聚集诱导发光材料及其在荧光纤维中的应用

管舒逸1, 马海燕1,2*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 241 -247.

PDF
化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 241-247. DOI: 10.19817/j.cnki.issn1006-3536.2026.01.024
开发与应用

聚集诱导发光材料及其在荧光纤维中的应用

    管舒逸1, 马海燕1,2*
作者信息 +

Aggregation-induced emission (AIE) materials and their applications in fluorescent fibers

  • Guan Shuyi1, Ma Haiyan1,2
Author information +
文章历史 +
PDF

摘要

集诱导发光(AIE)材料具有聚集或固态下能显著增强发光效率、光稳定性好、高活性氧(ROS)产率和良好的生物相容性等优点,将AIE材料引入荧光纤维解决了传统荧光淬灭问题,同时又促进荧光纤维应用从单一功能向多功能领域发展。从AIE材料和应用两个方面综述其研究进展和成果,简要介绍常见的AIE材料及AIE荧光纤维的制备技术,重点介绍了AIE荧光纤维在生物医学、智能传感与穿戴及能源和环境领域的应用进展,最后对其未来发展进行展望,以期AIE荧光纤维取得更多创新应用和突破性的研究成果。

Abstract

Aggregation-Induced Emission (AIE) materials have the advantages of significantly enhanced luminescence efficiency,good light stability,high reactive oxygen species (ROS) yield,and good biocompatibility in aggregation or solid state.The introduction of AIE materials into fluorescent fibers has solved the problem of traditional fluorescence quenching while simultaneously advancing the application of fluorescent fibers from a single function to a multi-functional field.The research progress and achievements of AIE materials and their applications were reviewed.The common AIE materials and the preparation technology of AIE fluorescent fibers were briefly summarized,and then the application progress of AIE fluorescent fibers applied in biomedicine,intelligent sensing and wearable devices,energy and environment fields was mainly introduced.Finally,the future development directions of AIE fluorescent fibers were prospected in order to obtain more innovative applications and breakthrough research results of AIE fluorescent fibers.

关键词

聚集诱导发光材料 / 荧光纤维 / 制备技术 / 生物医学 / 智能 / 能源环境

Key words

aggregation-induced emission materials / fluorescent fiber / preparation technology / biomedicine / intelligent / energy environment

引用本文

引用格式 ▾
聚集诱导发光材料及其在荧光纤维中的应用[J]. 化工新型材料, 2026, 54(1): 241-247 DOI:10.19817/j.cnki.issn1006-3536.2026.01.024

