与二元复合材料相比,石墨烯/BiOX基三元复合材料具有更宽的可见光响应范围、更高效的载流子迁移率和更优异的可见光催化活性。综述了石墨烯/BiOX/碳材料、石墨烯/BiOX/金属硫化物、石墨烯/BiOX/磁性材料、石墨烯/BiOX/银系半导体复合材料的制备方法,介绍了这些复合材料在有机污染物降解、光解水析氢和还原重金属离子等方面的应用,并对石墨烯/BiOX基三元复合材料未来发展及实际应用方向进行了展望。
Compared to binary composite materials,graphene/BiOX-based ternary composites exhibit a broader visible light response range,more efficient carrier mobility,and superior photocatalytic activity.The preparation methods of graphene/BiOX/carbon materials,graphene/BiOX/metal sulfides,graphene/BiOX/magnetic materials,and graphene/BiOX/silver-based semiconductor composites were reviewed.Furthermore,the applications of these composites for degradation of organic pollutant,photocatalytic hydrogen generation,reduction of heavy metal ions were described,and the future development and practical application direction of graphene/BiOX-based ternary composites were prospected.
[1] 全玉莲,靳振英,赵洁妤,等.卤氧化铋/石墨烯复合光催化剂的研究进展[J].河北环境工程学院学报,2021,31(3):71-74,79.
[2] Pan H,Gu J,Hou K,et al.High-efficiency,compressible,and recyclable reduced graphene oxide/chitosan composite aerogels supported g-C3N4/BiOBr photocatalyst for adsorption and degradation of rhodamine B[J].J Environ Chem Eng,2022,10:107157-107169.
[3] Ahmad I,Athar M S,Muneer M,et al.Graphene oxide decorated BiOI/CdS nanocomposite:an efficient ternary heterostructure for photodegradation and adsorption study of organic pollutants[J].Surf Interfaces,2024,45:103819-103834.
[4] Premalatha N,Miranda L R.A magnetic separable 3D hierarchical BiOI/rGO/Fe3O4 catalyst for degradation of Rhodamine B under visible light:kinetic studies and mechanism of degradation[J].Mater Sci Eng B,2022,276:115576-115592.
[5] Zhang J,Tong H,Pei W,et al.Integrated photocatalysis-adsorption-membrane separation in rotating reactor for synergistic removal of RhB[J].Chemosphere,2021,270:129424-129432.
[6] Lan M,Wang M,Zheng N,et al.Hierarchical polyurethane/RGO/BiOI fiber composite as flexible,self-supporting and recyclable photocatalysts for RhB degradation under visible light[J].J Ind Eng Chem,2022,108:109-117.
[7] Thirumalraj B,Jaihindh D P,Alaswad S O,et al.Fabricating BiOCl/BiVO4 nanosheets wrapped in a graphene oxide heterojunction composite for detection of an antihistamine in biological samples[J].Environ Res,2022,212:113636-113646.
[8] Yang L,Xu C,Wan F,et al.Synthesis of RGO/BiOI/ZnO composites with efficient photocatalytic reduction of aqueous Cr(Ⅵ) under visible-light irradiation[J].Mater Res Bull,2019,112:154-158.
[9] Zhai B,Chen Y,J,Li J,et al.Two-dimensional composite (BiOCl/GO/MOF-5) by ultrasonic-assisted solvothermal synthesis with enhanced photocatalytic activity[J].Micro Nano Lett,2020,15(3):149-154.
[10] Fu J,Chen L W,Dai Y,et al.BiOmFn/BiOxIy/GO Nanocomposites:synthesis,characterization,and photocatalytic activity[J].Mol Catal,2018,455:214-223.
[11] Zhang B,Wang D,Cao J,et al.Efficient doping induced by charge transfer at the hetero-interface to enhance photocatalytic performance[J].Appl Mater Interfaces,2023,15:12924-12935.
