为进一步提升路用水性树脂改性乳化沥青服役性能,促进其在工程实践中的应用,全面调查了路用水性树脂改性乳化沥青材料的材料选配与制备工艺,系统梳理了不同类型水性树脂对乳化沥青路用性能提升效果,揭示了水性树脂对乳化沥青的改性机理。研究表明,当前研究沥青主要选用70#基质沥青,乳化剂主要选用阳离子慢裂型乳化剂;水性树脂主要选用水性环氧树脂(WER),其次为水性聚氨酯(WPU);水性树脂掺量主要集中在5%~20%;掺加水性树脂可提升乳化沥青蒸发残留物的基本性能、力学性能与高温流变性能,其中WER可显著增强其拉伸强度和黏结强度,WPU可赋予材料更优的柔韧性,而WER/WPU复合改性可使材料保持强度的同时兼具柔韧性;水性树脂改性乳化沥青改性机理以物理共混为主,同时伴随化学反应。
To enhance the service performance of waterborne resin-modified emulsified asphalt for road constructions and promote its practical engineering applications,this paper comprehensively investigated the material selection and preparation techniques of waterborne resin-modified emulsified asphalt for road applications.The enhancement effects of different waterborne resins on the road performance of emulsified asphalt were identified,and the modification mechanisms were revealed.It was demonstrated that 70# base asphalt and cationic slow-set emulsifiers were predominantly employed in current research.Among waterborne resins,waterborne epoxy resin (WER) was the most widely used,followed by waterborne polyurethanes (WPU).The dosage of waterborne resin was mainly 5%-20%.The incorporation of waterborne resins enhanced the fundamental properties,mechanical performance,and high-temperature rheology of emulsified asphalt residue.In particular,WER significantly improved tensile and bonding strength,and WPU imparted superior flexibility to the materials.Moreover,composite modification with WER/WPU enabled the material to maintain strength while also achieving good flexibility.The modification mechanism of waterborne resin modified emulsified asphalt was mainly physical blending,accompanied by chemical reaction.
[1] 冯雷,王俊博,李彦伟,等.不同制备工艺对水性树脂改性乳化沥青性能的影响[J].公路,2025,70(7):41-49.
[2] 陈谦,刘思拓,王朝辉,等.生物油-树脂复合调优技术研究进展与性能评价[J].长沙理工大学学报(自然科学版),2024,21(3):79-94.
[3] Fan Z,Wang C,Li Y,et al.State of the art review on fog seal for asphalt pavement:material composition,classification,performance evaluation,and mechanism analysis[J].Progress in Organic Coatings,2024,194:108573.
[4] 王朝辉,陈谦,李彦伟,等.考虑纹理重构的道路养护吸能封层制备调控与功能评价[J].中国公路学报,2024,37(10):1-13.
[5] 陈谦,王朝辉,李彦伟,等.道路养护吸能封层增韧缓力功效评价[J].中国公路学报,2023,36(12):249-262.
[6] 傅豪,王朝辉,刘鲁清,等.路用水性环氧改性乳化沥青组成优化及耐久性能评价[J].材料导报,2023,37(18):282-290.
[7] Wang C,Fan Z,Wang Z,et al.Multi-component waterborne polymer modifiers for road emulsified asphalt:modular design,mechanism of action and performance evaluation[J].Journal of Cleaner Production,2025,513:145740.
[8] 刘侠,郑木莲,曹眉舒,等.水性环氧树脂(WER)-丁苯橡胶(SBR)复合改性乳化沥青韧性性能[J].中国科技论文,2023,18(6):630-636.
[9] 王清洲,梁瑛硕,马小江,等.环氧掺量对水性环氧乳化沥青微观结构及性能影响[J].热固性树脂,2022,37(1):49-54.
[10] 李彦伟,王育聪,冯雷,等.微表处用水性树脂基改性乳化沥青流变性能[J].空军工程大学学报,2024,25(5):19-28.
[11] 肖庆一,范津,陈向伟,等.水性丙烯酸树脂改性乳化沥青性能试验研究[J].热固性树脂,2022,37(6):6-11,22.
[12] Yao X,Tan L,Xu T.Preparation,properties and compound modification mechanism of waterborne epoxy resin/styrene butadiene rubber latex modified emulsified asphalt[J].Construction and Building Materials,2022,318:126178.
[13] Zhang H,Zhang D,Liu F,et al.Investigation of a novel blocked waterborne polyurethane emulsified asphalt mixture for pothole repair:material development,road performance and construction parameters[J].Road Materials and Pavement Design,2025,26(12):3161-3195.
[14] Zhou X,Wang Z,Guo H,et al.Property improvement of epoxy emulsified asphalt modified by waterborne polyurethane in consideration of environmental benefits[J].Case Studies in Construction Materials,2024,21:e03559.
[15] Chen D,Wu H,Chen X,et al.Fabrication of high-performance asphalt mixture using waterborne epoxy-acrylate resin modified emulsified asphalt (WEREA)[J].Polymers,2024,16(19):2743.
[16] Xu L,Li X,Zong Q,et al.Chemical,morphological and rheological investigations of SBR/SBS modified asphalt emulsions with waterborne acrylate and polyurethane[J].Construction and Building Materials,2021,272:121972.
[17] 王鹏,王杰,兰勇,等.水性聚氨酯改性不黏轮乳化沥青制备及其路用性能研究[J].北京化工大学学报(自然科学版),2024,51(6):71-78.
[18] Xu P,Wang Y,Cheng P,et al.Toughness modification of waterborne epoxy emulsified asphalt by waterborne polyurethane elastomer[J].Construction and Building Materials,2023,386:131547.
