以高性能的碳纳米管(CNT)薄膜为骨架,利用超声雾化喷头将环氧树脂(EP)喷涂到CNT薄膜的孔隙中实现CNT/EP复合材料的一体化成型。在复合过程中较好地保留了CNT薄膜的结构完整性,一定程度上解决了其他方法中CNT难分散的问题,简单有效的工艺也更有利于实现复合材料的大规模制备。通过优化树脂含量并采用预拉伸的方式来提升CNT在复合材料中的取向性,成功制备出高取向、高致密性且性能均匀的高性能复合膜,其拉伸强度达到1.9GPa,韧性达到47.7J/cm3。如此高性能的CNT/EP复合材料在多个领域具有重要的应用前景。
Using high-performance carbon nanotube (CNT) film as the skeleton,epoxy resin (EP) was sprayed into the pores of the CNT film by ultrasonic atomizing nozzle to realize the integration of the forming of the composite material.The structural integrity of CNT film was well preserved during the composite process,which addressed the dispersion challenges of CNT commonly encountered with other methods to a certain extent.The simple and effective process was also more conducive to the realization of large-scale preparation of composite materials.By optimizing the resin content and using a pre-stretching method to improve the CNT orientation in the composites,a high-performance composite film with high orientation,high density,and uniform properties was successfully prepared,with a tensile strength of 1.9GPa and a toughness of 47.7J·cm-3.It is suggested that such a high performance composite material is potential for applications in many fields.
[1] Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56-58.
[2] Shin M K,Oh J,Lima M,et al.Elastomeric conductive composites based on carbon nanotube forests[J].Advanced Materials,2010,22(24):2663-1669.
[3] Peng B,Locascio M,Zapol P,et al.Measurements of near-ultimate strength for multiwalled carbon nanotubes and irradiation-induced crosslinking improvements[J].Nature Nanotechnology,2008,3(10):626-631.
[4] Bai Y X,Yue H J,Wang J,et al.Super-durable ultralong carbon nanotubes[J].Science,2020,369(6507):1104-1110.
[5] Bai Y,Zhang R,Ye X,et al.Carbon nanotube bundles with tensile strength over 80 GPa[J].Nature Nanotechnology,2018,13(7):589-595.
[6] Xu W,Chen Y,Zhan H,et al.High-strength carbon nanotube film from improving alignment and densification[J].Nano Letters,2016,16(2):946-952.
[7] Zhang R,Wen Q,Qian W,et al.Superstrong ultralong carbon nanotubes for mechanical energy storage[J].Advanced Materials,2011,23(30):3387-3391.
[8] Demczyk B G,Wang Y M,Cumings J,et al.Direct mechanical measurement of the tensile strength and elastic modulus of multiwalled carbon nanotubes[J].Materials Science and Engineering:A,2002,334(1-2):173-178.
[9] Jou W S,Cheng H Z,Hsu C F.The electromagnetic shielding effectiveness of carbon nanotubes polymer composites[J].Journal of Alloys and Compounds,2007,434:641-645.
[10] Hayashida K,Matsuoka Y.Highly enhanced dielectric constants of barium titanate-filled polymer composites using polymer-grafted carbon nanotube matrix[J].Carbon,2013,60:506-513.
[11] TabkhPaz M,Shajari S,Mahmoodi M,et al.Thermal conductivity of carbon nanotube and hexagonal boron nitride polymer composites[J].Composites Part B:Engineering,2016,100:19-30.
[12] Lai W L,Sachdeva N,Tan Y V,et al.Experimental assessment on the mechanical,physical,thermal,and chemical properties of halloysite and carbon nanoparticles reinforced epoxy resins for repair applications[J].Polymers for Advanced Technologies,2023,34(10):3260-3275.
[13] Cheng X,He G Y,Sun Z W,et al.Enhanced surface insulation for SiO2/epoxy resin composites through co-modification of nanofiller with silane coupling agent and plasma[J].Journal of Physics D:Applied Physics,2023,56(36):1156-1167.
