化工新型材料

化工新型材料 ›› 2026, Vol. 54 ›› Issue (1) : 207-212. DOI: 10.19817/j.cnki.issn1006-3536.2026.01.003

科学研究

MoS₂/rGO复合材料的制备及其光催化性能研究

^1,2,3

作者信息 +

Preparation and photocatalytic performance study of MoS₂/rGO composite materials

Xu Haisheng^1,2,3, Ren Zhechen¹, Li Shanjian¹, Ding Liqin¹

Author information +

文章历史 +

Received		Published
2024-12-09		2026-01-20
Issue Date	Revised Date
2026-01-20	2024-12-09

PDF

摘要

以钼酸钠为钼源、硫脲为硫源,采用水热法制备二硫化钼/还原氧化石墨烯(MoS₂/rGO)复合材料,利用X射线衍射仪、扫描电子显微镜、傅里叶变换红外光谱仪等对复合材料进行表征和分析,通过有机染料罗丹明B(RhB)的光降解实验评价了复合材料的光催化性能。结果表明:在反应时间16h、反应温度220℃、活性组分钼酸钠和硫脲含量为1.5mmol和3mmol的条件下,光照100min后MoS₂/rGO复合材料对RhB降解率达到99.33%,相比MoS₂降解率有较大提高。这主要是由于石墨烯作为载体提供了更大的比表面积,暴露了更多的催化活性中心,有利于复合材料中光生电子和空穴的有效转移和快速分离。

Abstract

MoS₂/rGO composites were prepared by hydrothermal method with sodium molybdate as molybdenum source and thiourea as sulfur source.The catalysts were characterized and analyzed by XRD,SEM and FT-IR.The photocatalytic performance for organic dye Rhodamine B(RhB) was evaluated by photodegradation experiments.The results showed that under the conditions of 16h reaction time,220℃ reaction temperature,1.5mmol of sodium molybdate and 3 mmol of thiourea active component,the degradation rate of RhB by the MoS₂/rGO composites could reach 99.33% after 100min illumination,which was higher than that of MoS₂.This was mainly due to the larger specific surface area provided by graphene as a carrier,exposing more catalytic active centers,which was conducive to the efficient transfer and rapid separation of photogenerated electrons and holes in the composite.

关键词

石墨烯 / 钼酸钠 / 硫脲 / 光催化 / 降解

Key words

graphene / sodium molybdate / thiourea / photocatalysis / degradation

引用本文

引用格式 ▾

MoS₂/rGO复合材料的制备及其光催化性能研究[J]. 化工新型材料, 2026, 54(1): 207-212 DOI:10.19817/j.cnki.issn1006-3536.2026.01.003