[19] Meng Y,Lu T,Fang G,et al.Study on modification mechanism and properties of SBR/WER composite modified emulsified asphalt waterproof binder[J].Construction and Building Materials,2025,465:140246.
[20] Li Y,Wang H,Ma Z,et al.Performance optimization design of waterborne epoxy resin emulsified asphalt chip sealer based on RSM methodology[J].Construction and Building Materials,2025,466:140283.
[21] 徐凌,王小兵,李先锐,等.水性乳液对聚合物改性沥青封层性能的影响[J].同济大学学报(自然科学版),2022,50(10):1471-1481.
[22] Fu H,Wang C,Niu L,et al.Composition optimisation and performance evaluation of waterborne epoxy resin emulsified asphalt tack coat binder for pavement[J].International Journal of Pavement Engineering,2022,23(11):4034-4048.
[23] Li P,Ji J,Wang Z,et al.Performance evaluation and equivalent conversion of waterborne epoxy resin emulsified asphalt based on different evaporation methods[J].Journal of Cleaner Production,2022,353:131461.
[24] 刘富强,郭伟东,傅金琳,等.水性环氧树脂-SBR改性生物沥青性能优化研究[J].化工新型材料,2023,51(S2):577-583,587.
[25] 陈谦,王朝辉,周璐,等.中国路用水性环氧材料工作性能研究与应用进展[J].长安大学学报(自然科学版),2022,42(3):26-40.
[26] Cai Y,Yun S,Liu H.The properties of a new fog seal material made from emulsified asphalt modified by composite agents[J].Road Materials and Pavement Design,2024,25(3):439-453.
[27] Peng Y,Miao J,Yu X,et al.The effect of anionic emulsifiers' diversity and manufacturing processes on the stability and mechanical properties of the water-based epoxy-emulsified asphalt[J].Scientific Reports,2024,14(1):22268.
[28] Yang F,Zhou Q,Yang L,et al.Preparation and performance evaluation of waterborne epoxy resin modified emulsified asphalt binder[J].Case Studies in Construction Materials,2024,21:e03548.
[29] He L,Hou Y,Yang F.Study of the properties of waterborne epoxy resin emulsified asphalt and its modification mechanism[J].Journal of Materials in Civil Engineering,2023,35(6):04023145.
[30] Li Y,Huang G,He Y,et al.Effect of waterborne polyurethane on rheological properties of styrene-butadiene rubber emulsified asphalt[J].Journal of Materials in Civil Engineering,2023,35(3):04022470.
[31] 王朝辉,马健云,张志强,等.碎石封层用树脂基改性乳化沥青调控制备及性能[J].材料导报,2025,39(23):251-258.
[32] Zhang Q,Huang T,Wu J,et al.Cohesion performance of tack coat materials between polyurethane mixture and asphalt mixture[J].Journal of Materials in Civil Engineering,2024,36(1):04023534.
[33] Kong L,Su S,Wang Z,et al.Microscale mechanism and key factors of waterborne epoxy resin emulsified asphalt enhancing interlayer bonding performance and shear resistance of bridge deck pavement[J].Construction and Building Materials,2024,419:135570.
[34] Song W,Chen D,Wu H,et al.Preparation and performance characterization of waterborne epoxy resin modified asphalt emulsion for tack coat[J].Journal of Cleaner Production,2024,475:143715.
[35] 冯雷,葛腾旺,李彦伟,等.路用水性环氧树脂改性聚氨酯的制备及性能评价[J].化工新型材料,2025,53(8):217-224,228.
[36] Zhou X,Xu X,Wang Z,et al.Adhesion enhancement of epoxy emulsified asphalt-aggregate interface by waterborne polyurethanes:multi-scale experimental characterization and molecular dynamics insights[J].Construction and Building Materials,2025,487:142107.
[37] Yang F,Yang L,Gong H,et al.Investigating on the composite modification process and pavement performance of emulsified asphalt by styrene-butadiene latex/waterborne epoxy resin[J].Construction and Building Materials,2025,487:142134.
[38] Ai D,Mo R,Wang H,et al.Preparation of waterborne epoxy dispersion and its application in 2K waterborne epoxy coatings[J].Progress in Organic Coatings,2019,136:105258.
[39] Gu Y,Tang B,He L,et al.Compatibility of cured phase-inversion waterborne epoxy resin emulsified asphalt[J].Construction and Building Materials,2019,229:116942.
[40] 张辉.WPU-WER乳化沥青复合冷补料研究[D].西安:长安大学,2021.
[41] 周启伟,凌天清,郝增恒,等.水性环氧树脂-乳化沥青共混物特性分析[J].建筑材料学报,2018,21(3):414-419.
[42] 郑木莲,马赛,王可,等.WER-SBR复合改性活性乳化沥青性能研究[J].硅酸盐通报,2022,41(3):1085-1093.
[43] 李骏,余定洋,李一鹤,等.水性环氧乳化沥青改性特性及机理研究[J].应用化工,2020,49(S1):325-328.
[44] 刘秀芬.聚氨酯-环氧复合乳液改性乳化沥青的制备及性能研究[D].济南:济南大学,2023.
[45] 田书赫.SBR-WPU改性乳化沥青及其半柔性混合料性能研究[D].青岛:青岛理工大学,2024.
[46] 申祖桢.水性环氧复合改性乳化沥青性能及机理研究[D].重庆:重庆交通大学,2023.
[47] 秦龙飞,刘万才.水性环氧树脂对SBR改性乳化沥青老化前后性能的影响[J].新型建筑材料,2023,50(8):25-29.
基金资助
陕西省创新能力支撑计划项目(2022TD-07);太行城乡建设集团有限公司科技项目(KT-2);中央高校基本科研业务费专项资金项目(300102215203)