其热性能研究[J].高分子学报,2016(2):242-249.
[25] 陈旭,王瑞.乳液聚合法制备石墨烯改性MUF/石蜡相变材料微胶囊[J].成都纺织高等专科学校学报,2017,34(2):11-16.
[26] 郭军红,张鹏中,慕波,等.氧化石墨烯增强聚苯乙烯/硬脂酸丁脂微胶囊相变材料的研究[J].功能材料,2016,47(12):12178-12183.
[27] 惠龙.导热增强型相变微胶囊的制备与应用[D].无锡:东南大学,2015.
[28] Latibari S T,Mehrali Mo,Mehrali Me,et al.Synthesis,characterization and thermal properties of nanoencapsulated phase change materials via sol-gel method[J].Energy,2013,61(4):664-672.
[29] 童晓梅,张敏,雷垒,等.纳米SiO2和石墨改性相变储热微胶囊的研究[J].化工新型材料,2010,38(9):128-130.
[30] Xuan Y M,Huang Y,Li Q.Experimental investigation on thermal conductivity and specific heat capacity of magnetic microencapsulated phase change material suspension[J].Chemical Physics Letters,2009,479(4):264-269.
[31] Chai L X,Wang X D,Wu D Z.Development of bifunctional microencapsulated phase change materials with crystalline titanium dioxide shell for latent-heat storage and photocatalytic effectiveness[J].Applied Energy,2015,138:661-674.
[32] Cao L,Tang F,Fang G Y.Preparation and characteristics of microencapsulated palmitic acid with TiO2 shell as shape-stabilized thermal energy storage materials[J].Solar Energy Materials and Solar Cells,2014,123(2):183-188.
[33] Pan L,Tao Q H,Zhang S D,et al.Preparation,characterization and thermal properties of micro-encapsulated phase change materials[J].Solar Energy Materials and Solar Cells,2012,98(1):66-70.
[34] 乔榛,毛健.石墨烯包覆的MUF石蜡微胶囊的制备及在红外隐身领域的应用[J].化工新型材料,2016,44(12):88-90.
[35] Yuan K J,Wang H C,Liu J,et al.Novel slurry containing grapheme oxide-grafted microencapsulated phase change material with enhance thermo-physical properties and photo-thermal performance[J].Solar Energy Materials and Solar Cells,2015,143(143):29-37.
基金资助
国家自然科学基金项目(51403169);陕西省教育厅重点实验室项目(15JS029);中国纺织工业联合会科技指导性项目(2016034);中国博士后科学基金面上资助项目(2017M622620)
PDF
(1190KB)
