聚酰亚胺(PI)是一种聚合物,其是由二酐和二胺单体经过缩聚反应生成,主链上含有酰亚胺环。由于其具有独特的热稳定性、耐高温性、机械性能和易成膜性等特点,因此在航空航天、电力电子等领域得到广泛应用。综述了聚酰亚胺及其薄膜的制备工艺,其中涵盖了平面薄膜、可展曲面膜和非可展曲面膜这3种类型。同时对聚酰亚胺薄膜在共形电路领域的发展进行了展望,重点强调了聚酰亚胺非可展曲面膜在未来军事航空航天领域的重要性。
Polyimide (PI) is a polymer formed by a polycondensation reaction of dianhydride and diamine monomer,and contains an imide ring in its main chain.Because of its unique thermal stability,high temperature resistance,mechanical properties and easy film formation,it has been widely used in aerospace,power electronics and other fields.The preparation technology of polyimide and its films was reviewed,including three types:planar film,developable curved surface film and non-developable curved surface film.At the same time,the development of polyimide films in the field of conformal circuits was prospected,and the importance of polyimide non-developable curved surface films in the field of military aerospace in the future was emphasized.
[1] 陈思扬,陈志豪,陈广泽,等.含咪唑基团的聚酰亚胺薄膜的制备及性能[J].高分子材料科学与工程,2023,39(8):26-31.
[2] Wu S S,Liang J C,Shi Y P,et al.Design of interchain hydrogen bond in polyimide membrane for improved gas selectivity and membrane stability[J].Journal of Membrane Science,2020,618:118659.
[3] Hossain I,Munsur A Z A,Choi O,et al.Bisimidazolium PEG mediated crosslinked 6FDA-durene polyimide membranes for CO2 separation[J].Separation and Purification Technology,2019,224:180-188.
[4] 李晓文,吴东森,刘鹏波.利用超临界二氧化碳制备低介电常数聚酰亚胺微孔薄膜[J].高分子材料科学与工程,2014,30(6):136-141.
[5] Bian J,Zhou L B,Wan X D,et al.Experimental study of laser lift-off of ultra-thin polyimide film for flexible electronics[J].Science China Technological Sciences,2019,62,233-242.
[6] Wang C X,Lv Z S,Mohan M P,et al.Pangolin-inspired stretchable,microwave-invisible metascale[J].Advanced materials,2021,33:2102131.
[7] Zhang D Y,Li L L,Wang Y,et al.Methods and strategies to decrease the dielectric properties of polyimide films:a review[J].Journal of Sol-Gel Science and Technology,2023,108:1-12.
[8] Hirai S,Phanthong P,Wakabayashi T,et al.Fabrication of porous polyimide membrane with through-hole via multiple solvent displacement method[J].Chemistry Open,2021,10:352-359.
[9] 史恩,董杰,赵昕,等.基于异氰酸酯的可溶性聚酰亚胺的合成及其气体分离性能[J].高分子通报,2023,36(9):1182-1190.
[10] Shahram M A,Naeemeh B L,Ahmad A.Comparison of one-step and two-step methods of polyimidization and substitution effect in the synthesis of new poly(ester-imide)s with bulky pendent group[J].Polymer Degradation and Stability,2006,91:2622-2631.
[11] Inoue H,Sasaki Y,Ogawa T.Comparison of one-pot and two-step polymerization of polyimide from BPDA/ODA[J].Applied Polymer,1996,60:123-131.
[12] Wang Z,Chen X,Yang H,et al.The in-plane orientation and thermal mechanical properties of the chemically imidized polyimide films[J].Chinese Journal of Polymer Science,2019,37:268-278.
[13] Suhaimi N H,Yeong Y F,Jusoh N,et al.Amine-functionalized metal organic framework(MOF)/6FDA-durene composite membrane for CO2 removal from CH4[J].Materials Today:Proceedings,2019,19:1730-1737.
[14] Chen W J,Chen W,Zhang B Q,et al.Thermal imidization process of polyimide film:interplay between solvent evaporation and imidization[J].Polymer,2017,109:205-215.
[15] 廉萌,童发钦,赵飞,等.玻璃粉复合聚酰亚胺薄膜的制备及性能研究[J].中国塑料,2023,37(7):47-52.
[16] 罗伟.半芳香无色透明聚酰亚胺薄膜的制备与性能[D].上海:东华大学,2022.
[17] Wang Y,Yang Y,Jia Z,et al.Effect of chemical structure and preparation process on the aggregation structure and properties of polyimide film[J].Journal of Applied Polymer Science,2012,127:4581-4587.
[18] 耿慧彬,闫博雅,常娜,等.聚酰亚胺气体分离膜的制备与改性研究进展[J].高分子材料科学与工程,2022,38(4):174-182.
[19] 宋艳江,潘庆华,祁盼盼,等.聚酰亚胺薄膜的制备及其结构与性能分析——推荐一个高分子化学综合实验[J].大学化学,2023,38(11):230-237.
[20] 曾祥华,朱秀榕.聚酰亚胺平面/调制薄膜的制备与测量[J].赣南师范大学学报,2016,37(6):38-40.
[21] 胡学欢,张明玉.耐电晕聚酰亚胺复合薄膜的新工艺设计[J].电工材料,2022(3):13-17.
[22] 李超,尹恩怀,周苓.基于3D打印的聚酰亚胺介质层制备工艺研究[J].绝缘材料,2019,52(6):30-34.
[23] 王海鹏,张树青,王安妮.一种聚酰亚胺薄膜曲面预成形装置:CN104960187B[P].2017-03-01.
[24] 刘秀利,苑博.曲面共形微带天线阵面的制备方法:CN109755760B[P].2020-08-25.
[25] Wang C,Wang Q H,Wang T M.Simple method for preparation of porous polyimide film with an ordered surface based on in situ self-assembly of polyamic acid and silica microspheres[J].Lan-muir:the ACS Journal of Surfaces and Colloids,2010,26:18357-18361.
[26] 刘建鹏.复杂曲面电子的剪纸共形设计与柔性传感应用[D].广州:华中科技大学,2023.
[27] Liu F,Chen Y,Song H L,et al.High performance,tunable electrically small antennas through mechanically guided 3D assembly[J].Small,2019,15:1804055.
[28] Hirokazu M,Dai Y,Kiyoshi K.Three-dimensionally ordered macroporous polyimide composite membrane with controlled pore size for direct methanol fuel cells[J].Journal of Power Sources,2007,178:596-602.
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