相变温度调节剂对CaCl2·6H2O-SrCl2·6H2O复合相变材料热物性的影响研究

王强强1, 罗孝学1*, 李祥林2, 王天任1, 汪永杰1

化工新型材料 ›› 2025, Vol. 53 ›› Issue (6) : 94 -98.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (6) : 94-98. DOI: 10.19817/j.cnki.issn1006-3536.2025.06.031
新材料与新技术

相变温度调节剂对CaCl2·6H2O-SrCl2·6H2O复合相变材料热物性的影响研究

    王强强1, 罗孝学1*, 李祥林2, 王天任1, 汪永杰1
作者信息 +

Study on the effect of phase change temperature modifier on the thermophysical properties of CaCl2·6H2O-SrCl2·6H2O composite phase change materials

  • Wang Qiangqiang1, Luo Xiaoxue1, Li Xianglin2, Wang Tianren1, Wang Yongjie1
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摘要

以CaCl2·6H2O-SrCl2·6H2O为相变基材,尿素、氯化铵、乙二醇、丙三醇、氯化钠和氯化钾为相变温度调节剂,分析不同类型温度调节剂对CaCl2·6H2O-SrCl2·6H2O复合相变材料相变温度与相变潜热值的影响。结果表明:乙二醇、丙三醇能够显著调节复合相变材料的相变温度,过冷度较小,且能够保持较高的相变潜热值,其次是尿素、氯化铵,而氯化钠和氯化钾温效果不佳,同时增加了复合相变材料的过冷度,影响复合相变材料的储热能力。

Abstract

In order to analyze the effects of various temperature modifiers on the phase change temperatures and the latent heat values of the phase change of CaCl2·6H2O-SrCl2·6H2O composite phase change materials,CaCl2·6H2O-SrCl2·6H2O was used as the phase change substrate,and urea,ammonium chloride,ethylene glycol,glycerol,propanetriol,sodium chloride,and potassium chloride were employed as the phase change temperature regulators.The experimental results indicated that ethylene glycol and propanetriol could significantly regulate the phase change temperature of the composite phase change materials,with less subcooling and relatively higher latent heat values,followed by urea and ammonium chloride,while sodium chloride and potassium chloride had poor temperature adjustment,increasing the degree of subcooling of the composite phase change materials and negatively affecting the heat storage capacity of the composite phase change materials.

关键词

相变温度调节剂 / 相变温度 / 相变潜热值 / 过冷度

Key words

phase change temperature regulator / phase change temperature / latent heat value of phase change / subcooling

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相变温度调节剂对CaCl2·6H2O-SrCl2·6H2O复合相变材料热物性的影响研究[J]. 化工新型材料, 2025, 53(6): 94-98 DOI:10.19817/j.cnki.issn1006-3536.2025.06.031

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基金资助

北部湾大学校级科研项目(YLXKKY202270);广西自然科学基金面上项目(2018GXNSFAA138157);北部湾大学高层次人才科研启动经费项目(23KYQD17)

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