铋系光电半导体材料拥有独特的带隙结构、优异的热稳定性、高载流子迁移率和强氧化能力,在海洋制氢中展现出巨大潜力。开发新型环保高效的铋系光电半导体,不仅有助于海洋资源的合理利用,也对保护海洋环境和实现可持续发展至关重要。综述了铋系光电半导体材料在海洋光降解制氢中的最新进展,分析了其优势与面临的挑战,并展望其在未来海洋工程中的应用前景。
Bismuth-based photoelectrochemical semiconductors,with unique band gap structures,high thermal stability,superior carrier mobility,and strong oxidative capability,show significant potential for marine hydrogen production.The development of efficient and environmentally friendly bismuth-based semiconductors is essential for the rational utilization of marine resources,environmental protection,and achieving sustainable development.This review examined recent advancements in bismuth-based photoelectrochemical materials for marine photocatalytic hydrogen production,evaluated their advantages and challenges,and discussed their future prospects in marine engineering applications.
[1] Bie C,Wang L,Yu J.Challenges for photocatalytic overall water splitting[J].Chemistry,2022,8(6):1567-1574.
[2] Qian Q,Zhu Y,Nazir A,et al.Recent advancements in electrochemical hydrogen production via hybrid water splitting[J].Advanced Materials,2024,36(4):2306108.1-2306108.37.
[3] Finegold L,Cude J L.Biological sciences:one and two-dimensional structure of alpha-helix and beta-sheet forms of poly(L-alanine) shown by specific heat measurements at low temperatures (1.5～20K)[J].Nature.1972,238:38-40.
[4] Di J,Xia J,Li H.Bismuth oxyhalide layered materials for energy and environmental applications[J].Nano Energy,2017,41:172-192.
[5] Wang S,Wang L,Huang W.Bismuth-based photocatalysts for solar energy conversion[J].Journal of Materials Chemistry A,2020,8(46):24307-24352.
[6] Wu X,Te C Y,Su C.Preparation of Bi-based photocatalysts in the form of powdered particles and thin films:a review[J].Journal of Materials Chemistry A,2020,8(31):15302-15318.
[7] Yang Y,Zhang C,Lai C,et al.BiOX(X=Cl,Br,I) photocatalytic nanomaterials:applications for fuels and environmental management[J].Advances in Colloid and Interface Science,2018,254:76-93.
[8] Li S G,Zhao L,Liu J,et al.Up-conversion luminescence and Bi SPR effect promoted Z-scheme BiVO4(040)-Bi-(NaYF4∶Er,Yb,Tm@BiOBr)/Bi photocatalyst for efficient photocatalytic hydrogen production with simultaneous degradation of malachite green[J].International Journal of Hydrogen Energy,2024,84(9):739-758.
[9] Walsh A,Payne D J,Egdell R G.Stereochemistry of post-transition metal oxides:revision of the classical lone pair model[J].Chemical Society Reviews,2011,40(9):4455-4463.
[10] Kim M W,Joshi B,Samuel E,et al.Highly nanotextured β-Bi2O3 pillars by electrostatic spray deposition as photoanodes for solar water splitting[J].Journal of Alloys and Compounds,2018,764:881-889.
[11] Shang J,Hao W,Lv X,et al.Bismuth oxybromide with reasonable photocatalytic reduction activity under visible light[J].ACS Catalysis,2014,4:954-961.
[12] Walsh A,Payne D J,Egdell R G,et al.Stereochemistry of post-transition metal oxides:revision of the classical lone pair model[J].Chemical Society Reviews,2011,40(9):4455-4463.
[13] Li F,Dong B,Feng S.Bi shell-BiOI core microspheres modified TiO2 nanotube arrays photoanode:improved effect of Bi shell on photoelectrochemical hydrogen evolution in seawater[J].International Journal of Hydrogen Energy,2019,44(57):29986-29999.
[14] Tahir M B,Nawaz T,Sagir M,et al.Functionalized role of highly porous activated carbon in bismuth vanadate nanomaterials for boosted photocatalytic hydrogen evolution and synchronous activity in water[J].International Journal of Hydrogen Energy,2021,46(80):39778-39785.
[15] Li J,Yu Y,Zhang L.Bismuth oxyhalide nanomaterials:layered structures meet photocatalysis[J].Nanoscale,2014,6(15):8473-8488.
[16] Yang J,Jiang P,Yue M,et al.Bi2Ga4O9:an undoped single-phase photocatalyst for overall water splitting under visible light[J].Catalysts,2017,345:236-244.
[17] Yang Y,Kang L,Li H.Enhancement of photocatalytic hydrogen production of BiFeO3 by Gd3+ doping[J].Ceramic International,2019,45(6):8017-8022.
[18] Cheng H,Huang B,Dai Y.Engineering BiOX (X=Cl,Br,I) nanostructures for highly efficient photocatalytic applications[J].Nanoscale,2014,6(4):2009-2026.
[19] Ye L,Su Y,Jin X,et al.Recent advances in BiOX(X=Cl,Br and I) photocatalysts:synthesis,modification,facet effects and mechanisms[J].Environmental Science:Nano,2014,1(2):90.
[20] Ye L,Tian L,Peng T,et al.Synthesis of highly symmetrical BiOI single-crystal nanosheets and their {001} facet-dependent photoactivity[J].Journal of Materials Chemistry,2011,21:12479-12484.
