化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (3) : 14-18.

综述与专论

石墨烯基多孔碳材料对CO₂的捕集分离研究进展

作者信息 +

Review on the capture and separation of CO₂ from the graphene based porous carbon material

Liao Hongbin, Yang Zhiyuan, Liu Jiaoping

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文章历史 +

Received		Published
2016-12-13		2018-03-20
Issue Date	Revised Date
2018-04-09	2016-12-13

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摘要

日益严重的温室效应引起人们对CO₂捕集分离技术的关注。石墨烯基多孔碳材料以其优异的导热性、热稳定性、多孔性和高机械强度等优点,在CO₂捕集分离等方面展现出广阔的应用前景。对石墨烯基多孔碳材料在CO₂捕集分离方面的研究进展进行了综述,分析了二维石墨烯、三维石墨烯以及石墨烯复合多孔材料在CO₂捕集分离的研究进展。总结了提高石墨烯基多孔材料性能的方法,简述了石墨烯基多孔材料在CO₂捕集分离中的不足以及未来的研究方向。

Abstract

The increasing greenhouse effect caused the concern of CO₂ separation and capture technology.Graphene based porous carbon materials with excellent thermal conductivity,thermal stability,porosity and high mechanical strength,show a broad application prospect in the adsorption of CO₂.The progress in the study on the adsorption of graphene based porous carbon materials on CO₂ was summarized,and analyzed the progress of the two-dimensional graphene,the three-dimensional graphene and graphene composite porous materials on CO₂ adsorption.The methods to improve the performance of graphene based porous materials were summarized and pointed out the limitations and future research direction of graphene based porous materials on CO₂ separation and capture.

关键词

石墨烯基多孔材料 / CO₂捕集分离 / 比表面积 / 吸附容量

Key words

graphene based porous material / CO₂ separation and capture / specific surface area / adsorption capacity

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石墨烯基多孔碳材料对CO₂的捕集分离研究进展[J]. 化工新型材料, 2018, 46(3): 14-18 DOI:

