吸附法在废水处理领域占据重要地位,开发环境友好、成本低廉且吸附效果好的吸附材料是吸附分离技术未来重要的发展方向。汉麻杆作为农业固体废弃物,含有大量的纤维素、半纤维素及木质素,拥有丰富的活性官能团,同时具有天然纳米级孔隙结构,是制备高性能吸附剂理想的生物质材料。综述了近年来国内外以汉麻杆为原料制备吸附材料的化学改性方法、活性原理及特点,总结了汉麻杆基吸附材料在气体吸附、废水处理中的应用,并对其未来的发展方向进行了展望。
Adsorption method plays a vital role in the field of wastewater treatment,and the development of environmentally friendly,low-cost,and effective adsorption materials is an important direction in the future.Hemp stems,as an agricultural solid waste,contain a large amount of cellulose,hemicellulose,lignin,abundant active functional groups,and natural nanoscale pore structure,making them an ideal biomass material for preparing high-performance adsorbents.This article reviewed the chemical modification methods,activating principles,and characteristics of preparing adsorption materials from hemp stems at home and abroad in recent years,summarized their applications in gas adsorption and wastewater treatment,and looked forward to their future development directions.
[1] Upadhyay U,Sreedhar I,Singh S A,et al.Recent advances in heavy metal removal by chitosan based adsorbents[J].Carbohydr Polym,2021,251:1-28.
[2] Jiang Y J,Hu Y Q,Luan B Q,et al.Benchmark single-step ethylene purification from ternary mixtures by a customized fluorinated anion-embedded MOF[J].Nat Commun,2023,14(1):401.
[3] 郝军杰,郭成,高翔鹏,等.甘蔗渣活性炭的制备及应用研究进展[J].现代化工,2021,41(3):31-35.
[4] 温萍,刘圣勇,王炯.乙酸锌改性稻壳生物炭电容及电吸附Cu2+性能[J].精细化工,2023,41(12):23-28.
[5] Arami M,Limaee N Y,Mahmoodi N M,et al.Removal of dyes from colored textile wastewater by orange peel adsorbent:equilibrium and kinetic studies[J].Colloid Interf Sci,2005,288(2):371-376.
[6] Gümückaya E,Usta M,Balaban M.Carbohydrate components and crystalline structure of organosolv hemp (Cannabis sativa L.)bast fibers pulp[J].Bioresource Technology,2007,98(3):491-497.
[7] 张婷,高雅琳,林小云.汉麻杆活性炭的制备及对竹醋液脱色脱臭的研究[J].沈阳大学学报(自然科学版),2012,24(4):10-15.
[8] 王佳,刘建宇,周梦圆.陕甘汉麻秆基活性炭的制备及表征[J].中国麻业科学,2023,45(4):152-159.
[9] 连惠山,朱小平,陈国华.工业大麻杆芯粉对亚甲基蓝染料的吸附性能[J].华侨大学学报,2009,30(4):406-413.
[10] Kyzas G Z,Terzopoulou Z,Nikolaidis V,et al.Low-cost hemp biomaterials for nickel ions removal from aqueous solutions[J].Journal of Molecular Liquids,2015,209(4):209-218.
[11] 许鹏博,何晶,俞娟.高锰酸钾改性汉麻秆芯对亚甲基蓝吸附性能的研究[J].林产化学与工业,2018,38(6):81-87.
[12] Bai Z H,Liu Q,Zhang H S,et al.High efficiend biosorption of uranium(Ⅵ) ions from solution by using hemp fibers functionalized with imidazole-4,5-dicarboxylic[J].Journal of Molecular Liquids,2020,297(8):111-119.
[13] 白子恒.汉麻纤维表面功能化及其铀吸附性能研究[D].哈尔滨:哈尔滨工程大学,2020.
[14] Bai Z H,Liu Q,Zhang H S,et al.A novel 3D reticular anti-fouling bio-adsorbent for uranium extraction from seawater:polyethylenimine and guanidyl functionalizec hemp fibers[J].Chemical Engineering Journal,2020,382:122555.
[15] 谢晓亮,聂小琴,马春彦.胺化大麻纤维的制备及其对铀的高效提取研究[J].西南科技大学学报,2023,38(3):58-69.
[16] 石雨,田媛,李国巍.汉麻秆基活性炭研究进展[J].黑龙江科学,2012,5(7):28-29.
[17] 周梦圆,张洛红,赵鑫.高比表面积汉麻秆活性炭的制备及应用研究现状[J].化学工程师,2022,319(4):66-70.
[18] 葛战勤.磷酸法制备低灰分活性炭的研究[J].河北工业科技,2004,21(6):4-6.
[19] 李慧琴.汉麻杆基活性炭的制备及表征[D].北京:北京化工大学,2007.
[20] 孙金菊,高建民,郝新敏,等.KOH活化法制备汉麻秆活性炭及其微孔结构的研究[J].功能材料,2014,45(21):21136-21139.
[21] 孙晓娟.麻秆基介孔活性炭的制备及对有机染料的吸附性能研究[D].太原:太原理工大学,2022.
[22] 刘振勇.汉麻秆芯基多孔碳的制备及性能研究[D].天津:天津科技大学,2019.
[23] Lupul I,Yperman J,Carleer R,et al.Adsorption of atrazine on hemp stem-based activated carbons with different surface chem istry[J].Adsorption,2015,21(6/7):489-498.
[24] 关中相.汉麻秸秆基生物质碳用于锂离子电池负极及其电化学性能研究[D].长春:吉林大学,2020.
[25] 张骥.改性TiO2负载汉麻杆活性炭光催化降解甲醛机理[D].北京:北京林业大学,2018.
[26] Deng L H,Zhang D H,Kong Z N,et al.Strong immobilization of phosphate in wastewater onto the surface of MgO-modified in dustrial hemp-stem-driven biochar by flowerlike crystallization[J].Industrial & Engineering Chemistry Research,2020,59(33):14578-14586.
[27] Yang R,Liu G Q,Li M,et al.Preparation and N2,CO2 and H2 adsorption of super activated carbon derived from biomass source hemp (Cannabis sativa L.)stem[J].Microporous & Mesoporous Materials,2012,158:108-116.
[28] 于双喜.氮掺杂植物基活性炭材料结构及其吸附性能的研究[D].北京:北京化工大学,2010.
[29] 韩磊,杨儒,刘国强,等.汉麻杆基活性炭表面织构与储氢性能的研究[J].无机化学学报,2009,25(12):2097-2104.
[30] 张华,张建春,张杰.汉麻——一种高值特种生物质资源及应用[J].高分子通报,2011,32(8):1-7.
[31] 张旭,柏广宇,高宝昌.KMnO4改性汉麻废弃物对水体中Pb2+吸附工艺优化研究[J].化学试剂,2021,43(8):1032-1036.
[32] 周文迪.碱预抽提大麻杆芯生物炭制备及对水中重金属铜镍的吸附性能研究[D].昆明:昆明理工大学,2022.
[33] 蒋志茵.汉麻杆活性炭对染料吸附性能的研究[M].北京:北京化工大学,2009.
[34] 李慧琴,杨儒,徐新花,等.麻炭的制备及其微观结构[J].北京化工大学学报(自然科学版),2007,34(5):508-513.
基金资助
黑龙江省自然科学基金资助项目(LH2024B028)