[21] Li J,Li H,Zhan G,et al.Zhang L Z.Solar water splitting and nitrogen fixation with layered bismuth oxyhalides[J].Accounts of Chemical Research,2017,50:112-121.
[22] Nishikubo R,Saeki A.Solution-processed Bi2S3 photoresistor film to mitigate a trade-off between morphology and electronic properties[J].Journal of Physical Chemistry Letters,2018,9(18):5392-5399.
[23] Lu R,Li M,Lei J,et al.Template-free synthesis of BiVO4 nanostructures:Ⅱ.relationship between various microstructures for monoclinic BiVO4 and their photocatalytic activity for the degradation of rhodamine B under visible light[J].Nanotechnology,2009,20(40):405602-405609.
[24] Wang C,Hu C,Chen F,et al.Polar layered bismuth-rich oxyhalide piezoelectrics Bi4O5X2(X-Br,I):efficient piezocatalytic pure water splitting and interlayer anion-dependent activity[J].Advanced Functional Materials,2023,33(29):2301144.
[25] Lu X,Wang W Z,Wang M,et al.Visible light responsive bismuth niobate photocatalyst:enhanced contaminant degradation and hydrogen generation[J].Journal of Materials Chemistry,2010,20(38):8405-8410.
[26] Murugesan S,Subramanian V R.Robust synthesis of bismuth titanate pyrochlore nanorods and their photocatalytic applications[J].Chemical Communications,2009(34):5109-5111.
[27] García-Pérez U M,Martínez-de la Cruz A,Sepúlveda-Guzmán S,et al.Low-temperature synthesis of BiVO4 powders by pluronic-assisted hydrothermal method:effect of the surfactant and temperature on the morphology and structural control[J].Ceramics International,2014,40(3):4631-4638.
[28] Xia Y,Yang D,Zhu X,et al.Microstructure and photocatalytic performance study of visible-light-responsive two-dimensional Bi2MoO6 nanosheets[J].Materials Letters,2024,357:135630.
[29] Das P K,Arunachalam M,Seo Y J,et al.Electrolyte effects on undoped and Mo-doped BiVO4 film for photoelectrochemical water splitting[J].Journal of Electroanalytical Chemistry,2019,842:41-49.
[30] Jovalekic C,Zdujic M,Poleti D,et al.Structural and electrical properties of the 2Bi2O3·3ZrO2 system[J].Journal of Solid State Chemistry,2008,181(6):1321-1329.
[31] Li X,Jun L,Xiao J,et al.Study on the relationship between Bi2S3 with different morphologies and its photocatalytic hydrogen production performance[J].Journal of Analytical Science & Technology,2022,13:19.
[32] Chang C J,Chen Y C,Tsai Z T.Effect of calcination induced phase transition on the photocatalytic hydrogen production activity of BiOI and Bi5O7I based photocatalysts[J].International Journal of Hydrogen Energy,2022,49(96):40777-40786.
[33] Ge L.Novel Pd/BiVO4 composite photocatalysts for efficient degradation of methyl orange under visible light irradiation[J].Materials Chemistry and Physics,2008,107:465-470.
[34] Ye L,Jin X,Leng Y,et al.Synthesis of black ultrathin BiOCl nanosheets for efficient photocatalytic H2 production under visible light irradiation[J].Journal of Power Sources 2015,293:409-415.
[35] Liu X G,Chen W J,Zhang X.Bimetallic Pd-Bi nanocatalysts derived from NaBH4 reduction of BiOCl and Pd2+ and exhibit highly efficient hydrogen production over formaldehyde solution[J].International Journal of Hydrogen Energy,2022,47:32425-32435.
[36] Wang X,Zhu J,Fu X,et al.Boosted visible-light photocatalytic performance of Au/BiOCl/BiOI by high-speed spatial electron transfer channel[J].Journal of Alloys and Compounds,2022(890):161736.
[37] Yu C L,Cao F F,Li G,et al.Novel noble metal (Rh,Pd,Pt)/BiOX(Cl,Br,I) composite photocatalysts with enhanced photocatalytic performance in dye degradation[J].Separation and Purification Technology,2013,120:110-122.
[38] Zhao L,Fang W,Meng X,et al.In-situ synthesis of metal Bi to improve the stability of oxygen vacancies and enhance the photocatalytic activity of Bi4O5Br2 in H2 evolution.Journal of Alloys and Compounds,2022,910:164883.
[39] Mumtaz F,Jabbar H,Khan M Z,et al.Optimization of Z-scheme Bi0.5Na0.5TiO3/RGO-Co3O4 composite catalyst for water splitting reaction through piezo-photocatalysis[J].International Journal of Hydrogen Energy,2024,78(8):1468-1480.
[40] Ding D,Zhuo J,Dong J,et al.Bi2O2Se as a novel co-catalyst for photocatalytic hydrogen evolution reaction[J].Chemical Engineering Journal,2020,400:125931.
[41] Bai Y,Chen T,Wang P,et al.Bismuth-rich Bi4O5X2 (X=Br,and I) nanosheets with dominant {101} facets exposure for photocatalytic H2 evolution[J].Chemical Engineering Journal,2016,304:454-460.
[42] You Y,Wang S,Xiao K.Z-Scheme g-C3N4/Bi4NbO8Cl heterojunction for enhanced photocatalytic hydrogen production[J].ACS Sustainable Chemistry & Engineering,2018,6(12):16219-16227.
基金资助
陕西省教育厅自然科学专项项目(21JK0804)
PDF
