作为一种新型陶瓷材料,碳化硅(SiC)纳米材料因其高温稳定性、化学稳定性、高介电性能等特性,在电磁波吸收(EWA)材料领域备受关注。以纳米SiC基EWA材料为核心,系统总结了当前纳米SiC基EWA材料的制备工艺,阐明了不同微观结构对材料EWA性能的调控机制,归纳了引入异质元素进行掺杂或与其他功能材料复合等关键性能优化策略,同时分析了当前纳米SiC基EWA材料在EWA方面的不足、挑战和前景。
As a novel ceramic material,silicon carbide (SiC) nanomaterials have garnered significant attention in the field of electromagnetic wave absorption (EWA) materials due to their high-temperature stability,chemical stability,and high dielectric properties.Centered on nanoscale SiC-based EWA materials,this study systematically summarized current preparation techniques for them.It elucidated the regulatory mechanisms of different structures on EWA performance and outlined key optimization strategies,such as heteroatomic element doping or compositing them with other functional materials.Simultaneously,it also analyzed the current shortcomings,challenges,and prospects of SiC-based nanoscale EWA materials in the field of EWA.
[1] Wang P,Cheng L,Zhang Y,et al.Synthesis of SiC nanofibers with superior electromagnetic wave absorption performance by electrospinning[J].Journal of Alloys and Compounds,2017,716:306-320.
[2] 郝婧,曹雪媛,潘凯.碳化硅纳米纤维的制备及电磁波吸收性能[J].高分子材料科学与工程,2020,36(2):127-132.
[3] Guo B,Jiang Y,Zhang Y,et al.Differentiated electromagnetic wave absorption enabled by load modulation of cross-dimensional SiC nanostructures[J].Chemical Engineering Journal,2025,509:161364.
[4] Ma Y,Lin Y,Cheng Y,et al.Branch-leaf ZrO2@SiC@WS2 fibers as outstanding microwave absorber with high-temperature tolerance[J].Chemical Engineering Journal,2025,507:160488.
[5] Zhang B,Jing Q,Yan S,et al.Electron irradiation modified point defects of SiC nanoparticles with tunable high electromagnetic wave absorption[J].Carbon,2024,218:118727.
[6] Wen L,Yan Z,Zhu Y,et al.Recent progress on the electromagnetic wave absorption of one-dimensional carbon-based nanomaterials[J].Journal of Materials Research and Technology,2023,26:2191-2218.
[7] Wang P,Wang X,Qiao L,et al.High-frequency magnetic properties and microwave absorption performance of oxidized Pr2Co17 flakes/epoxy composite in X-band[J].Journal of Magnetism and Magnetic Materials,2018,468:193-199.
[8] Liu J,Li G,Zhao T,et al.The effects of in situ growth of SiC nanowires on the electromagnetic wave absorption properties of sic porous ceramics[J].Materials,2025; 18(9):1910.
[9] Singh S,Bhaskar R,Narayanan K B,et al.Development of silicon carbide (SiC)-based composites as microwave-absorbing materials (MAMs):a review[J].Journal of the European Ceramic Society,2024,44(13):7411-7431.
[10] Zhou L,Yang T,Wang E,et al.Synthesis and reliable functional applications of SiC nanomaterials under harsh environments[J].Advanced Functional Materials,2025,35(33):2426020.
[11] Tan Z,Dong L,Lyu Z.Silicon carbide aerogels:fabrication,properties,and applications[J].Small,2025,21(22):2500907.
[12] Liu C,Lin F,Zhang K,et al.Controllable fabrication and applications of one-dimensional silicon carbide nanomaterials:a review[J].Journal of the American Ceramic Society,2025,108:e20526.
[13] Ye X,Zhang H,Yu H,et al.Synergistic design of C/SiC@SiC aerogel for enhanced thermal insulation and electromagnetic wave absorption[J].Ceramics International,2024,50(21):43023-43031.
[14] Su L,Wang H,Niu M,et al.Ultralight,recoverable,and high-temperature-resistant SiC nanowire aerogel[J].ACS Nano,2018,12(4):3103-3111.
[15] Na K H,Jang K P,Kim S W,et al.Fabrication of electrospun Ni0.5Zn0.5Fe2O4 nanofibers using polyvinyl pyrrolidone precursors and electromagnetic wave absorption performance improvement[J].Polymers,2021; 13(23):4247.
[16] Sun C,Guo Y,Xu X,et al.In situ preparation of carbon/Fe3C composite nanofibers with excellent electromagnetic wave absorption properties[J].Composites Part A:Applied Science and Manufacturing,2017,92:33-41.
[17] Zhang M,Chang M,Tian W,et al.Interfacial modulation of SiC/TiC hybrid nanofibers for fabricating flexible ceramic electromagnetic wave absorbers[J].Materials Research Bulletin,2024,178:112883.
[18] Liu Y,Li G,Huan L,et al.Advancements in silicon carbide-based supercapacitors:materials,performance,and emerging applications[J].Nanoscale,2024,16(2):504-526.
[19] Liu H,Zhang X,Xu N,et al.Progress of one-dimensional SiC Nanomaterials:design,fabrication and sensing applications[J].Nanomaterials,2024,14(2):187.
[20] Zhao K,Ye F,Cheng L,et al.Synthesis of embedded ZrC-SiC-C microspheres via carbothermal reduction for thermal stability and electromagnetic wave absorption[J].Applied Surface Science,2022,591:153105.
[21] Wang D,Wang H,Cao H,et al.Synthesis and in situ growth mechanism of SiO2@SiC core-shell nanocomposite[J].Applied Physics A,2020,126(6):423.
[22] Song L,Wang L,Chen Y,et al.Engineered core-shell SiC@SiO2 nanofibers for enhanced electromagnetic wave absorption performance[J].Small,2024,20(52):2407563.
