综述了铁铁氢化酶活性中心的结构特征及相关功能模拟方面的工作成果,归纳总结了铁铁氢化酶的电化学催化产氢机理,解析了四类典型质子酸在氢化酶电化学催化过程中的作用机理并展望了氢化酶未来的发展方向,旨在为氢化酶模型物的研究提供参考。
In this paper,we reviewed the research progress of the structural characteristics and the related functional simulations of Fe-Fe hydrogenase active centers,and summarized the electrochemical hydrogen production mechanisms of Fe-Fe hydrogenases.Additionally,we analyzed the roles of four typical proton acids in the electrochemical catalytic process,and discussed the future development directions,aiming to provide a foundational reference for subsequent research on hydrogenase model compounds.
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基金资助
国家自然科学基金地区科学基金项目(82460364);桂北特色药资源研究中心项目(YGZX202301,YJZX202102,YJZX202104);广西自然科学基金(2023GXNSFBA026314,2023GXNSFAA026452);广西重点研发项目(2023AB01140);广西中青年项目(2021KY0939);桂林师范学院校级科研项目(KYB202006)
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