光固化3D打印技术(SLA)作为一种增材制造技术,因其能够逐层构建具有复杂结构的对象而在多个领域受到关注。光敏树脂作为光固化3D打印的主体材料,其成分组成对器件的性能与应用有着决定性影响。目前,光敏树脂3D打印产品的力学强度、材料性能、使用寿命等还无法满足各行各业多元化发展的要求。将从SLA的基本原理和光敏树脂的组分出发,结合光敏树脂的功能化改性研究,对提高树脂性能的方法进行总结和类比,目的在于提供一个有关光敏树脂材料研究进展的全面视角。最后对光敏树脂的未来研究方向进行展望总结。
Photocuring printing technology (SLA),as an additive manufacturing technology,has attracted attention in many fields because it can build objects with complex structure layer by layer.As the main material of photocuring 3D printing,the composition of photosensitive resin has a decisive impact on the performance and application of devices.At present,the mechanical strength,material properties and service life of photosensitive resin 3D printing products can not meet the requirements of diversified development of all walks of life.In this paper,starting from the basic principle of SLA and the components of photosensitive resin,combined with the functional modification research of photosensitive resins,the methods to improve the performance of resins were summarized and compared in order to provide a comprehensive perspective on the research progress of photosensitive resin materials.Finally,the future research directions of photosensitive resins were prospected and summarized.
[1] Shiwpursad Jasveer,Xue Jianbin.Comparison of different types of 3D printing technologies[J].International journal of Scientific and Research Publications,2018,8(4):1-9.
[2] 刘创纪,徐英杰,黄蓓青,等.高韧性3D打印光敏树脂制备及性能研究[J].印刷与数字媒体技术研究,2024(3):274-282.
[3] Li Y,Ren X,Zhu L,et al.Synthesis and characterization of polyurethane acrylate with bio-oil modification for photo-curing 3D printed flexible structures[J].Polymer,2024,306:127225.
[4] 彭小晋,聂光临,黄玲艳,等.基于光固化3D打印技术的陶瓷快速成形研究进展[J].陶瓷,2024(5):54-58,84.
[5] 张娜,李东兵,聂俊,等.自由基光固化丙烯酸类活性稀释剂研究进展[J].涂料工业,2017,47(7):80-87.
[6] 宋彩雨,王磊,孙明明,等.活性稀释剂对紫外光固化树脂性能的影响[J].化学与黏合,2017,39(2):94-97,111.
[7] Sun X,Chen S,Qu B,et al.Novel photosensitive resin simultaneously with outstanding cryogenic strength and toughness for digital light processing three-dimensional Printing[J].Materials Today Chemistry,2023,27:101301.
[8] 王虎.纳米改性光固化快速成型树脂性能的研究[D].青岛:青岛科技大学,2016.
[9] 白国巨,肖娜,陈兆奇,等.3D打印用紫外光固化光敏树脂的研究进展:组成、增韧改性与可持续发展[J].塑料科技,2025,53(4):177-182.
[10] 韩俊凤,卢双,王正平.光引发剂对自由基型UV固化反应的影响[J].应用科技,2006(4):57-59.
[11] 贾景霞,刘建平,薛俊杰.紫外光固化树脂的研究进展[J].辽宁化工,2018,47(5):434-436.
[12] Cunningham A F,Desobry V,Dietliker K,et al.Recent developments in radical photoinitiator chemistry[J].Chimia,1994,48(9):423-423.
[13] 武青青,沈虎峻,邓明森.可见光引发剂研究进展[J].涂料工业,2020,50(8):71-80.
[14] Zhang B,Li T,Kang Y.Synthesis and characterization of triarylsulfonium salts as novel cationic photoinitiators for UV-photopolymerization[J].Research on Chemical Intermediates,2017,43:6617-6625.
[15] Praveena B A,Lokesh N,Buradi A,et al.A comprehensive review of emerging additive manufacturing (3D printing technology):methods,materials,applications,challenges,trends and future potential[J].Materials Today:Proceedings,2022,52:1309-1313.
[16] 卢依婷,韩蔚瑶,黄宇刚.3D打印光敏树脂材料的着色效果及固化性能研究[J].数字印刷,2022(2):102-109.
[17] Trembecka-Wójciga K,Jankowska M,Tomal W,et al.Advanced 3D printing of graphene oxide nanocomposites:a new initiator system for improved dispersion and mechanical performance[J].European Polymer Journal,2023,198:112403.
