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摘要
通过一种简便直接的策略来制备高荧光碳量子点(CDs)。该碳量子点以黄花倒水莲叶为碳源,通过一步水热法合成。合成的碳量子点发出明亮的蓝色荧光,在385nm激发下于461nm处有强发射峰。这些碳量子点不仅具有优异的光致发光性能和水溶性,还可作为一种多功能荧光传感器,用于高灵敏度和选择性的Ag+检测探针。此外,该荧光探针的猝灭效率在0~20μmol/L范围内的Ag+浓度呈现良好的线性关系(R2=0.9901),检测限低至0.74μmol/L。该方法适用于实际水样中的检测,回收率为96.3~100.2%,是一个极具发展前景的检测体系。
Abstract
This paper presented a simple and straightforward strategy for the preparation of highly fluorescent carbon quantum dots (CDs).These carbon quantum dots were synthesized by a one-step hydrothermal method using the leaves of polygala fallax hemsl as the carbon source.The synthesized carbon quantum dots emitted bright blue fluorescence and had a strong emission peak at 461nm under 385nm excitation.These carbon quantum dots not only possessed excellent photoluminescence properties and water solubility but could also serve as a multifunctional fluorescent sensor and be used as a probe for the highly sensitive and selective detection of Ag+.In addition,the quenching efficiency of this fluorescent probe exhibited a good linear relationship with the Ag+ concentration in the range of 0~20μmol/L(R2=0.9901),and the detection limit was as low as 0.74μmol/L.This method was applicable to the detection in actual water samples,with a recovery rate of 96.3~100.2%,making it a highly promising detection system.
关键词
黄花倒水莲
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荧光碳点
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水热法
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荧光探针
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Ag+
Key words
polygala fallax hemsl
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fluorescent carbon dots
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hydrothermal
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fluorescent probes
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Ag+
黄花倒水莲碳点的制备及对水中Ag+的光学检测[J].
化工新型材料, 2026, 54(4): 227-231 DOI:10.19817/j.cnki.issn1006-3536.2026.04.033
基金资助
国家重点研发计划项目(2022YFD16003);广西科技重大专项项目(桂科AA22096020);广西植物功能物质与资源持续利用重点实验室项目(FPRU2020-4);桂林师范高等专科学校高层次人才项目(GCC202207)