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Labus K,Gryglewicz S,Machnikowski J.Granular KOH-activated carbons from coal-based cokes and their CO₂ adsorption capacity[J].Fuel,2014,118:9-15.
[2] Araminiya A,Rufford T E,Zhu Z.Nitrogen-doped carbon foams synthesized from banana peel and zinc complex template for adsorption of CO₂,CH₄,and N₂[J].Energy Fuels,2016,30(9):7298-7309.
[3] Arami Niya A,Rufford T E,Zhu Z.Activated carbon monoliths with hierarchical pore structure from tar pitch and coal powder for the adsorption of CO₂,CH₄ and N₂[J].Carbon,2016,103:115-124.
[4] Chai S,Liu Z M,Huang K,et al.Amine functionalization of microsized and nanosized mesoporous carbons for carbon dioxide capture[J].Ind Eng Chem Res,2016,55(27):7355-7361.
[5] Ge C,Song J,Qin Z,et al.Polyurethane foam-based ultramicroporous carbons for CO₂ capture[J].Appl Mater Interfaces,2016,8(29):18849-18859.
[6] Adeniran B,Masika E,Mokaya R.A family of microporous carbons prepared via a simple metal salt carbonization route with high selectivity for exceptional gravimetric and volumetric post-combustion CO₂ capture[J].J Mater Chem A,2014,2(35):14696-14710.
[7] Díez N,Álvarez P,Granda M,et al.CO₂ adsorption capacity and kinetics in nitrogen-enriched activated carbon fibers prepared by different methods[J].Chemical Engineering Journal,2015,281:704-712.
[8] Choma J,Osuchowski L,Marszewski M,et al.Developing microporosity in Kevlar1-derived carbon fibers by CO₂ activation for CO₂ adsorption[J].Journal of CO₂ Utilization,2016,16:17-22.
[9] Lee S Y,Park S J.Determination of the optimal pore size for improved CO₂ adsorption in activated carbon fibers[J].Journal of Colloid and Interface Science,2013,389(1):230-235.
[10] 汤艳萍,徐庆,唐睿智,等.二维碳质材料的制备和应用[J].新型炭材料,2016,31(3):213-231.
[11] Koenig S P,Wang L,Pellegrino J,et al.Selective molecular sieving through porous grapheme[J].Nature Nanotechnology,2012,7(11):728-732.
[12] Meyer J C,Geim A K,Katsnelson M I,et al.The structure of suspended graphene sheets[J].Nature,2007,446(7131):60-63.
[13] Lee C,Wei X,J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.
[14] Leenaerts O,Partoens B,Peeters F M.Graphene:a perfect nanoballoon[J].Appl Phys Lett,2008,93(19):183-186.
[15] Bunch J S,Verbridge S S,Alden J S,et al.Impermeable atomic membranes from graphene sheets[J].Nano Lett,2008,8(8),2458-2462.
[16] Chen S,Brown L,Levendorf M,et al.Oxidation resistance of graphene-coated Cu and Cu/Ni alloy[J].Nano,2011,5(2),1321-1327.
[17] Huang L,Zhang M,Li C,et al.Graphene-based membranes for molecular separation[J].J Phys Chem Lett,2015,6(14):2806-2815.
[18] Dreyer D R,Park S,Bielawski C W,et al.The chemistry of graphene oxide[J].Chem Soc Rev,2010,39(1):228-240.
[19] Wood B C,Bhide S Y,Dutta D,et al.Methaneand carbon dioxide adsorption on edge-functionalized graphene:a comparative DFT study[J].J Chem Phys,2012,137(5):573-586.
[20] Seema H,Kemp K C,Le N H,et al.Highly selective CO₂ capture by S-doped microporous carbon materials[J].Carbon,2014,66:320-326.
[21] Haque E,Sarkar S,Hassan M,et al.Tuning graphene for energy and environmental applications:oxygen reduction reaction and greenhouse gas mitigation[J].Journal of Power Sources,2016,328:472-481.
[22] 孙成珍,张锋,柳海,等.多孔石墨烯气体分离膜分子渗透机理[J].化工学报,2014,65(8):3026-3031.
[23] Sun C,Wen B,Bai B.Application of nanoporous graphene membranes in natural gas processing:molecular simulations of CH₄/CO₂,CH₄/H₂S and CH₄/N₂ separation[J].Chemical Engineering Science,2015,138:616-621.
[24] 温伯尧,孙成珍,白博峰.多孔石墨烯分离CH₄/CO₂的分子动力学模拟[J].物理化学学报,2015,31(2):261-267.
[25] 刘晓强,田之悦,储伟,等.CH₄,CO₂和H₂O在非金属原子修饰石墨烯表面的吸附[J].物理化学学报,2014,30(2):251-256.
[26] Souza L K C D,Wickramaratne N P,Ello A S,et al.Enhancement of CO₂ adsorption on phenolic resin-based mesoporous carbons by KOH activation[J].Carbon,2013,65:334-340.
[27] Srinivas G,Burress J,Yildirim T,et al.Graphene oxide derived carbons (GODCs):synthesis and gas adsorption properties[J].Energy Environ Sci,2012,5(4):6453-6459.
[28] Ganesan A,Shaijumon M M.Activated graphene-derived porous carbon with exceptional gas adsorption properties[J].Microporous and Mesoporous Materials,2016,220(1):21-27.
[29] Xia K,Tian X,Fei S,et al.Hierarchical porous graphene-based carbons prepared by carbon dioxide activation and their gas adsorption properties[J].International Journal of Hydrogenenergy,2014,39(21):11047-11054.
[30] Sui Z Y,Meng Q H,Li J T,et al.High surface area porous carbons produced by steam activation of graphene aerogels[J].J Mater Chem A,2014,2(25):9891-9898.
