锂离子电池用二硫化锡基负极材料研究进展

张竟博, 张龙华, 何玉, 刘伟*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 20 -26.

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化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 20-26. DOI: 10.19817/j.cnki.issn1006-3536.2026.01.033
综述与专论

锂离子电池用二硫化锡基负极材料研究进展

    张竟博, 张龙华, 何玉, 刘伟*
作者信息 +

Research progress on tin disulfide-based anode materials for lithium-ion batteries

  • Zhang Jingbo, Zhang Longhua, He Yu, Liu Wei
Author information +
文章历史 +
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摘要

在当今社会,锂离子电池作为主导的能量存储手段,彰显出众多卓越特性。SnS2作为一种层状结构的金属硫化物,凭借其宽广的能带隙、高度稳定以及地壳中丰富的蕴藏量,成为了锂离子电池负极材料的热门候选。然而,纯态的二硫化锡面临着导电性能欠佳以及在充放电循环中体积显著膨胀的难题,这些问题严重制约了其可逆容量和容量保持率。为应对这些挑战,复合化与纳米化技术应运而生,成为行之有效的解决方案。着重介绍了近年来围绕SnS2纳米结构设计为核心的研究成果,以及其与碳材料复合和多金属硫化物复合等复合材料的形貌特征、比容量、循环稳定性等。这些复合材料不仅展现出了更为出色的电化学性能,还为锂离子电池技术的未来发展开辟了新的可能路径。

Abstract

In contemporary society,lithium-ion batteries (LIBs) have emerged as the leading means of energy storage,showcasing numerous exceptional characteristics.SnS2,as a layered metal sulfide,has become a prominent candidate for LIB anode materials due to its wide bandgap,high stability,and abundant reserves in the Earth's crust.However,pure SnS2 faces challenges such as poor electrical conductivity and significant volume expansion during charging and discharging cycles,which severely limit its reversible capacity and capacity retention.To address these challenges,compositing and nanotechnology have emerged as effective solutions.This paper highlighted the recent research achievements centered on the nanostructural design of SnS2,as well as the morphological characteristics,specific capacity,and cycle stability of composite materials,including those combined with carbon materials and multi-metal sulfides.These composite materials not only exhibited superior electrochemical performance but also paved the way for new possibilities in the future development of lithium-ion battery technology.

关键词

锂离子电池 / 负极材料 / 二硫化锡 / 电化学性能

Key words

lithium-ion battery / anode material / SnS2 / electrochemical performance

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锂离子电池用二硫化锡基负极材料研究进展[J]. 化工新型材料, 2026, 54(1): 20-26 DOI:10.19817/j.cnki.issn1006-3536.2026.01.033

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基金资助

河南省科技攻关计划项目(222103810038);河南省高等学校重点科研项目(24B430007)

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