二维过渡金属硫族化物(TMC)及异质结因其独特的物理化学性质,在光电器件领域展现出巨大潜力。通过表面修饰、插层沉积及可控化学气相沉积(CVD)等方法制备的TMC结构,可以实现其电子能带结构的丰富调控,使其在光学、电学和力学等方面表现出各向异性的物理特性。这些材料结构在光谱检测、光电探测和非线性光学器件等领域具有广泛的应用前景。结合近年来国内外研究现状,综述了高光电转换效率、高灵敏度的二维TMC材料的制备技术,包括构建超薄非层状、不同相态的插层结构和堆垛结构,并展望其在偏振光和非线性光学器件等领域的应用前景。
Two-dimensional transition metal chalcogenides (TMCs) and their heterostructures exhibit tremendous potential in the field of optoelectronic devices due to their unique physicochemical properties.TMC structures prepared through surface modification,intercalation deposition,and controlled chemical vapor deposition (CVD) enable rich tuning of their electronic band structures,resulting in anisotropic physical characteristics in optical,electrical,and mechanical properties.These material structures have broad application prospects in spectral detection,photodetection,and nonlinear optical devices.Combining recent domestic and international research advances,this review summarized the preparation techniques of two-dimensional TMC materials with high photoelectric conversion efficiency and high sensitivity,including the construction of ultrathin non-layered,different phase intercalation,and stacking structures.It further discussed their potential applications in polarized light and nonlinear optical devices.
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基金资助
国家自然科学基金(NSFC.51303131);江苏省省级科研平台资助计划项目(YGKF202012)
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