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 张明星.辐射改性制备荧光聚乙烯/聚丙烯无纺布及其应用研究[D].上海:中国科学院上海应用物理研究所,2021.
[2] Luo J D,Xie Z L,Lam J W Y,et al.Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole[J].Chemical Communications,2001(18):1740-1741.
[3] Hu Q L,Gao M,Feng G X,et al.Mitochondria-targeted cancer therapy using a light-up probe with aggregation-induced-emission characteristics[J].Angewandte Chemie International Edition,2014,53(51):14225-14229.
[4] Chen S J,Wang H,Hong Y N,et al.Fabrication of fluorescent nanoparticles based on AIE luminogens (AIE dots) and their applications in bioimaging[J].Materials Horizons,2016,3(4):283-293.
[5] Kang M M,Zhang Z J,Song N,et al.Aggregation-enhanced theranostics:AIE sparkles in biomedical field[J].Aggregate,2020,1(1):80-106.
[6] Mei J,Huang Y H,Tian H.Progress and trends in AIE-based bioprobes:a brief overview[J].ACS Applied Materials & Interfaces,2018,10(15):12217-12261.
[7] Dalapati S,Gu C,Jiang D L.Luminescent porous polymers based on aggregation-induced mechanism:design,synthesis and functions[J].Small,2016,12(47):6513-6527.
[8] Zhao W J,He Z K,Peng Q,et al.Highly sensitive switching of solid-state luminescence by controlling intersystem crossing[J].Nature Communications,2018,9(1):3044.
[9] Asad M,Imran Anwar M,Abbas A,et al.AIE based luminescent porous materials as cutting-edge tool for environmental monitoring:state of the art advances and perspectives[J].Coordination Chemistry Reviews,2022,463:214539.
[10] 王蓉.荧光纤维的制备及其性能研究[D].上海:东华大学,2015.
[11] 丁文凤.柔性可穿戴纤维制备及其性能研究[D].杭州:浙江理工大学,2020.
[12] 陈超.发光Lyocell纤维的制备及结构与性能的研究[D].上海:东华大学,2013.
[13] 李曼丽,季志浩,龙柱,等.壳聚糖荧光防伪印花涂料的制备及其应用性能[J].纺织学报,2024,45(3):114-121.
[14] Bauri K,Saha B,Banerjee A,et al.Recent advances in the development and applications of nonconventional luminescent polymers[J].Polymer Chemistry,2020,11(46):7293-7315.
[15] 张大伟,王从焕,吕素芳,等.噻咯及其衍生物的合成及性能研究进展[J].有机硅材料,2019,33(4):310-316.
[16] Zhao Z J,Wang Z M,Lu P,et al.Structural modulation of solid-state emission of 2,5-bis(trialkylsilylethynyl)-3,4-diphenylsiloles[J].Angewandte Chemie International Edition,2009,48(41):7608-7611.
[17] 全昌云.基于噻咯衍生物的聚集诱导发光材料的设计、合成与应用[D].广州:华南理工大学,2016.
[18] Hong Y N,Lam J W Y,Tang B Z.Aggregation-induced emission:phenomenon,mechanism and applications[J].Chemical Communications,2009(29):4332-4353.
[19] 娄丹丹.四苯乙烯类荧光染料的构象调节研究[D].济南:山东大学,2019.
[20] Xiang X S,Zhou Z K,Feng H J,et al.Fine tuning of the electronic properties of novel BTPE using oligosilanyl linkages and their application in rapid high-resolution visualization of latent fingerprints[J].CCS Chemistry,2020,2(3):329-336.
[21] 张扬.含非典型性生色团AIE聚合物的合成及光学性能研究[D].兰州:西北师范大学,2017.
[22] Zhao J X,Zhou M J,Zhou Y,et al.Multi-stimuli-responsive color/fluorescence dual-switching behavior of a hyperbranched polyamidoamine bearing viologen and adamantane units[J].European Polymer Journal,2022,176:111404.
[23] Shao L H,Wan K W,Wang H,et al.A non-conjugated polyethylenimine copolymer-based unorthodox nanoprobe for bioimaging and related mechanism exploration[J].Biomaterials Science,2019,7(7):3016-3024.
[24] Wu D C,Liu Y,He C B,et al.Blue photoluminescence from hyperbranched poly(amino ester)s[J].macromolecules,2005,38(24):9906-9909.
[25] Yuan L Y,Yan H X,Bai L H,et al.Unprecedented multicolor photoluminescence from hyperbranched poly(amino ester)s[J].Macromolecular Rapid Communications,2019,40(17):1800658.
[26] Niu S,Yan H X,Chen Z Y,et al.Water-soluble blue fluorescence-emitting hyperbranched polysiloxanes simultaneously containing hydroxyl and primary amine groups[J].Macromolecular Rapid Communications,2016,37(2):136-142.
[27] 白利华.AIE超支化聚硅氧烷的功能化及荧光机理研究[D].西安:西北工业大学,2020.
[28] 白天,颜红侠,牛松,等.AIE聚硅氧烷的结构与发光性能研究[J].高分子通报,2019(10):1-9.
