生物质衍生碳是一类以可再生生物质为前驱体制备的电催化材料,具有大比表面积、多孔结构和自掺杂的特点。用于电催化领域的生物质衍生碳主要分为自掺杂型生物质衍生碳材料和以其为载体的生物质衍生碳复合催化材料。综述了生物质衍生碳材料在电催化反应,如氧还原反应、析氧反应、析氢反应及二氧化碳还原反应中的应用研究进展,总结了该材料的催化性能优势,如电子结构调控、活性位点暴露和增强的电荷/离子传输效率,并展望了生物质衍生碳材料未来的发展方向。
Biomass-derived carbon refers to a class of electrocatalytic materials prepared from renewable biomass precursors,featuring a large specific surface area,porous structure and intrinsic doping properties.Biomass-derived carbon materials applied in the electrocatalysis field are mainly classified into two categories:self-doped biomass-derived carbon materials and biomass-derived carbon composite catalytic materials with the former as the carrier.This paper reviewed the research progress in the applications of biomass-derived carbon materials in electrocatalytic reactions,including the oxygen reduction reaction (ORR),oxygen evolution reaction (OER),hydrogen evolution reaction (HER) and carbon dioxide reduction reaction (CO2RR).It also summarized the advantages of such materials in catalytic performance,such as electronic structure regulation,active site exposure and enhanced charge/ion transport efficiency,and prospected the future development directions of biomass-derived carbon materials.
[1] Tyagi A,Banerjee S,Singh S,et al.Biowaste derived activated carbon electrocatalyst for oxygen reduction reaction:effect of chemical activation[J].International Journal of Hydrogen Energy,2020,45(34):16930-16943.
[2] Li Z,Kumar A,Liu N,et al.Oxygenated P/N co-doped carbon for efficient 2e-oxygen reduction to H2O2[J].Journal of Materials Chemistry A,2022,10(27):14355-14363.
[3] Ren X,Zhai Y,Yang N,et al.Lattice oxygen redox mechanisms in the alkaline oxygen evolution reaction[J].Advanced Functional Materials,2024,34(32):2401610.
[4] Dalai N,Jena B.Iron nickel sulfide nanorods for oxygen and hydrogen evolution reaction[J].Chemistry Select,2023,8(13):202204370.
[5] Xu H,Zhang S,Zhang X,et al.Atomically dispersed iron re-gulating electronic structure of iron atom clusters for electrocatalytic H2O2 production and biomass upgrading[J].Angewandte Chemie International Edition,2023,62(52):202314414.
[6] Plauck A,Stangland E E,Dumesic J A,et al.Active sites and mechanisms for H2O2 decomposition over Pd catalysts[J].Proceedings of the National Academy of Sciences,2016,113(14):1973-1982.
[7] Fu H,Wei J,Chen G,et al.Axial coordination tuning Fe single-atom catalysts for boosting H2O2 activation[J].Applied Catalysis B:Environmental,2023,321:122012.
[8] Lin Z,Li Y,Li R,et al.Defect engineering induced high metal loading Co-single-atom catalyst on carbon dots for efficient H2O2 electrosynthesis[J].Chemical Engineering Journal,2024,501:157661.
[9] Zhao X,Li Y G.Two-electron oxygen reduction reaction by high-loading molybdenum single-atom catalysts[J].Rare Metals,2020,39(5):455-457.
[10] Alqudaihi K,Alrwaily B,Alzawad B,et al.Advances in biomass-derived carbon materials:production,functionalization,and applications for contaminant removal[J].Chemistry-An Asian Journal,2025,20(17):445.
[11] Rois M F,Widiyastuti W,Setyawan H,et al.Preparation of activated carbon from alkali lignin using novel one-step process for high electrochemical performance application[J].Arabian Journal of Chemistry,2021,14(6):103162.
[12] Panganoron H O,Pascasio J D A,Esparcia Jr E A,et al.Hydrothermally carbonized waste biomass as electrocatalyst support for α-MnO2 in oxygen reduction reaction[J].Catalysts,2020,10(2):177.
[13] Lu J,Ruan S,He X,et al.Plasma-enhanced chemical vapor deposition-assisted construction of biomass-derived porous carbon[J].Energy & Fuels,2025,39(21):10092-10102.
[14] Dong X,Wang J,Liu X,et al.Characterization of halophyte biochar and its effects on water and salt contents in saline soil[J].Environ Sci Pollut Res Int,2022,29(8):11831-11842.
[15] Panomsuwan G,Hussakan C,Kaewtrakulchai N,et al.Nitrogen-doped carbon derived from horse manure biomass as a catalyst for the oxygen reduction reaction[J].RSC Adv,2022,12(27):17481-17489.
[16] Wang Y,Ma C,Kong D,et al.Review on application of algae-based biochars in environmental remediation:progress,challenge and perspectives[J].Journal of Environmental Chemical Engineering,2023,11(6):111263.
[17] Zhang S,Li Y,Du Y,et al.Apple-pomace-based porous biochar as electrode materials for supercapacitors[J].Diamond and Related Materials,2022,130:109507.