[31] Lee J,Aluru N R.Water-solubility-driven separation of gases using graphene membrane[J].Journal of Membrane Science,2013,428(2):546-553.
[32] Casco M E,Morelos-Gómez A,Vega-Díaz S M,et al.CO₂ adsorption on crystalline graphitic nanostructures[J].Journal of CO₂ Utilization,2014(5):60-65.
[33] Wang X,Chi C,Tao J,et al.Improving the hydrogen selectivity of graphene oxide membranes by reducing non-selective pores with intergrown ZIF-8 crystals[J].Chem Commun,2016,52(52):8087-8090.
[34] Saha D,Nelson K,Chen J,et al.Adsorption of CO₂,CH₄,and N₂ in micro-mesoporous nanographene:a comparative study[J].J Chem Eng Data,2015,60(9):2636-2645.
[35] Kwac K,Ji H L,Choi J W,et al.Computational analysis of pressure-dependent optimal pore size for CO₂ capture with graphitic surfaces[J].J Phys Chem C,2016,120(7):3978-3985.
[36] Sudeep P M,Narayanan T N,Ganesan A,et al.Covalently interconnected three dimensional graphene oxide solids[J].Nano,2013,7(8):7034-7040.
[37] Yun S,Lee H,Lee W E,et al.Multiscale textured,ultralight graphene monoliths for enhanced CO₂ and SO₂ adsorption capacity[J].Fuel,2016,174:36-42.
[38] Sui Z Y,Han B H.Effect of surface chemistry and textural properties on carbon dioxide uptake in hydrothermally reduced graphene oxide[J].Carbon,2015,82:590-598.
[39] Dong L,Zhang C,Bai Y,et al.High performance PEBA2533-functional MMT mixed matrix membrane containing high-speed facilitated transport channels for CO₂/N₂ separation[J].Sustainable Chem Eng,2016,4(6):3486-3496.
[40] Lin R,Ge L,Liu S,et al.Mixed-matrix membranes with metal-organic framework decorated CNT fillers for efficient CO₂ separation[J].Appl Mater Interfaces,2015,7(27):14750-14757.
[41] Smith Z P,Freeman B D.Graphene oxide:a new platform for high-performance gas-and liquid-separation membranes[J].Angew Chem Int Ed,2014,53(39):10286-10288.
[42] Joshi R K,Carbone P,Wang F C,et al.Precise and ultrafast molecular sieving through grapheneoxide membranes[J].Science,2014,343(6172):752-754.
[43] Li X,Cheng Y,Zhang H,et al.Efficient CO₂ capture by functionalized graphene oxide nanosheets as fillers to fabricate multi-permselective mixed matrixmMembranes[J].Appl Mater Interfaces,2015,7(9):5528-5537.
[44] Wang J,Stevens L A,Drage T C Drage,et al.Preparation and CO₂ adsorption of amine modified Mg-Al LDH via exfoliation route[J].Chemical Engineering Science,2012,68(1):424-431.[45] Garciagallastegui A,Iruretagoyena D,Gouvea V,et al.Graphene oxide as support for layered double hydroxides:enhancing the CO₂ Adsorption Capacity[J].Chem Mater,2012,24(23):4531-4539.
[46] Iruretagoyena D,Huang X,Shaffer M S P,et al.Influence of alkali metals (Na,K,and Cs) on CO₂ adsorption by layered double oxides supported on graphene oxide[J].Ind Eng Chem Res,2015,54(46):11610-11618.
[47] Chowdhury S,Parshetti G K,Balasubramanian R.Post-combustion CO₂ capture using mesoporous TiO₂/graphene oxide nanocomposites[J].Chemical Engineering Journal,2015,263:374-384.
[48] Rad A S,Foukolaei V P.Density functional study of Al-doped graphene nanostructure towards adsorption of CO,CO₂ and H₂O[J].Synthetic Metals,2015,210:171-178.
[49] Li W,Yang H,Jiang X,et al.Highly selective CO₂ adsorption of ZnO based N-doped reduced graphene oxide porous nanomaterial[J].Applied Surface Science,2016,360:143-147.
[50] Kudasheva A,Sorribas S,Zornoza B,et al.Pervaporation of water/ethanol mixtures through polyimide based mixed matrix membranes containing ZIF-8,ordered mesoporous silica and ZIF-8-silica core-shell spheres[J].J Chem Technol Biotechnol,2015,90(4):669-677.
[51] Kumar R,Jayaramulu K,Maji T K,et al.Growth of 2D sheets of a MOF on grapheme surfaces to yield composites with novel gas adsorption characteristics[J].Dalton Trans,2014,43(20):7383-7386.
[52] Qiu X,Wang X,Li Y.Controlled growth of dense and ordered metal-organic framework nanoparticles on graphene oxide[J].Chem Commun,2015,51:3874-3877.
[53] Bian Z,Xu J,Zhang S,et al.Interfacial growth of metal organic framework/graphite oxide composites through pickering emulsion and their CO₂ capture performance in the presence of humidity[J].Langmuir,2015,31(26):7410-7417.
[54] Kumar R,Jayaramulu K,Maji T K,et al.Hybrid nanocomposites of ZIF-8 with graphene oxide exhibiting tunable morphology,significant CO₂ uptake and other novel properties[J].Chem Commun,2013,49(43):4947-4949.
[55] Xu F,Yu Y,Yan J,et al.Ultrafast room temperature synthesis of GrO@HKUST-1 composites with high CO₂ adsorption capacity and CO₂/N₂ adsorption selectivity[J].Chemical Engineering Journal,2016,303:231-237.