Rice husk char,a by-product derived from rice husk gasification in the industrial setting,was utilized as the precursor to synthesize magnetic composites (Fe3O4@NRHC) through nitrogen-doping and Fe3O4 loading.The Fe3O4@NRHC exhibited superior electromagnetic wave absorbing performance,with a minimum reflection loss of -54.67dB at a corresponding absorber thickness of 3mm and an effective absorption bandwidth of 2.22GHz.This absorption mechanism could be attributed to multiple factors including the composite's high conductivity,hierarchically porous structure,and multi-polarization relaxation.The hierarchically porous structure facilitated the deeper penetration of electromagnetic waves into the material.The high conductivity and rich interface polarization and dipole polarization greatly enhanced the dielectric loss ability of Fe3O4@NRHC.This study focused on the modification of the electromagnetic parameters of rice husk char via nitrogen doping and Fe3O4 loading,aiming to improve the absorption capacity for electromagnetic waves across various frequency bands.
[1] Wu N N,Hu Q,Wei R B,et al.Review on the electromagnetic interference shielding properties of carbon based materials and their novel composites:recent progress,challenges and prospects[J].Carbon,2021,176:88-105.
[2] Fang J Y,Shang Y S,Chen Z,et al.Rice husk-based hierarchically porous carbon and magnetic particles composites for highly efficient electromagnetic wave attenuation[J].Journal of Materials Chemistry C,2017,5(19):4695-5705.
[3] Wang L,Liu M C,Wang G,et al.An ultralight nitrogen-doped carbon aerogel anchored by Ni-NiO nanoparticles for enhanced microwave adsorption performance[J].Journal of Alloys and Compounds,2019,776:43-51.
[4] Han Y X,Guo H,Qiu H,et al.Multimechanism decoupling for low-frequency microwave absorption hierarchical Fe-doped Co magnetic microchains[J].Advanced Functional Materials,2025:2506803.
[5] Huang L,Li J J,Wang Z J,et al.Microwave absorption enhancement of porous C@CoFe2O4 nanocomposites derived from eggshell membrane[J].Carbon,2019,143:507-516.
[6] Li X,Xu D M,Zhou D,et al.Vertically stacked heterostructures of MXene/rGO films with enhanced gradient impedance for high-performance microwave absorption[J].Carbon,2023,208:374-383.
[7] Ren L G,Wang Y Q,Jia Z R,et al.Controlling the heterogeneous interfaces of Fe3O4/N-doped porous carbon via facile swelling for enhancing the electromagnetic wave absorption[J].Composites Communications,2022,29:101052.
[8] Wu Z H,Meng Z Z,Yao C,et al.Rice husk derived hierarchical porous carbon with lightweight and efficient microwave absorption[J].Materials Chemistry and Physics,2022,275:125246.
[9] Wang Y N,Zhou Z L,Chen M J,et al.From nanoscale to macroscale:engineering biomass derivatives with nitrogen doping for tailoring dielectric properties and electromagnetic absorption[J].Applied Surface Science,2018,439:176-185.
[10] Wang H Y,Zhang Y L,Wang Q Y,et al.Biomass carbon derived from pine nut shells decorated with NiO nanoflakes for enhanced microwave absorption properties[J].RSC Advances,2019,9(16):9126-9135.
[11] Liu L Y,Yang S,Hu H Y,et al.Lightweight and efficient microwave-absorbing materials based on loofah-sponge-derived hierarchically porous carbons[J].ACS Sustainable Chemistry & Engineering,2019,7(1):1228-1238.
[12] Dou Y Y,Zhang X Y,Zhao X B,et al.N,O-doped walnut-Like porous carbon composite microspheres loaded with Fe/Co nanoparticles for adjustable electromagnetic wave absorption[J].Small,2024,20(20):2308585.
[13] Eltouny N A,Ariya P A.Fe3O4 nanoparticles and carboxymethyl cellulose:a green option for the removal of atmospheric benzene,toluene,ethylbenzene,and o-xylene(BTEX)[J].Industrial & Engineering Chemistry Research,2012,51(39):12787-12795.
[14] Wilson D,Langell M A.XPS analysis of oleylamine/oleic acid capped Fe3O4 nanoparticles as a function of temperature[J].Applied Surface Science,2014,303:6-13.
[15] Zhao H Q,Cheng Y,Lv H L,et al.A novel hierarchically porous magnetic carbon derived from biomass for strong lightweight microwave absorption[J].Carbon,2019,142:245-253.
[16] Xiang Z,Song Y M,Xiong J,et al.Enhanced electromagnetic wave absorption of nanoporous Fe3O4@carbon composites derived from metal-organic frameworks[J].Carbon,2019,142:20-31.
[17] 曹雪芳,贾雪菲,贺永亮,等.MOFs衍生的多孔材料Co/C的吸波性能研究[J].化工新型材料,2024,52(2):130-138.
[18] Duan L T,Zhou J T,Yan Y,et al.Electron migratory polarization of interfacial electric fields facilitates efficient microwave absorption[J].Advanced Functional Materials,2025,35(10):2416727.
[19] Huang M Q,Wang L,You W B,et al.Single zinc atoms anchored on MOF-derived N-doped carbon shell cooperated with magnetic core as an ultrawideband microwave absorber[J].Small,2021,17(30):2101416.
[20] Shu X F,Fang B,Wu W J,et al.Acicular or octahedral Fe3O4/rice husk-based activated carbon composites through graphitization synthesis as superior electromagnetic wave absorbers[J].Composites Part A:Applied Science and Manufacturing,2021,151:106635.
[21] Jia Z R,Sun L F,Gao Z G,et al.Modulating magnetic interface layer on porous carbon heterostructures for efficient microwave absorption[J].Nano Research,2024,17(11):10099-10108.
[22] Wu Z C,Pei K,Xing L S,et al.Enhanced microwave absorption performance from magnetic coupling of magnetic nanoparticles suspended within hierarchically tubular composite[J].Advanced Functional Materials,2019,29(28):1901448.
[23] Li X,Xu D M,Zhou D,et al.Magnetic array vertically anchored on flexible carbon cloth with ‘magical angle’ for the increased effective absorption bandwidth and improved reflection loss simultaneously[J].Carbon,2023,210:118046.
基金资助
武汉科技大学煤转化与新型炭材料湖北省重点实验室开放基金项目(WKDM202107)