碳纤维及其复合材料在导热领域的研究进展

林安琪1,2, 申知朋1,2, 张晓晓1,2, 李汝哲1,2, 张永刚2, 郝梦圆2*

化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 33 -38.

PDF
化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 33-38. DOI: 10.19817/j.cnki.issn1006-3536.2026.01.016
综述与专论

碳纤维及其复合材料在导热领域的研究进展

    林安琪1,2, 申知朋1,2, 张晓晓1,2, 李汝哲1,2, 张永刚2, 郝梦圆2*
作者信息 +

Research progress of carbon fibers and their composites in thermal conductivity

  • Lin Anqi1,2, Shen Zhipeng1,2, Zhang Xiaoxiao1,2, Li Ruzhe1,2, Zhang Yonggang2, Hao Mengyuan2
Author information +
文章历史 +
PDF

摘要

碳纤维因其沿纤维轴高度取向的石墨结构,在导热领域展现了广阔的应用前景和发展潜力,不仅能够有效地传导热量,还具备轻质、高强度、高模量、低热膨胀系数等优点,被广泛应用于航空航天、军事装备、机械设备、微电子等工业领域。主要概括了碳纤维的导热机理,介绍了中间相沥青基碳纤维、聚丙烯腈基碳纤维、聚酰亚胺基碳纤维的研究进展,探讨了导热碳纤维复合材料的导热性能和导热差异,并展望了导热碳纤维面临的挑战与发展趋势。

Abstract

Carbon fibers have shown broad application prospects and development potential in the field of thermal conductivity due to their highly oriented graphite structure along the fiber axis.Carbon fibers not only exhibit excellent thermal conductivity but also possess advantages such as lightweight,high strength,high modulus,and a low thermal expansion coefficient.These properties make them widely applicable in various industrial fields including aerospace,military equipment,mechanical engineering,and microelectronics.The thermal conductivity mechanisms of carbon fibers were summarized.Moreover,the research progress on mesophase pitch-based carbon fibers,polyacrylonitrile-based carbon fibers and polyimide-carbon fibers were introduced.The discussion delved into the thermal conductivity characteristics and the variations in thermal conductivity within carbon fiber composites.Furthermore,the challenges and development trends of heat-conductive carbon fibers were prospected.

关键词

碳纤维 / 导热 / 复合材料 / 前驱体

Key words

carbon fiber / thermal conductivity / composites / precursor

引用本文

引用格式 ▾
碳纤维及其复合材料在导热领域的研究进展[J]. 化工新型材料, 2026, 54(1): 33-38 DOI:10.19817/j.cnki.issn1006-3536.2026.01.016

