Addressing the issue of performance degradation caused by the agglomerate of nano-SnO2 in ammonia sensors,this study utilized waste bamboo chopsticks as raw material to synthesize a porous bamboo charcoal carrier via hydrothermal treatment followed by high-temperature sintering.Leveraging its vascular bundle structure,the loaded SnO2 nanoparticles could suppress agglomeration,resulting in the fabrication of a flexible bamboo charcoal/SnO2 ammonia sensor.The experimental results demonstrated that the 0.05mol/L bamboo charcoal/SnO2 sensor exhibited a response of 13.82 toward 5×10-6 ammonia at room temperature,with response/recovery times of 37s/23s and a detection limit as low as 0.41×10-6 (S/N≥3).Even under 90% relative humidity,the sensor maintained a response of 5.55 toward 5×10-6 ammonia,demonstrating robust humidity resistance.
[1] Das B,Behera S,Satpati B,et al.Layered SnS2/porous nickel foil based Schottky junction:an excellent ammonia sensor at room temperature[J].Journal of Hazardous Materials,2022,428:128252.
[2] Chang J,Zhu C,Wang Z,et al.A full-set and self-powered ammonia leakage monitor system based on CNTs-PPy and triboelectric nanogenerator for zero-carbon vessels[J].Nano Energy,2022,98:107271.
[3] Freddi S,Perilli D,Vaghi L,et al.Pushing down the limit of NH3 detection of graphene-based chemiresistive sensors through functionalization by thermally activated tetrazoles dimerization[J].ACS Nano,2022,16(7):10456-10469.
[4] Barreca D,Gasparotto A,Gri F,et al.Plasma-assisted growth of β-MnO2 nanosystems as gas sensors for safety and food industry applications[J].Advanced Materials Interfaces,2018,5(23):1800792.
[5] Li Q,Xu M,Jiang C,et al.Highly sensitive graphene-based ammonia sensor enhanced by electrophoretic deposition of MXene[J].Carbon,2023,202:561-570.
[6] Liu Q,Zhao R,Zhan H,et al.Au nanoparticle-modified ZnO/SnO2 heterojunction nanocomposites for highly sensitive detection of NH3[J].Journal of Materials Science:Materials in Electronics,2024,35(9):626.
[7] Zang C,Ma K,Yano Y,et al.SnO2-CuO heterostructured nanofibers for enhanced NH3-gas-sensing performance and potential application in breath analysis[J].IEEE Sensors Journal,2023,23(16):17925-17931.
[8] 陈秀武,马耀通.Sb3+修饰的SnO2/SnS蜂巢状TEA气敏传感器性能研究[J].西北师范大学学报(自然科学版),2021,57(6):45-49;117.
[9] Han Y,Hao S,Liu L,et al.Fabrication of high-performance NH3 flexible sensor based on PANI/SnO2 hollow nanosphere composite[J].Microchimica Acta,2025,192(9):565.
[10] Chen C,Hu L.Nanoscale ion regulation in wood-based structures and their device applications[J].Advanced Materials,2021,33(28):2002890.
[11] Yang C,Wu Q,Xie W,et al.Copper-coordinated cellulose ion conductors for solid-state batteries[J].Nature,2021,598(7882):590-596.
[12] Huang H H,de Silva K K H,Kumara G R A,et al.Structural evolution of hydrothermally derived reduced graphene oxide[J].Scientific Reports,2018,8(1):6849.
[13] Guo M,Wang B,Bian H,et al.Low-temperature ppm-level H2S flexible gas sensor on the basis of ag-modified ZnO[J].Materials Science in Semiconductor Processing,2025,185:108944.
[14] 申来法,张校刚,原长洲,等.SnO2/MWCNTs纳米复合材料的低热固相制备及其超电容特性研究[J].无机化学学报,2009,25(9):1601-1606.
[15] Sun Q,Wu Z,Qin Z,et al.A dog nose-inspired high-perfor-mance NH3 gas sensor of biomass carbon materials with a pleated structure derived from rose tea[J].Journal of Materials Chemistry A,2022,10(27):14326-14335.
[16] Zou Y,Chen S,Sun J,et al.Highly efficient gas sensor using a hollow SnO2 microfiber for triethylamine detection[J].ACS Sensors,2017,2(7):897-902.
[17] Yu H,Li J,Luo W,et al.Hetero-structure La2O3-modified SnO2-Sn3O4 from tin anode slime for highly sensitive and ppb-level formaldehyde detection[J].Applied Surface Science,2020,513:145825.
[18] He T,Liu W,Lv T,et al.MXene/SnO2 heterojunction based chemical gas sensors[J].Sensors and Actuators,B:Chemical,2021,329:129275.
[19] Deng C,Qian X,Lu M,等.CO oxidation and NO reduction by CO over Sn4+ doped CeO2 catalysts:determination of active sites as well as commonness and differences[J].Applied Catalysis B:Environment and Energy,2023,333:122791.
[20] Shi N,Yan H,Wang X,et al.A flexible and wearable PET-based chemiresistive H2S gas sensor modified with MoS2-AgCl@AgNPs nanocomposite for the dynamic monitoring of egg spoilage[J].Analytica Chimica Acta,2023,1279:341836.
[21] Kang W,Pei X,Rusinek C A,et al.Determination of lead with a copper-based electrochemical sensor[J].Analytical Chemistry,2017,89(6):3345-3352.
[22] Zhou T,Zhang T.Recent progress of nanostructured sensing materials from 0D to 3D:overview of structure-property-application relationship for gas sensors[J].Small Methods,2021,5(9):2100515.
[23] Chang X,Li K,Qiao X,et al.ZIF-8 derived ZnO polyhedrons decorated with biomass derived nitrogen-doped porous carbon for enhanced acetone sensing[J].Sensors and Actuators,B:Chemical,2021,330:129366.
基金资助
甘肃省市场监督管理局科技计划资助项目“汽车罐车防波板风险评价及检验方法研究”(SSCJG-J202302)