[12] Jiang L,Xie Y,He F,et al.Facile synthesis of GO as middle carrier modified flower-like BiOBr and C3N4 nanosheets for simultaneous treatment of chromium(Ⅵ) and tetracycline[J].Chinese Chem Lett,2021,32:2187-2191.
[13] Li Y,Zhou M,Cheng B,et al.Recent advances in g-C3N4-based heterojunction photocatalysts[J].J Mater Sci Technol,2020,56:1-17.
[14] Bao Y,Chen K.Novel Z-scheme BiOBr/reduced graphene oxide/protonated g-C3N4 photocatalyst:synthesis,characterization,visible light photocatalytic activity and mechanism[J].Appl Surf Sci,2018,437:51-61.
[15] Xue J,Li X,Ma S,et al.Facile fabrication of BiOCl/RGO/protonated g-C3N4 ternary nanocomposite as Z-scheme photocatalyst for tetracycline degradation and benzyl alcohol oxidation[J].J Mater Sci,2019,54:1275-1290.
[16] Dai K,Lu L,Liang C,et al.A high efficient graphitic-C3N4/BiOI/graphene oxide ternary nanocomposite heterostructured photocatalyst with graphene oxide as electron transport buffer material[J].Dalton Trans,2015,44:7903-7911.
[17] Yu H J,Shi R,Zhao Y F,et al.Smart utilization of carbon dots in semiconductor photocatalysis[J].Adv Mater,2016,28:9454-9477.
[18] Qu S,Xiong Y,Zhang J.Graphene oxide and carbon nanodots co-modified BiOBr nanocomposites with enhanced photocatalytic 4-chlorophenol degradation and mechanism insight[J].J Colloid Interface Sci,2018,527:78-86.
[19] Qu S,Xiong Y,Zhang J.Fabrication of GO/CDots/BiOI nanocomposites with enhanced photocatalytic 4-chlorophenol degradation and mechanism insight[J].Sep Purif Technol,2019,210:382-389.
[20] Arumugam M,Lee S J,Begildayeva T,et al.Enhanced photocatalytic activity at multidimensional interface of 1D-Bi2S3@2D-GO/3D-BiOI ternary nanocomposites for tetracycline degradation under visible-light[J].J Hazard Mater,2021,404:123868-123880.
[21] Li Y,Lai Z,Huang Z,et al.Fabrication of BiOBr/MoS2/graphene oxide composites for efficient adsorption and photocatalytic removal of tetracycline antibiotics[J].Appl Surf Sci,2021,550:149342-149352.
[22] Zhang W,Fu J,Wang Y,et al.Enhanced visible-light photocatalytic activity of ZnS/BiOBr/graphene oxide ternary composite[J].J Phys Chem Solids,2019,127:19-27.
[23] Xia Y M,Zhang J H,Xia M,et al.Peony-like magnetic graphene oxide/Fe3O4/BiOI nanoflower as a novel photocatalyst for enhanced photocatalytic degradation of Rhodamine B and Methylene blue dyes[J].J Mater Sci:Mater Electron,2020,31(3):1996-2009.
[24] Zhang R,Li Y,Han Q,et al.Investigation the high photocatalytic activity of magnetically separable graphene oxide modified BiOBr nanocomposites for degradation of organic pollutants and antibiotic[J].J Inorg Organomet Polym Mater,2020,30:1703-1715.
[25] Cui S,Cong Y,Zhao W,et al.A novel multifunctional magnetically recyclable BiOBr/ZnFe2O4-GO S-scheme ternary heterojunction:photothermal synergistic catalysis under Vis/NIR light and NIR-driven photothermal detection of tetracycline[J].J Colloid Interface Sci,2024,654:356-370.
[26] 姜苗苗,丁颖,徐丽慧,等.纳米银材料的合成及其应用研究进展[J].化工新型材料,2022,50(6):245-249.
[27] Zhong S,Wang B,Zhou H,et al.Fabrication and characterization of Ag/BiOI/GO composites with enhanced photocatalytic activity[J].J Alloys Compd,2019,806:401-409.
