针对日益高涨的性能需求与环保意识,开发实现可持续性和更高性能的聚乙烯醇/纤维素绿色复合材料是当务之急。介绍了聚乙烯醇/纤维素复合材料的改性方法,通过与纤维素直接复配、对纤维素化学改性后进行复合,可以有效改善聚乙烯醇材料的力学性能、阻燃性能、耐水性能和热塑性能等。综述了聚乙烯醇/纤维素复合材料在生物医用、食品包装、柔性传感器和过滤吸附等领域的应用进展,并指出了现阶段该复合材料存在的问题。
In response to the escalating performance demands and environmental awareness,it is of utmost urgency to develop and implement sustainable and higher-performance green composite materials based on polyvinyl alcohol/cellulose composites.This article introduced the modification methods of polyvinyl alcohol/cellulose composite materials.By directly blending with cellulose or compounding chemically modified-cellulose,the mechanical properties,flame retardant properties,water resistance,and thermoplastic properties of polyvinyl alcohol materials could be effectively improved.It summarized the application progress of polyvinyl alcohol/cellulose composite materials in biomedicine,food packaging,flexible sensors,filtration and adsorption,and pointed out the current challenges facing the composite materials.
[1] 黄得伟,陶忠,黄荣贵,等.聚乙烯醇纤维增强磷建筑石膏基复合材料的性能[J].材料导报,2024,38(S2):651-656.
[2] 梁晓旭,程倩,林丹蕾,等.新型水凝胶基伤口敷料的研究进展[J].现代化工,2023,43(2):26-30.
[3] 周柯鑫,张晨曦,吴柔芬,等.植物纳米纤维素材料制备的研究进展[J].中国科学:化学,2025,55(1):242-257.
[4] 李章康,白绘宇.聚乙烯醇/纤维素包装材料的研究进展[J].塑料包装,2018,28(4):16-19.
[5] 王小英,唐淑玮,吴正国,等.生物质基高阻隔复合膜的研究现状[J].林业工程学报,2021,6(6):13-22.
[6] Dong R,Lu F,Liu P,et al.Preparation of nanocellulose-polyvinyl alcohol composite hydrogels from Desmodium intortum (Mill.) Urb.:chemical property characterization[J].Industrial Crops & Products,2022,176:114371.
[7] Lee D,Park J,Hwang K,et al.Poly (vinyl alcohol) hydrogels reinforced with cellulose nanocrystals for sustained delivery of salicylic acid[J].ACS Applied Nano Materials,2024,7(4):3918-3930.
[8] Yudhanto F,Jamasri J,Rochardjo H S B,et al.Experimental study of polyvinyl alcohol nanocomposite film reinforced by cellulose nanofibers from agave cantala[J].International Journal of Engineering,2021,34(4):987-998.
[9] 马佳波,戴静,廖庭霞,等.柠檬皮/聚乙烯醇/细菌纤维素复合膜的制备及性能研究[J].食品与发酵工业,2024,50(15):104-111.
[10] Wei J,Zhao C,Li Y,et al.A simple and green strategy for preparing poly (vinyl alcohol)/phosphate cellulose aerogel with enhanced flame-retardant properties[J].Polymer Engineering & Science,2021,61(3):693-705.
[11] Pan H,Qian X,Ma L,et al.Preparation of a novel biobased flame retardant containing phosphorus and nitrogen and its performance on the flame retardancy and thermal stability of poly (vinyl alcohol)[J].Polymer Degradation and Stability,2014,106:47-53.
[12] 吴淑茗,陈诗洛,刘万全,等.羧甲基纤维素钠-聚乙烯醇-壳聚糖聚电解质复合膜合成工艺及性能研究[J].云南化工,2021,48(4):40-42.
[13] 刘洋.TEMPO氧化法纳米纤维素及其复合膜的制备与研究[D].呼和浩特:内蒙古农业大学,2020.
[14] Jia R J,Teng K Y,Huang J Y,et al.Hydrogen bonding crosslinking of starch-polyvinyl alcohol films reinforced by ultrasound-assisted and cellulose nanofibers dispersed cellulose nanocrystals[J].Starch-Stärke,2022,74(3/4):2100227.
[15] 段林娟,段燕,王徵,等.Fenton法制备的纤维素纳米纤丝在聚乙烯醇复合膜中的应用研究[J].中国造纸,2020,39(9):1-9.
[16] 黄佳茵,周雅琪,陈美玉,等.基于甲基纤维素改性聚乙烯醇指示膜的制备、表征及对南美白对虾的鲜度指示[J].食品科学,2021,42(3):194-203.
[17] 刘晓钰,赵洁云,叶子茵,等.生物基共混阻燃聚乙烯醇的研究进展[J].纺织科学与工程学报,2024,41(2):78-87.
[18] Hasan M Z,Arafat Y,Bashar M M,et al.Poly-(vinyl alcohol) composite films reinforced with carboxylated functional microcrystalline cellulose from jute fiber[J].Composites and Advanced Materials,2022,31:26349833221103888.