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Hoccaoglu S M,Mohamad I A I,Basturk I,et al.Preparation of TiO₂-diatomite composites and photocatalytic degradation of dye wastewater[J].International Journal of Environmental Science and Technology,2023,20(10):10887-10902.
[2] Xie W,Liu G,Liu Y,et al.Multidimensional TiO₂ photocatalysts for the degradation of organic dyes in wastewater treatment[J].Journal of Porous Materials,2024,31(5):1655-1681.
[3] Ali A,Oh W C.Photocatalytic performance of CoS₂-graphene-TiO₂ ternary composites for reactive black B (RBB) degradation[J].Journal of the Korean Ceramic Society,2017,54(4):308-313.
[4] V V,K J,Alsawalha M,et al.Rational design of full-spectrum visible-light-responsive bimetallic sulfide Bi₂S₃/CoS₂ compo-sites for high-efficiency photocatalytic degradation of naproxen and bacterial inactivation[J].Journal of Environmental Management,2023,348(1):119246.
[5] Zhu S,Wang D.Photocatalysis:basic principles,diverse forms of implementations and emerging scientific opportunities[J].Advanced Energy Materials,2017,7(23):1700841.
[6] Khan S,Noor T,Iqbal N,et al.Photocatalytic dye degradation from textile wastewater:a review[J].ACS Omega,2024,9(20):21751-21767.
[7] Dalrymple O K,Stefanakos E,Trota M A,et al.A review of the mechanisms and modeling of photocatalytic disinfection[J].Applied Catalysis B:Environment and Energy,2010,98(1/2):27-38.
[8] Wang F,Tan J,He Y,et al.Preparation of Fe-lignin/geopolymer porous microspheres for catalytic degradation of dye wastewater[J].Industrial & Engineering Chemistry Research,2023,62(19):7763-7768.
[9] 徐海升,郜鹏程,薛媚月,等.石墨烯材料功能化改性的研究进展[J].石油化工,2021,50(11):1202-1206.
[10] 徐海升,何丽娟,王豪.新型石墨烯复合材料的制备及其催化应用研究进展[J].化工新型材料,2019,47(3):6-10.
[11] Ma B,Wang Y,Tong X,et al.Graphene-supported CoS₂ particles:an efficient photocatalyst for selective hydrogenation of nitroaromatics in visible light[J].Catalysis Science & Technology,2017,7(13):2805-2812.
[12] Cho A,Koh J H,Lee S I,et al.Activity and thermal stability of sonochemically synthesized MoS₂ and Ni-promoted MoS₂ catalysts[J].Catalysis Today,2010,149(1/2):47-51.
[13] Liu J,Lin H,He Y,et al.Novel CoS₂/MoS₂@Zeolite with excellent adsorption and photocatalytic performance for tetracycline removal in simulated wastewater[J].Journal of Cleaner Production,2020,260(1):121047.
[14] 危阳,马新国,祝林,等.二硫化钼/石墨烯异质结的界面结合作用及其对带边电位影响的理论研究[J].物理学报,2017,66(8):305-314.
[15] 徐一鑫,王爽,全静,等.二硫化钼量子点/还原氧化石墨烯复合材料的制备及其光催化降解有机染料、四环素和Cr(Ⅵ)[J].应用化学,2022,39(5):769-778.
[16] 刘梦佳,余昌强,刘晓文,等.一种新型增强可见光催化性能MoS₂/电气石/石墨烯三元复合材料的制备[J].有色金属工程,2022,12(1):28-35.
[17] Yuan Y,Shen P,Li Q,et al.Excellent photocatalytic perfor-mance of few-layer MoS₂/graphene hybrids[J].Journal of Alloys and Compounds,2017,700(2):12-17.
[18] Costa M C F,Marangoni V S,Ng P R,et al.Accelerated synthesis of graphene oxide from graphene[J].Nanomaterials,2021,11(2):551.
[19] Gupta V,Sharma N,Singh U,et al.Higher oxidation level in graphene oxide[J].Optik,2017,143(5):115-124.
[20] Murugan M,Kumar R M,Alsalme A,et al.Synthesis and property studies of molybdenum disulfide modified reduced graphene oxide (MoS₂-rGO) nanocomposites for supercapacitor applications[J].Journal of Nanoscience and Nanotechnology,2017,17(8):5469-5474.
[21] Zou L,Qu R,Gao H,et al.MoS₂/RGO hybrids prepared by a hydrothermal route as a highly efficient catalytic for sonocatalytic degradation of methylene blue[J].Results in Physics,2019,14(1):102458.
[22] Li H,Li W,Yang H,et al.Photocatalytic properties of MoS₂ nanoflakes vertically assembled on reduced graphene oxide[J].Thin Solid Films,2019,672(3):176-181.
[23] Zou X,Zhang J,Zhao X,et al.MoS₂/RGO composites for photocatalytic degradation of ranitidine and elimination of NDMA formation potential under visible light[J].Chemical Engineering Journal,2020,383(1):123084.
[24] Zhang L,Sun L,Liu S,et al.Effective charge separation and enhanced photocatalytic activity by the heterointerface in MoS₂/reduced graphene oxide composites[J].RSC Advances,2016,6(65):60318-60326.