[18] Li H,Zuo J,Dong B,et al.Effect of lamellar inorganic fillers on the properties of epoxy emulsion cement mortar[J].International Journal of Concrete Structures and Materials,2020,14:1-11.
[19] Huang W,Luo Q,Zhu Y,et al.Modified rod-shaped calcium carbonate with thiols improving UV-curing 3D printing resin[J].Journal of Applied Polymer Science,2022,139(47):e53185.
[20] 刘莹莹,陈进,宁蕾,等.纳米氧化铝改性3D打印光敏材料的制备及性能研究[J].塑料工业,2021,49(10):18-22,61.
[21] Ryu K H,Kim U S,Kim J H,et al.Impact of optimal silane concentration on the rheological properties and 3D printing performance of Al2O3-acrylate composite slurries[J].Materials,2024,17(22):5541.
[22] 谷明辉,龚培双,郭小锋,等.硅酸铝增强数字光固化光敏树脂制备及工艺参数优化[J].工程塑料应用,2024,52(12):158-164.
[23] 朱丽梅,郭卫卫,王爱玲,等.SiC晶须改性紫外光敏树脂的研究[J].兵器材料科学与工程,2010,33(5):85-87.
[24] 王凤芝,刘秀军,张庆印,等.超细粉ZrO2增韧补强3D打印光敏树脂[J].热固性树脂,2019,34(6):56-60.
[25] Liu Y,Lin Y,Jiao T,et al.Photocurable modification of inorganic fillers and their application in photopolymers for 3D printing[J].Polymer Chemistry,2019,10(46):6350-6359.
[26] 王世崇,陈彦羽,侯阳,等.光固化3D打印改性碳纤维/光敏树脂复合材料的制备与性能调控[J].复合材料学报,2022,39(10):4509-4517.
[27] 宋星,金肖克,祝成炎,等.玻璃纤维/光敏树脂复合材料的3D打印及其力学性能[J].纺织学报,2021,42(1):73-77.
[28] 宁蕾,陈进.纳米二氧化钛增韧补强3D打印光固化树脂[J].塑料工业,2021,49(6):66-70.
[29] Li J,Cui Y,Wu K,et al.Lowering the curing shrinkage of epoxy acrylate-based photosensitive resins through nano-TiO2 particle with surface grafted by thiol-terminated hyperbranched polymer[J].Journal of Applied Polymer Science,2022,139(32):e52750.
[30] Huang L,Wang Y,Wei Z,et al.Synthesis and optimization of a free-radical/cationic hybrid photosensitive UV curable resin using polyurethane acrylate and graphene oxide[J].Polymers,2022,14(10):1959.
[31] 苏少珍,黄丽婕,零平,等.自由基-阳离子混杂固化型3D打印光敏树脂研究[J].工程塑料应用,2021,49(4):40-47.
[32] Zhao X,Jiao H,Du B,et al.Polyurethane acrylate oligomer (PUA) microspheres prepared using the pickering method for reinforcing the mechanical and thermal properties of 3D printing resin[J].Polymers,2023,15(21):4320.
[33] Chen J,Zheng L,Zhou W,et al.Preparation and performance of silicone-modified 3D printing photosensitive materials[J].e-Polymers,2023,23(1):20230110.
[34] 肖本雄.阳离子型高强度3D打印用光敏树脂的改性及性能研究[D].武汉:江汉大学,2021.
[35] Huang L,Wang Y,Wei Z,et al.Synthesis and optimization of a free-radical/cationic hybrid photosensitive UV curable resin using polyurethane acrylate and graphene oxide[J].Polymers,2022,14(10):1959.
[36] 张亚飞,周志祥,申金福,等.聚四氢呋喃丙烯酸酯增韧改性3D打印光敏树脂[J].工程塑料应用,2023,51(5):14-21.
[37] 师锦,李家欣,况子洋,等.丙烯酸酯型3D打印光敏树脂的制备和性能研究[J].上海塑料,2022,50(2):46-50.
[38] 王志军.助剂的环保创新技术和发展[J].涂料工业,2024,54(S1):25-32.
[39] 朱琳,李永霞,任学勇,等.毛竹热解油改性光敏树脂光固化3D打印优化研究[J].木材科学与技术,2024,38(3):49-55.
基金资助
国家自然科学基金青年科学基金项目(51705414);国家自然科学基金(51641105)
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