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Han W H,Wang Q Y,Long Y,et al.Personalized customization of in-plane thermal conductive networks by a novel electrospinning method[J].Composites Part B:Engineering,2025,290:111971.
[2] 李伟斌,焦蓬,殷志敏.柔性导热材料研究进展[J].化工新型材料,2021,49(S1):35-38.
[3] Duan Y S,Yu H T,Zhang F,et al.Preparation technologies for polymer composites with high-directional thermal conductivity:a review[J].Nano Research,2024,17(11):9796-9814.
[4] Wang J Q,Hu L,Li W H,et al.Development and perspectives of thermal conductive polymer composites[J].Nanomaterials-Basel,2022,12(20):3574.
[5] Zhu P,Wang P P,Shao P Z,et al.Research progress in interface modification and thermal conduction behavior of diamond/metal composites[J].International Journal of Minerals,Metallurgy and Materials,2022,29(2):200-211.
[6] He J B,Song M S,Chen K Y,et al.Polymer-derived ceramics technology:characteristics,procedure,product structures,and properties,and development of the technology in high-entropy ceramics[J].Crystals,2022,12(9):1292.
[7] Yu B K,Zhou Y H,Luo Z A,et al.Highly thermally conductive flexible insulated PI/BNNS@rGO nanocomposite paper with a three-dimensional network bridge structure[J].Applied Surface Science,2023,630:157457.
[8] Wang J Y,Wang G Y.Nanocarbon-based hybrid fillers in thermally conductive polymer composites:a review[J].Advanced Engineering Materials,2024,26(10):2301983.
[9] Sun W,Wang L D,Yang Z Q,et al.Tuning the oxidation degree of graphite toward highly thermally conductive graphite/epoxy composites[J].Chemistry of Materials Journal,2018,30(21):7473-7483.
[10] Zhan C,Cui W Z,Li L J,et al.Dual-Aligned carbon nanofiber scaffolds as heat conduction path to enhance thermal conductivity of polymer composites[J].Composites Science and Technology,2023,231:109823.
[11] Yang G,Yi H K,Yao Y G,et al.Thermally conductive graphene films for heat dissipation[J].ACS Applied Nano Materials Journal,2020,3(3):2149-2155.
[12] Wu X F,Tang B,Chen J,et al.Epoxy composites with high cross-plane thermal conductivity by constructing all-carbon multidimensional carbon fiber/graphite networks[J].Composites Science and Technology,2021,203:108610.
[13] Lu Q Y,Rizwan-Uddin.A finite element approach for nonlinear,transient heat conduction problems with convection,radiation or contact boundary conditions[J].Annals of Nuclear Energy,2023,193:110009.
[14] Ren W J,Lu S,Yu C Q,et al.Carbon honeycomb structure with high axial thermal transport and strong robustness[J].Rare Metals,2023,42(8):2679-2687.
[15] 谢世红,高洁,宁来元,等.碳纤维/聚合物复合材料热导率近十年研究进展[J].复合材料学报,2024,41(2):561-571.
[16] 张倩玉,李伏虎,金芮昕.沥青基碳纤维的制备与应用研究进展[J].化工新型材料,2023,51(S2):565-568.
[17] Shi K,Lai Y,Li C F,et al.Improving the spinnability of mesophase pitch and its carbon fiber performance by modifying toluene solubles content in the precursor[J].Journal of Materials Science,2024,59(40):19319-19336.
[18] Xu H T,Guo J G,Li W L,et al.The effect of the molecular structure of naphthalene-based mesophase pitch on the properties of carbon fibers derived from it[J].New Carbon Materials,2023,38(2):369-377.
[19] Guo J G,Li X K,Xu H T,et al.Molecular structure control in mesophase pitch via Co-carbonization of coal tar pitch and petroleum pitch for production of carbon fibers with both high mechanical properties and thermal conductivity[J].Energy & Fuels Journal,2020,34(5):6474-6482.
[20] Liu Y,Liu J H,Yang J X,et al.In-situ doping B4C nanoparticles in mesophase pitch for preparing carbon fibers with high thermal conductivity by boron catalytic graphitization[J].Molecules,2022,27(16):5132.
[21] Li B L,Qin Y D,Gao F,et al.Preparation,microstructure and thermal properties of aligned mesophase pitch-based carbon fiber interface materials by an electrostatic flocking method[J].Nanomaterials-Basel,2024,14(5):393.
[22] Chen Q,Zhu L A,Bai S X,et al.Preparation and properties of highly thermal conductive C/C-SiC[J].Materials Today Communications,2023,36:106595.
[23] Zhang N Y,Huang D,Chen X,et al.Improving the interlaminar bonding and thermal conductivity of polymer composites by using split-radial mesophase pitch-based carbon fiber as reinforcement[J].Composites Part B:Engineering,2023,252:110509.
[24] Wu S,Liu Y Q,Ge Y C,et al.Surface structures of PAN-based carbon fibers and their influences on the interface formation and mechanical properties of carbon-carbon composites[J].Composites Part A:Applied Science and Manufacturing,2016,90:480-488.
[25] Newcomb B A,Giannuzzi L A,Lyons K M,et al.High resolution transmission electron microscopy study on polyacrylonitrile/carbon nanotube based carbon fibers and the effect of structure development on the thermal and electrical conductivities[J].Carbon,2015,93:502-514.
[26] Lee S,Jang D,Chung Y S,et al.Cost-effective and highly efficient surface heating elements using high thermal conductive carbon fibers[J].Composites Part A:Applied Science and Manufacturing,2020,137:105992.
[27] Lee S,Cho S Y,Chung Y S,et al.High electrical and thermal conductivities of a PAN-based carbon fiber via boron-assisted catalytic graphitization[J].Carbon,2022,199:70-79.
[28] Dong Q,Lu C,Tulugan K,et al.Thermal conductivity of diamond packed electrospun PAN-based carbon fibers incorporated with multi wall carbon nanotubes[J].Journal of Nanoscience and Nanotechnology,2016,16(2):1843-1847.
[29] Hao M Y,Hu Z,Huang Y D,et al.Enhanced both in-plane and through-thickness thermal conductivity of carbon fiber/epoxy composites by fabricating high thermal conductive coaxial PAN/PBO carbon fibers[J].Composites Part B:Engineering,2022,229:109468.
[30] Elimat Z M,Hussain W T,Zihlif A M.PAN-based carbon fibers/PMMA composites:thermal,dielectric,and DC electrical properties[J].Journal of Materials Science:Materials in Electronics,2012,23(12):2117-2122.
[31] Li S Z,Zheng Z B,Liu S W,et al.Ultrahigh thermal and electric conductive graphite films prepared by g-C3N4 catalyzed graphitization of polyimide films[J].Chemical Engineering Journal,2022,430:132530.
[32] Kim J,Kim S,Heo S J,et al.Longitudinal alignment effect of graphene oxide nanoribbon on properties of polyimide-based carbon fibers[J].Carbon,2022,198:219-229.
[33] Yuan Z Z,Chen W,Shi Y K,et al.Thermal conductivity of graphite nanofibers electrospun from graphene oxide-doped polyimide[J].New Carbon Materials,2021,36(5):940-947.
[34] Xiao M,Zhang X W,Xiao W T,et al.The influence of chemical constitution on the structure and properties of polyimide fibre and their graphite fibre[J].Polymer,2019,165:142-151.
[35] 林利芝,王先鹏.石墨烯/聚酰亚胺衍生碳纤维复合气凝胶的制备及其导热和力学性能[J].湖南科技大学学报(自然科学版),2023,38(3):77-87.
[36] Li X,Xu T L,Cao W J,et al.Graphene/carbon fiber network constructed by co-carbonization strategy for functional integrated polyimide composites with enhanced electromagnetic shielding and thermal conductive properties[J].Chemical Engineering Journal,2023,464:142595.

基金资助

国家自然科学基金(52403123);中国博士后科学基金项目(2023M733598)

AI Summary AI Mindmap
PDF

418

访问

0

被引

导航
相关文章

AI思维导图

/