以超滤和微滤为核心的低压分离膜技术已广泛应用于废水处理领域,但膜污染问题一直是限制其高效低耗运行的主要瓶颈。聚多巴胺(PDA)作为一种仿生粘附材料,具有优异的亲水性和界面修饰能力,可有效提升低压分离膜的抗污染能力。综述了PDA在低压分离膜亲水化改性中的研究进展,详述了PDA的形成与界面粘附机理,重点介绍了PDA直接沉积改性、PDA共混改性及PDA作为中间层改性等传统改性方法及其优缺点,并介绍了氧化促进PDA沉积等新型改性策略,旨在为PDA改性技术在膜分离领域的推广应用提供指导。
Low-pressure separation membrane technologies centered on ultrafiltration and microfiltration have been widely applied in wastewater treatment processes,but membrane fouling has always been the main bottleneck restricting their efficient and low-cost operation.Polydopamine (PDA),as a bio-inspired adhesive material,can effectively enhance the anti-fouling ability of separation membranes due to its excellent hydrophilicity and interfacial modification capability.This review systematically summarized research progress on the application of PDA for enhancing the hydrophilicity of low-pressure separation membranes,detailing the formation and interfacial adhesion mechanisms of PDA.It focused on the traditional modification methods including PDA direct deposition,PDA blending,and PDA intermediate layer modification,as well as their advantages and disadvantages.Furthermore,novel strategies such as oxidation-accelerated PDA deposition were introduced,aiming to offer valuable insights for the further development and practical application of PDA technology in membrane separation.
[1] Kammakakam I,Lai Z.Next-generation ultrafiltration membranes:a review of material design,properties,recent progress,and challenges[J].Chemosphere,2023,316:137669.
[2] Dong X,Lu D,Harris T A L,et al.Polymers and solvents used in membrane fabrication:a review focusing on sustainable membrane development[J].Membranes,2021,11(5):309.
[3] Saqib J,Aljundi I H.Membrane fouling and modification using surface treatment and layer-by-layer assembly of polyelectrolytes:state-of-the-art review[J].Journal of Water Process Engineering,2016,11:68-87.
[4] Yang H C,Luo J,Lv Y,et al.Surface engineering of polymer membranes via mussel-inspired chemistry[J].Journal of Membrane Science,2015,483:42-59.
[5] Lee M,Lee S H,Oh I K,et al.Microwave-accelerated rapid,chemical oxidant-free,material-independent surface chemistry of poly (dopamine)[J].Small,2017,13(4):1600443.
[6] Yan Z,Zhang Y,Yang H,et al.Mussel-inspired polydopamine modification of polymeric membranes for the application of water and wastewater treatment:a review[J].Chemical Engineering Research and Design,2020,157:195-214.
[7] Xi Z Y,Xu Y Y,Zhu L P,et al.A facile method of surface modification for hydrophobic polymer membranes based on the adhesive behavior of poly (DOPA) and poly (dopamine)[J].Journal of Membrane Science,2009,327(1/2):244-253.
[8] Vale A C,Pereira P R,Alves N M.Polymeric biomaterials inspired by marine mussel adhesive proteins[J].Reactive and Functional Polymers,2021,159:104802.
[9] 王彩萍,蔺存国,张金伟,等.贻贝粘附蛋白及其衍生物多巴胺的研究进展[J].材料开发与应用,2014,29(4):101-104.
[10] 李珍妮,邓字巍.仿贻贝黏附性多巴胺的研究与应用进展[J].高分子材料科学与工程,2015,31(1):185-190.
[11] Zhang N,Yan T,Li C,et al.Improved separation performance of polyamide based reverse osmosis membrane incorporated with poly (dopamine) coated carbon nanotubes[J].Journal of Applied Polymer Science,2021,138(32):50808.
[12] Ding Y,Weng L T,Yang M,et al.Insights into the aggregation/deposition and structure of a polydopamine film[J].Langmuir,2014,30(41):12258-12269.
[13] Łuczak T.Preparation and characterization of the dopamine film electrochemically deposited on a gold template and its applications for dopamine sensing in aqueous solution[J].Electrochimica Acta,2008,53(19):5725-5731.
[14] Ryu J H,Messersmith P B,Lee H.Polydopamine surface chemistry:a decade of discovery[J].ACS Applied Materials & Interfaces,2018,10(9):7523-7540.
[15] Lee H,Dellatore S M,Miller W M,et al.Mussel-inspired surface chemistry for multifunctional coatings[J].Science,2007,318(5849):426-430.
[16] Wang D,Wang Q,Lin Z,et al.Effect of pH and concentration of dopamine solution on the deposited polydopamine film and the prepared graphene-like material[J].Crystals,2023,13(4):607.
[17] Hong S,Na Y S,Choi S,et al.Non-covalent self-assembly and covalent polymerization co-contribute to polydopamine formation[J].Advanced Functional Materials,2012,22(22):4711-4717.
[18] Lim J,Zhang S,Heo J M,et al.Polydopamine adhesion:catechol,amine,dihydroxyindole,and aggregation dynamics[J].ACS Applied Materials & Interfaces,2024,16(24):31864-31872.