[19] 宫贵贞,冯迪,堵锡华,等.柑橘皮纤维素/聚磷酸铵/三聚氰胺/聚乙烯醇复合膜的制备及其性能[J].塑料工业,2020,48(6):172-177.
[20] 周闯,李普旺,屈云慧,等.聚乙烯醇膜耐水改性的研究进展[J].高分子通报,2021(2):9-17.
[21] Ibrahim M M,Koschella A,Kadry G,et al.Evaluation of cellulose and carboxymethyl cellulose/poly (vinyl alcohol) membranes[J].Carbohydrate Polymers,2013,95(1):414-420.
[22] 葛鑫,程厚富,黄森涛,等.聚乙烯醇-微晶纤维素-六方氮化硼复合膜制备及性能[J].生物质化学工程,2019,53(3):8-14.
[23] Song M,Yu H,Gu J,et al.Chemical cross-linked polyvinyl alcohol/cellulose nanocrystal composite films with high structural stability by spraying Fenton reagent as initiator[J].International Journal of Biological Macromolecules,2018,113:171-178.
[24] 石伊康.聚乙烯醇的增塑改性及其可纺性研究[D].天津:天津科技大学,2023.
[25] 冯彦洪,陈帅杰,孙航.热塑性纤维素与PVA混溶性的分子动力学模拟[J].原子与分子物理学报,2025,42(3):155-164.
[26] Van Nguyen S,Nguyen T K,Lee B K.Thermal and heat-sealing properties of polyvinyl alcohol/cellulose nanocrystals-based nanocomposites for food packaging[J].Materials Today Communications,2024,40:109926.
[27] Marcovich N E,Kurańska M,Prociak A,et al.Open cell semi-rigid polyurethane foams synthesized using palm oil-based bio-polyol[J].Industrial Crops and Products,2017,102:88-96.
[28] 苏伟,戴佰林,王武,等.PVA/竹纤维素复合膜的制备及性能研究[J].山东化工,2021,50(22):27-30.
[29] Zhu L,Liu Y,Jiang Z,et al.Highly temperature resistant cellulose nanofiber/polyvinyl alcohol hydrogel using aldehyde cellulose nanofiber as cross-linker[J].Cellulose,2019,26:5291-5303.
[30] 许文才,刘鹏,李东立,等.可降解抑菌功能薄膜的制备及性能研究[J].包装工程,2015,36(11):1-4;9.
[31] 杨陈,林燕萍,李永贵.纳米纤维素材料研究进展[J].化工新型材料,2020,48(10):232-235.
[32] 黄巧雨,孙争光,张玉红,等.聚乙烯醇基复合水凝胶慢性伤口敷料研究进展[J].高分子材料科学与工程,2024,40(9):173-181.
[33] 计烨,杨建军,吴庆云,等.单宁酸-纤维素/聚乙烯醇/聚丙烯酸双网络水凝胶的制备及性能[J].高分子材料科学与工程,2024,40(1):17-24.
[34] 陈欣玥,管舒仪,蔡晓丹,等.木质纳米纤维素增强聚乙烯醇复合水凝胶的制备及性能研究[J].化工新型材料,2023,51(2):218-222;228.
[35] Van Nguyen S,Lee B K.PVA/CNC/TiO2 nanocomposite for food-packaging:improved mechanical,UV/water vapor barrier,and antimicrobial properties[J].Carbohydrate Polymers,2022,298:120064.
[36] 李慧,田家瑶,庞姗姗,等.聚乙烯醇/纳米纤维素/石榴皮多酚复合抗菌薄膜性能研究[J].食品与机械,2023,39(4):103-109;177.
[37] 刘伟,吴显,陈小澄,等.羧基化填料对聚乙烯醇/纳米纤维素水凝胶力学、导电和传感性能的影响[J].中国塑料,2022,36(6):16-23.
[38] 伍秋萍,马兑新,方凤莹,等.纤维素/聚乙烯醇/聚苯胺阻燃气凝胶传感器的制备及性能[J].高分子材料科学与工程,2024,40(7):145-152.
[39] Mu Y,Ai Z,Zhang L,et al.Insight into core-shell dependent anoxic Cr(Ⅵ) removal with Fe@Fe2O3 nanowires:indispensable role of surface bound Fe(Ⅱ)[J].ACS Applied Materials & Interfaces,2015,7(3):1997-2005.
[40] 杨兴林,伏广好,赵白云,等.沙柳/聚乙烯醇新型水凝胶复合膜的制备及性能研究[J].化工新型材料,2022,50(1):161-166;176.
[41] 周亲雄,陈英,刘瑞,等.罗布麻秆中纤维素提取及其气凝胶的制备[J].印染,2024,50(3):49-54.
[42] He Y,Liu H,Ying W.Constructing stable polyvinyl alcohol/gelatin/cellulose nanocrystals composite electrospun membrane with excellent filtration efficiency for PM2.5[J].Polymers,2024,16(12):1656.
PDF