[29] Boominathan M,Sathish V,Nagaraj M,et al.Aggregation induced emission characteristics of maleimide derivatives[J].RSC Advances,2013,3(44):22246-22252.
[30] Shang C,Wei N,Zhuo H M,et al.Highly emissive poly(maleic anhydride-alt-vinyl pyrrolidone) with molecular weight-dependent and excitation-dependent fluorescence[J].Journal of Materials Chemistry C,2017,5(32):8082-8090.
[31] 张慧茹,黄素萍,龚静华,等.荧光纤维的结构与性能[J].上海纺织科技,2003(2):13-15,13.
[32] 薛伟.有机聚合物复合荧光纤维及其传感性能研究[D].南京:南京邮电大学,2020.
[33] Jiang Y M,Cheng Y H,Liu S J,et al.Solid-state intramolecular motions in continuous fibers driven by ambient humidity for fluorescent sensors[J].National Science Review,2021,8(4):nwaa135.
[34] Lu H W,Zou L M,Xu Y J,et al.Preparation and study of poly vinyl alcohol/hyperbranched polylysine fluorescence fibers via wet spinning[J].Materials Research Express,2018,5(2):025102.
[35] Rodrigues B V M,Cabral T S,Sgobbi L F,et al.A simple and green method for the production of nanostructured materials from poly(vinyl alcohol)/graphene quantum dots[J].Materials Chemistry and Physics,2018,219:242-250.
[36] Jiang Q,Yuan H L,Dong K,et al.Continuous and scalable manufacture of aggregation induced emission luminogen fibers for anti-counterfeiting and hazardous gas detecting smart textiles[J].Materials & Design,2021,205:109761.
[37] Xu J R,Ji W X,Li C,et al.Reversible thermal-induced fluorescence color change of tetraphenylethylene-labeled nylon-6[J].Advanced Optical Materials,2018,6(6):1701149.
[38] Zhao L,Chen Y F,Yuan J,et al.Electrospun fibrous mats with conjugated tetraphenylethylene and mannose for sensitive turn-on fluorescent sensing of escherichia coli[J].ACS Applied Materials & Interfaces,2015,7(9):5177-5186.
[39] Liu F K,Cui M X,Ma J J,et al.An optical fiber taper fluorescent probe for detection of nitro-explosives based on tetraphenylethylene with aggregation-induced emission[J].Optical Fiber Technology,2017,36:98-104.
[40] Chen Z J,Liu W P,Zhao L,et al.Acid-Labile degradation of injectable fiber fragments to release bioreducible micelles for targeted cancer therapy[J].Biomacromolecules,2018,19(4):1100-1110.
[41] Zhao L,Xie S Z,Liu Y,et al.Janus micromotors for motion-capture-lighting of bacteria[J].Nanoscale,2019,11(38):17831-17840.
[42] Dong R H,Li Y,Chen M,et al.In situ electrospinning of aggregation-induced emission nanofibrous dressing for wound healing[J].Small Methods,2022,6(5):2101247.
[43] Zhao L,Zhang Z L,Liu Y,et al.Fibrous strips decorated with cleavable aggregation-induced emission probes for visual detection of Hg2+[J].Journal of Hazardous materials,2020,385:121556.
[44] Zhang Y J,Li S H,Pan G X,et al.Stretchable nanofibrous membranes for colorimetric/fluorometric HCl sensing:highly sensitive charge-transfer excited state[J].Sensors and Actuators B:Chemical,2018,254:785-794.
[45] Cheng Y H,Wang J G,Qiu Z J,et al.Multiscale humidity visualization by environmentally sensitive fluorescent molecular rotors[J].Advanced Materials,2017,29(46):1703900.
[46] Liu P C,Chu C S Z,Qiu W Q,et al.3D/4D printed versatile fibre-based wearables for embroidery,AIE-chemosensing,and unidirectional draining[J].Aggregate,2024,5(3):e521.
[47] Ding W F,Sun J M,Chen G Y,et al.Stretchable multi-luminescent fibers with AIEgens[J].Journal of Materials Chemistry C,2019,7(35):10769-10776.
[48] Li H X,Wen H F,Zhang Z J,et al.Reverse thinking of the aggregation-induced emission principle:amplifying molecular motions to boost photothermal efficiency of nanofibers[J].Angewandte Chemie International Edition,2020,59(46):20371-20375.
[49] Lin J H,Feng X,Huang J T,et al.Flexible AIE/PCM composite fiber with biosensing of alcohol,fluorescent anti-counterfeiting and body thermal management functions[J].Biosensors and Bioelectronics,2025,267:116799.
AI Summary AI Mindmap
PDF

235

访问

0

被引

导航
相关文章

AI思维导图

/