[19] Ball V,Del Frari D,Toniazzo V,et al.Kinetics of polydopamine film deposition as a function of pH and dopamine concentration:insights in the polydopamine deposition mechanism[J].Journal of Colloid and Interface Science,2012,386(1):366-372.
[20] Sedó J,Saiz-Poseu J,Busqué F,et al.Catechol-based biomimetic functional materials[J].Advanced Materials,2013,25(5):653-701.
[21] 陶彩虹,马阜生,刘宝勇,等.基于聚多巴胺的表面改性方法研究现状[J].化学通报,2015,78(11):983-990.
[22] Xu Z,Li L,Liu J,et al.Mussel-inspired superhydrophilic membrane constructed on a hydrophilic polymer network for highly efficient oil/water separation[J].Journal of Colloid and Interface Science,2022,608:702-710.
[23] Davari S,Omidkhah M,Salari S.Role of polydopamine in the enhancement of binding stability of TiO2 nanoparticles on polyethersulfone ultrafiltration membrane[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,622:126694.
[24] Shah V,Prasetya N,Li K.Polydopamine modification of high-performance PVDF ultrafiltration membranes prepared by the combined crystallisation and diffusion (CCD) method[J].Journal of Membrane Science,2021,635:119538.
[25] 孙文超,孙浩.聚多巴胺改性膜材料的研究进展[J].山东化工,2024,53(15):140-142.
[26] Kasemset S,Wang L,He Z,et al.Influence of polydopamine deposition conditions on hydraulic permeability,sieving coefficients,pore size and pore size distribution for a polysulfone ultrafiltration membrane[J].Journal of Membrane Science,2017,522:100-115.
[27] McCloskey B D,Park H B,Ju H,et al.Influence of polydopamine deposition conditions on pure water flux and foulant adhesion resistance of reverse osmosis,ultrafiltration,and microfiltration membranes[J].Polymer,2010,51(15):3472-3485.
[28] Jiang J H,Zhu L P,Zhang H T,et al.Improved hydrodynamic permeability and antifouling properties of poly(vinylidene fluoride) membranes using polydopamine nanoparticles as additives[J].Journal of Membrane Science,2014,457:73-81.
[29] 魏子涵,郑永山,翟英健,等.基于正交试验优化的PDA@ZnO/PVDF膜的结构及过滤性能[J].工业水处理,2025,45(7):113-120.
[30] Yang Z,Wang F,Guo H,et al.Mechanistic insights into the role of polydopamine interlayer toward improved separation performance of polyamide nanofiltration membranes[J].Environmental Science & Technology,2020,54(18):11611-11621.
[31] Li F,Meng J,Ye J,et al.Surface modification of PES ultrafiltration membrane by polydopamine coating and poly (ethylene glycol) grafting:morphology,stability,and anti-fouling[J].Desalination,2014,344:422-430.
[32] 包亚晴,黄李金鸿,李新冬,等.PDA夹层调控的荷正电纳滤膜的制备及在水处理中的应用[J].材料导报,2023,37(6):206-213.
[33] Wang C,Wu H,Yu G,et al.Fast preparation of a polydopamine/ceramic composite nanofiltration membrane with excellent permselectivity[J].RSC Advances,2023,13(1):615-623.
[34] Wang Z,Zhang W,Wen S,et al.Rapid co-deposition of dopamine and polyethyleneimine triggered by CuSO4/H2O2 oxidation to fabricate nanofiltration membranes with high selectivity and antifouling ability[J].Separation and Purification Technology,2023,305:122409.
[35] Tahroudi Z M,Razmjou A,Bagherian M,et al.Polydopamine surface modification with UV-shielding effect using KMnO4 as an efficient oxidizing agent[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,559:68-73.
[36] Wang J,Guo H,Shi X,et al.Fast polydopamine coating on reverse osmosis membrane:process investigation and membrane performance study[J].Journal of Colloid and Interface Science,2019,535:239-244.
[37] Wei Q,Zhang F,Li J,et al.Oxidant-induced dopamine polymerization for multifunctional coatings[J].Polymer Chemistry,2010,1(9):1430-1433.
[38] Zhu J,Tsehaye M T,Wang J,et al.A rapid deposition of polydopamine coatings induced by iron(Ⅲ) chloride/hydrogen peroxide for loose nanofiltration[J].Journal of Colloid and Interface Science,2018,523:86-97.
[39] Chew N G P,Zhao S,Malde C,et al.Polyvinylidene fluoride membrane modification via oxidant-induced dopamine polymerization for sustainable direct-contact membrane distillation[J].Journal of Membrane Science,2018,563:31-42.
[40] Zhang C,Lv Y,Qiu W Z,et al.Polydopamine coatings with nanopores for versatile molecular separation[J].ACS Applied Materials & Interfaces,2017,9(16):14437-14444.
[41] Miao R,Mi Y,Zhang X,et al.One-step preparation of PVDF-polydopamine blend ultrafiltration membranes via nonsolvent-induced phase separation and their characterization and antifouling mechanism analysis[J].Journal of Membrane Science,2025,725:124029.
基金资助
中煤科工西安研究院(集团)有限公司科技创新基金(2024XAJS16)