[18] Gu R,Fu D,Jin Y,et al.Aspergillus niger fermentation residues application to produce biochar for the anode of lithium-ion batteries[J].J Environ Manage,2023,346:118985.
[19] Din S U,Awan J M,Imran M,et al.Novel nanocomposite of biochar-zerovalent copper for lead adsorption[J].Microsc Res Tech,2021,84(11):2598-2606.
[20] Wang X,Zhang Q,Jing J,et al.Biomass derived S,N self-doped catalytic Janus cathode for flow-through metal-free electrochemical advanced oxidation process:better removal efficiency and lower energy consumption under neutral conditions[J].Chemical Engineering Journal,2023,466:143283.
[21] Ling C,Fang K,Lv Y R,et al.Boosting the ORR performance of rice husk carbon-supported iron porphyrin catalyst through synergistic effects of doped secondary heteroatoms (S,P) in whole pH range[J].International Journal of Hydrogen Energy,2025,123:194-208.
[22] Demir M,Farghaly A A,Decuir M J,et al.Supercapacitance and oxygen reduction characteristics of sulfur self-doped micro/mesoporous bio-carbon derived from lignin[J].Materials Chemistry and Physics,2018,216:508-516.
[23] Wang X,Wu H,Jing J,et al.Synergistically S/N self-doped biochar as a green bifunctional cathode catalyst in electrochemical degradation of organic pollutant[J].Green Energy & Environment,2025,10(1):214-230.
[24] Yang B,Gao J,Xie M,et al.N-self-doped porous carbon derived from animal-heart as an electrocatalyst for efficient reduction of oxygen[J].Journal of Colloid and Interface Science,2020,579:832-841.
[25] Murugan N,Thangarasu S,Seo S B,et al.N-doped defect-rich porous carbon nanosheets framework from renewable biomass as efficient metal-free bifunctional electrocatalysts for HER and OER application[J].Renewable Energy,2024,222:119801.
[26] Zhang X,Wang Y,Zou J,et al.Unraveling the oxygen evolution activity of biomass-derived porous carbon plate as self-supported metal-free electrocatalyst for water splitting[J].Progress in Natural Science:Materials International,2024,34(5):967-976.
[27] Kumar A,Narasimman K.Utilization of algal biomass-derived carbon in the alkaline water electrolysis for hydrogen production[J].Renewable Energy,2025,254:123760.
[28] Sekar S,Sadhasivam S,Shanmugam A,et al.Boosted hydrogen evolution catalysis using biomass-derived mesoporous carbon nanosponges[J].International Journal of Molecular Sciences,2025,26(17):8502.
[29] Hao X,An X,Patil A M,et al.Biomass-derived N-doped carbon for efficient electrocatalytic CO2 reduction to CO and Zn-CO2 batteries[J].ACS Applied Materials & Interfaces,2021,13(3):3738-3747.
[30] Zhao J,Wang Q,Zhang W,et al.Unravelling the performance of N-doped lignin-derived carbon materials during electro-ca-talytic reduction of CO2[J].International Journal of Hydrogen Energy,2024,67:127-135.
[31] Lin C W,Wang T H,Liu S H.Optimizing bimetallic-insect exuviate melanin composite cathodes using response surface methodology to enhance the H2O2 yield and selectivity of the electro-Fenton process[J].Journal of Water Process Engineering,2024,64:105633.
[32] Zhu J,Sun M,Ren Y,et al.Cotton shell biomass-derived carbon-supported Fe2O3/Fe3O4 nanohybrids for efficient oxygen evolution reaction[J].Fuel,2026,406:136903.
[33] Pei X,Yi S,Zhao Y,et al.Nickel oxide nanoparticles dispersed on biomass-derived amorphous carbon/cobalt silicate support accelerate the oxygen evolution reaction[J].Journal of Colloid and Interface Science,2022,616:476-487.
[34] Chen H,Jiang H,Cao X,et al.Castoff derived biomass-carbon supported MoS2 nanosheets for hydrogen evolution reaction[J].Materials Chemistry and Physics,2020,252:123244.
[35] Shi G,Ding W,Yan B,et al.Boosting electrocatalytic hydrogen evolution reaction by a cellulose-derived nitrogen-doped order carbon matrix decorated with Ni nanoparticles[J].Langmuir,2025,41(41):28007-28015.
[36] Zhang J,Li G,Zhang S,et al.Facile modulation of hierarchical structures in biomass-derived carbon via metal-organic framework-mediated assembly for enhanced oxygen and carbon dioxide reduction reactions[J].Nano Research,2025,18:94908149.
[37] Xu J,Sun H,Pan X,et al.One-step preparation of coconut shell derived mesoporous biochar supported CuZn catalysts for CO2 hydrogenation to methanol[J].Biomass and Bioenergy,2025,195:107710.
[38] Tabac-Agam S,Burda S,Zahan S M,et al.Biomass or bio-mess:tackling reproducibility in biomass-derived carbon electrocatalysts[J].Catalysis Science & Technology,2025,15(19):5678-5689.
基金资助
国家自然科学基金(5230041519);北京市生态环境保护科学研究院基金(Y2024-010)
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