α-Fe2O3氧化铁纳米颗粒的合成、表征及光催化性能研究

杜庆波1, 蔡红2,3, 朱军2,3, 耿涛2,3

化工新型材料 ›› 2018, Vol. 46 ›› Issue (3) : 194 -196.

PDF (2249KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (3) : 194-196.
科学研究

α-Fe2O3氧化铁纳米颗粒的合成、表征及光催化性能研究

    杜庆波1, 蔡红2,3, 朱军2,3, 耿涛2,3
作者信息 +

Synthesis,characterization and photocatalytic property of iron oxide nanoparticle

  • Du Qingbo1, Cai Hong2,3, Zhu Jun2,3, Geng Tao2,3
Author information +
文章历史 +
PDF (2302K)

摘要

采用溶剂热法,以硝酸铁为铁源,十六烷基三甲基溴化铵为表面活性剂,合成了α-Fe2O3纳米颗粒。采用X-射线粉末衍射(XRD)、扫描电子显微镜(SEM),透射电子显微镜(TEM)对样品进行了分析。把α-Fe2O3纳米颗粒用于光催化降解有机染料罗丹明B,并和商业Fe2O3粉体比较,结果发现,α-Fe2O3光催化活性明显高于商品Fe2O3粉体。

Abstract

The α-Fe2O3 nanoparticles were synthesized using ferric nitrate as Fe source and hexadecyltrimethylammonium bromide as surfactant by a simple solvothermal route,without any template or subsequent calcination.The as-obtained products were characterized by X-ray diffractometer (XRD),scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The photocatalytic activity of products was evaluated by photodegradation of RhB dye solution under UV light,and comparing with commercial hematite powder.The results showed that the photocatalytic activity were much higher than that of the commercial hematite powder.

关键词

α-Fe2O3 / 纳米材料 / 光催化

Key words

α-Fe2O3 / nanomaterial / photocatalysis

引用本文

引用格式 ▾
α-Fe2O3氧化铁纳米颗粒的合成、表征及光催化性能研究[J]. 化工新型材料, 2018, 46(3): 194-196 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Lee N,Choi Y,Lee Y,et al.Water-dispersible ferrimagnetic iron oxide nanocubes with extremely high r2 relaxivity for highly sensitive in vivo MRI of tumors[J].Nano Letters,2012,12(6):3127-3131.
[2] Huang Y,Wei T,Yu J,et al.Multifunctional metal rattle-type nanocarriers for MRI-guided photothermal cancer therapy[J].Molecular Pharmaceutics,2014,11(10):3386-3394.
[3] Balasubramaniam S,Kayandan S,Lin Y N,et al.Toward design of magnetic nanoparticle clusters stabilized by biocompatible diblock copolymers for T2-weighted MRI contrast[J].Langmuir,2014,30(6):1580-1587.
[4] Bigall N C,Dilena E,Dorfs D,et al.Hollow iron oxide nanoparticles in polymer nanobeads as MRI contrast agents[J].Journal of Physical Chemistry C,2015,119(11):6246-6253.
[5] Gale E M,Atanasova I P,Blasi F,et al.A manganese alternative to gadolinium for MRI contrast[J].J Am Chem Soc,2015,137(49):15548-15557.
[6] Bi D,Xu Y.Improved photocatalytic activity of WO3 through clustered Fe2O3 for organic degradation in the presence of H2O2[J].Langmuir,2011,27(15):9359-9366.
[7] Kang J,Kuang Q,Xie Z X,et al.Fabrication of the SnO2/α-Fe2O3 hierarchical heterostructure and its enhanced photocatalytic property[J].Journal of Physical Chemistry C,2011,115(16):7874-7879.
[8] Penki T R,Shivakumara S,Minakshi M,et al.Porous flower-like α-Fe2O3 nanostructure:a high performance anode material for lithium-ion batteries[J].Electrochimica Acta,2015,167:330-339.
[9] Kwon K A,Lim H S,Sun Y K,et al. α-Fe2O3 submicron spheres with hollow and macroporous structures as high-performance anode materials for lithium ion batteries[J].Journal of Physical Chemistry C,2014,118(6):2897-2907.
[10] Sun P,Wang W,Liu Y,et al.Hydrothermal synthesis of 3D urchin-like α-Fe2O3 nanostructure for gas sensor[J].Sensors and Actuators B:Chemical,2012,173:52-57.
[11] Wang C,Cheng X,Zhou X,et al.Hierarchical α-Fe2O3/NiO composites with a hollow structure for a gas sensor[J].ACS Applied Materials & Interfaces,2014,6(15):12031-12037.
[12] Mushove T,Breault T M,Thompson L T.Synthesis and characterization of hematite nanotube arrays for photocatalysis[J].Industrial & Engineering Chemistry Research,2015,54(16):4285-4292.
[13] Zhang C,Ai L,Jiang J.Graphene hybridized photoactive iron terephthalate with enhanced photocatalytic activity for the degradation of Rhodamine B under visible light[J].Industrial & Engineering Chemistry Research,2014,54(1):153-163.
[14] Zandi O,Beardslee J A,Hamann T.Substrate dependent water splitting with ultrathin α-Fe2O3 electrodes[J].Journal of Physical Chemistry C,2014,118(30):16494-16503.
[15] Zhang Y J,Liu L C,Ni L L,et al.A facile and low-cost synthesis of granulated blast furnace slag-based cementitious material coupled with Fe2O3 catalyst for treatment of dye wastewater[J].Applied Catalysis B:Environmental,2013,138:9-16.
[16] Sun T W,Zhu Y J,Qi C,et al.α-Fe2O3 nanosheet-assembled hierarchical hollow mesoporous microspheres:microwave-assisted solvothermal synthesis and application in photocatalysis[J].Journal of Colloid and Interface Science,2016,463:107-117.
[17] Hao H,Sun D,Xu Y,et al.Hematite nanoplates:controllable synthesis,gas sensing,photocatalytic and magnetic properties[J].Journal of Colloid and Interface Science,2016,462:315-324.
[18] Liu Y,Yu C,Dai W,et al.One-pot solvothermal synthesis of multi-shelled α-Fe2O3 hollow spheres with enhanced visible-light photocatalytic activity[J].Journal of Alloys and Compounds,2013,551:440-443.
[19] Ortega D,Garitaonandia J S,Barrera-Solano C,et al.γ-Fe2O3/SiO2 nanocomposites for magneto-optical applications:nanostructural and magnetic properties[J].Journal of Non-Crystalline Solids,2006,352(26):2801-2810.

基金资助

安徽省教育厅省级质量工程项目(2015jyxm692);自旋电子与纳米材料安徽省重点实验室开放课题(2014YKF46);安徽省教育厅自然科学研究项目(KJ2013Z315、KJ2015A271);安徽省高校优秀青年人才支持计划重点项目(gxyqZD2016342)

AI Summary AI Mindmap
PDF (2249KB)

1088

访问

0

被引

导航
相关文章

AI思维导图

/