聚丙烯蜂窝材料的MnOx改性及其甲醛净化性能

杨永忠, 姬文晋, 付琳, 李永峰*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (9) : 232 -236.

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化工新型材料 ›› 2026, Vol. 54 ›› Issue (9) : 232-236. DOI: 10.19817/j.cnki.issn1006-3536.2026.09.031
开发与应用

聚丙烯蜂窝材料的MnOx改性及其甲醛净化性能

    杨永忠, 姬文晋, 付琳, 李永峰*
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MnOx modification of polypropylene honeycomb material and its formaldehyde purification performance

  • Yang Yongzhong, Ji Wenjin, Fu Lin, Li Yongfeng
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摘要

为了高效净化室内空气中甲醛污染物,采用一步还原沉积法,在聚丙烯(PP)蜂窝基体材料表面直接负载锰氧化物(MnOx)活性组分进行改性,制备得到MnOx/PP复合材料。结果表明:该复合材料具有丰富介孔结构,使其比表面积和孔体积相比PP基体分别提高了4倍和9倍;同时在该复合材料表面形成的低结晶度α-MnO2活性层中,存在高比例Mn3+和氧空位,可有效增强甲醛吸附与氧化分解能力,因此该复合材料的甲醛饱和吸附容量显著优于商业锰基材料,具有很好的应用潜力。

Abstract

To effectively purify formaldehyde pollutant among indoor air,a facile one-step reducing deposition method was employed to modify polypropylene (PP) honeycomb substrate material by directly loading manganese oxide (MnOx) active components onto its surface,thereby preparing MnOx/PP composite material.The results showed that the composite material possessed a rich mesoporous structure,leading to the specific surface area and pore volume that were 4 and 9 times higher than that of the PP substrate,respectively.Additionally,the low crystallinity α-MnO2 active layer formed on the surface of the composite material contained the high proportion of Mn3+ and oxygen vacancies,which could greatly enhance the adsorption and oxidative decomposition of formaldehyde.Consequently,the formaldehyde saturated adsorption capacity of this composite material was significantly superior to that of commercial manganese-based materials,indicating good application potential.

关键词

聚丙烯材料 / 锰氧化物 / 甲醛 / 空气净化

Key words

polypropylene material / manganese oxide / formaldehyde / air purification

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聚丙烯蜂窝材料的MnOx改性及其甲醛净化性能[J]. 化工新型材料, 2026, 54(9): 232-236 DOI:10.19817/j.cnki.issn1006-3536.2026.09.031

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基金资助

国家自然科学基金面上项目(22278086)

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