[28] Li C Y,Wang B Q,Zhang F J,et al.Performance of Ag/BiOBr/GO composite photocatalyst for visible-light-driven dye pollutants degradation[J].J Mater Res Technol,2020,9(1):610-621.
[29] 余家国,许第发.银系半导体光催化材料研究进展[J].硅酸盐学报,2017,45(9):1240-1255.
[30] Chen J,Xiao X,Wang Y,et al.Novel AgI/BiOBr/reduced graphene oxide Z-scheme photocatalytic system for efficient degradation of tetracycline[J].J Alloys Compd,2019,800:88-98.
[31] Zhang R,Han Q,Li Y,et al.Fabrication of a Ag3PO4/reduced graphene oxide/BiOBr ternary photocatalyst for enhanced visible-light photocatalytic activity and stability[J].J Alloys Compd,2019,810:151868-151879.
[32] Jing Z,Dai X,Xian X,et al.Novel ternary heterogeneous reduction graphene oxide (RGO)/BiOCl/TiO2 nanocomposites for enhanced adsorption and visible-light induced photocatalytic activity toward organic contaminants[J].Materials,2020,13,2529-2546.
[33] Wang L,Gao R,He J,et al.Preparation and photocatalytic properties of Zr-BiOI/GO composites[J].J Solid State Chem,2024,332:124586-124595.
[34] Liu Y,Zhou Y,Zhu P,et al.Surfactant-assisted synthesis of highly dispersed ZnS(C)/BiOBr/GO ternary composites for effectively improve the degradation ability of organic pollutants under visible light[J] Journal of Molecular Liquids,2023,378,121621-121636.
[35] Liu X,Cai L.A novel double Z-scheme BiOBr-GO-polyaniline photocatalyst:study on the excellent photocatalytic performance and photocatalytic mechanism[J].Appl Surf Sci,2019,483:875-887.
[36] Singh P,Sudhaik A,Raizada P.Photocatalytic performance and quick recovery of BiOI/Fe3O4@graphene oxide ternary photocatalyst for photodegradation of 2,4-dintirophenol under visible light[J].Mater Today Chem,2019,12(1):85-95.
[37] Zhu M,Tonni A K,You Y,et al.2D graphene oxide (GO) doped p-n type BiOI/Bi2WO6 as a novel composite for photodegradation of bisphenol A (BPA) in aqueous solutions under UV-vis irradiation[J].Mat Sci Eng C-mater,2020,108:110420-110428.
[38] Maryam S,Mohammad H,Davood K,et al.Sono-solvothermal hybrid fabrication of BiOCl-Bi24O31Cl10/rGO nanoheterostructure photocatalyst with efficient solar-light-driven performance in degradation of fluoroquinolone antibiotics[J].Sol Energ Mat Sol C,2019,193:335-350.
[39] Hait P,Mehta R,Basu S.Advancing sustainable solutions:harnessing polyaniline/BiOCl/GO ternary nanocomposites for solar-powered degradation of organic pollutant and photocatalytic hydrogen generation[J] J Clean Prod,2023,424:138851-138861.
[40] Li H,Deng F,Zheng Y,et al.Visible-light-driven Z-scheme rGO/Bi2S3-BiOBr heterojunctions with tunable exposed BiOBr (102) facets for efficient synchronous photocatalytic degradation of 2-nitrophenol and Cr(Ⅵ) reduction[J].Environ Sci-Nano,2019,6(12):3670-3683.
[41] Wang Q,Li Y,Huang L,et al.Enhanced photocatalytic degradation and antibacterial performance by GO/CN/BiOI composites under LED light[J].Appl Surf Sci,2019,497:143753-143763.
基金资助
河北省优秀专家出国培训项目(201917);河北省高等学校科学技术研究项目(Z2020101);河北省大中学生科技创新能力培育专项项目(201902A009)
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