[23] Xiang Z,He Q,Wang Y,et al.Hollow porous SiC spheres prepared by in-situ reaction with efficient microwave absorption[J].Ceramics International,2022,48(23):35317-35327.
[24] Lan X,Li Y,Wang Z.High-temperature electromagnetic wave absorption,mechanical and thermal insulation properties of in-situ grown SiC on porous SiC skeleton[J].Chemical Engineering Journal,2020,397:125250.
[25] Zhang S,Wang C,Meng X,et al.Enhanced electromagnetic wave absorption of multicore Fe4N@N-doped porous carbon core-shell microspheres through dielectric-magnetic coordination[J].Carbon,2025,237:120176.
[26] Guo R,Zheng Q,Wang L,et al.Porous N-doped Ni@SiO2/graphene network:three-dimensional hierarchical architecture for strong and broad electromagnetic wave absorption[J].Journal of Materials Science & Technology,2022,106:108-117.
[27] Liu N,Dou Y,Zhang X,et al.Design of porous FeNi-carbon nanosheets by a double-effect synergistic strategy for electromagnetic wave absorption[J].Carbon,2022,190:125-135.
[28] Zhao Z,Gao Z,Lan D,et al.MOFs-derived hollow materials for electromagnetic wave absorption:prospects and challenges[J].Journal of Materials Science:Materials in Electronics,2021,32(21):25631-25648.
[29] Li S,Lin L,Yao L,et al.MOFs-derived Co-C@C hollow composites with high-performance electromagnetic wave absorption[J].Journal of Alloys and Compounds,2021,856:158183.
[30] Yan M,Pan Y,He P,et al.Flexible hierarchical hollow SiC/SiOx micro/nanofiber sponges for broadband electromagnetic wave absorption[J].Advanced Fiber Materials,2025,7:853-863.
[31] Feng S,Wang H,Ma J,et al.Fabrication of hollow Ni/NiO/C/MnO2@polypyrrole core-shell structures for high-performance electromagnetic wave absorption[J].Composites Part B:Engineering,2024,275:111344.
[32] Li G,Tan R,Gao B,et al.PB@COF-derived core-shell Fe/Fe3O4/C composites with excellent electromagnetic wave absorption performance for the entire Ku band[J].Chemical Engineering Journal,2025,504:159010.
[33] Liu S,Li S,Guo S,et al.In-situ growth of core-shell cofe@CoFe2O4 nanoparticles on carbon aerogel for broadband electromagnetic wave absorption and thermal insulation[J].Carbon,2025,243:120598.
[34] Feng W,Wang Y,Zou Y,et al.ZnO@N-doped porous carbon/Co3ZnC core-shell heterostructures with enhanced electromagnetic wave attenuation ability[J].Chemical Engineering Journal,2018,342:364-371.
[35] Wang P,Li Z,Cheng L,et al.SiC/rGO core-shell nanowire as a lightweight,highly efficient gigahertz electromagnetic wave absorber[J].ACS Applied Electronic Materials,2020,2(2):473-482.
[36] Zhu B,Cui Y,Lv D,et al.Synthesis and electromagnetic wave absorption properties of peanut shell-like SiC fibers[J].Materials Letters,2020,263:127288.
[37] Yu S,Wang C,Chen Z,et al.Additive manufacturing of broadband electromagnetic wave absorbing materials:polymer-derived SiC/Si3N4 composites with triply periodic minimal surface meta-structure[J].Chemical Engineering Journal,2024,483:149185.
[38] Chen Z,Zhang Y,Wang Z,et al.Bioinspired moth-eye multi-mechanism composite ultra-wideband microwave absorber based on the graphite powder[J].Carbon,2023,201:542-548.
[39] Song L,Wu C,Zhi Q,et al.Multifunctional SiC aerogel reinforced with nanofibers and nanowires for high-efficiency electromagnetic wave absorption[J].Chemical Engineering Journal,2023,467:143518.
[40] Zhang B,Chen P,Wang Z.Core-shell SiC@Fe3O4 with high-efficiency electromagnetic wave absorption attributed to enhanced interfacial polarization via electron irradiation modification[J].Journal of Materials Research and Technology,2025,38:2636-2647.
[41] Zhang M,Chen X,Sun J,et al.Hollow silicon carbide microspheres for excellent and lightweight electromagnetic wave absorber[J].Journal of Alloys and Compounds,2024,972:172647.
[42] Li X,Qi Y,Lu K,et al.Simple preparation of SiC@SiO2 nanofiber with bead-like structure by microwave sintering[J].Ceramics International,2024,50(8):13982-13987.
[43] Li Y,Yang W,Zhang J,et al.Precursor-derived Mo2C/SiC composites with a two-dimensional sheet structure for electromagnetic wave absorption[J].Materials,2025,18(7):1573.
[44] Kadhim M M,Rheima A M,Shadhar M H,et al.New type anode for calcium ion batteries based on silicon carbide monolayer[J].Silicon,2023,15(1):417-424.
[45] Xu B,He Q,Wang Y,et al.Novel accordion-like structure of SiC/C composites for enhanced electromagnetic wave absorption[J].Carbon,2023,215:118470.
[46] Liu J,Wang Z,Hao H,et al.Nanopore construction in SiC aerogels for continuous dual-peak electromagnetic wave absorption with full Ku-band coverage[J].Carbon,2024,224:119096.
[47] An Z,Ye C,Zhang R,et al.Flexible and recoverable SiC nanofiber aerogels for electromagnetic wave absorption[J].Ceramics International,2019,45(17):22793-22801.
基金资助
航天材料及工艺研究所重点实验室基金项目(6142906230101)