[14] Cha J,Jun G H,Park J K,et al.Improvement of modulus,strength and fracture toughness of CNT/epoxy nanocomposites through the functionalization of carbon nanotubes[J].Composites Part B:Engineering,2017,129:169-179.
[15] Zhang X H,Wang X,Zhang X,et al.Viscoelastic,ductile and repairable carbon nanotube films formed with CNT/PEI double networks containing branched polyethylenimine[J].Npg Asia Materials,2023,15(1):44-52.
[16] Hu D,Xing Y,Chen M,et al.Ultrastrong and excellent dynamic mechanical properties of carbon nanotube composites[J].Composites Science and Technology,2017,141:137-144.
[17] Furquan S A,Farooqui M R,Alam Z,et al.Melt spun PET/CNT nanocomposite fibers:effect of CNT and post drawing process on the mechanical properties[C].Composites Science and Technology:2020-Scientific and Technical Challenges:Proceedings of the 9th International Conference on Composite Science and Technology (ICCST-9),2013:356-363.
[18] Li Y L,Wang S J,He E Q,et al.The effect of sliding velocity on the tribological properties of polymer/carbon nanotube composites[J].Carbon,2016,106:106-109.
[19] Liu W,Wei B C,Xu F J.Investigation on the mechanical and electrical properties of carbon nanotube/epoxy composites produced by resin transfer molding[J].Journal of Composite Materials,2017,51(14):2035-2043.
[20] Wang X,Yong Z Z,Li Q W,et al.Ultrastrong,stiff and multifunctional carbon nanotube composites[J].Materials Research Letters,2013,1(1):19-25.
[21] Chen H,Chen Y,Zhan H,et al.Preparation of carbon nanotube/epoxy composite films with high tensile strength and electrical conductivity by impregnation under pressure[J].Frontiers of Materials Science,2019,13(2):165-173.
[22] Lin W,Shi Q Q,Chen H,et al.Mechanical properties of carbon nanotube fibers reinforced epoxy resin composite films prepared by wet winding[J].Carbon,2019,153:308-314.
[23] Nam T H,Goto K,Nakayama H,et al.Effects of stretching on mechanical properties of aligned multi-walled carbon nanotube/epoxy composites[J].Composites Part A:Applied Science and Manufacturing,2014,64:194-202.
[24] Nam T H,Goto K,Yamaguchi Y,et al.Improving mechanical properties of high volume fraction aligned multi-walled carbon nanotube/epoxy composites by stretching and pressing[J].Composites Part B:Engineering,2016,85:15-23.
[25] Wang L J,Qiu J H,Sakai E.Mechanical and electrical properties of polylactic acid/carbon nanotube composites by rolling process[J].Science and Engineering of Composite Materials,2018,25(5):891-901.
[26] Tran T Q,Fan Z,Mikhalchan A,et al.Post-treatments for multifunctional property enhancement of carbon nanotube fibers from the floating catalyst method[J].ACS Appl Mater Interfaces,2016,8(12):7948-7956.
[27] Shi Q Q,Zhan H,Mo R W,et al.High-strength and toughness carbon nanotube fiber/resin composites by controllable wet-stretching and stepped pressing[J].Carbon,2022,189:1-9.
[28] Shimamura Y,Oshima K,Tohgo K,et al.Tensile mechanical properties of carbon nanotube/epoxy composite fabricated by pultrusion of carbon nanotube spun yarn preform[J].Composites Part A:Applied Science and Manufacturing,2014,62:32-38.
[29] Nam T H,Goto K,Yamaguchi Y,et al.Improving mechanical properties of high volume fraction aligned multi-walled carbon nanotube/epoxy composites by stretching and pressing[J].Composites Part B:Engineering,2016,85:15-23.
[30] Zhang X,Jiang X,Qu S,et al.Effects of ultrasonication on the microstructures and mechanical properties of carbon nanotube films and their based composites[J].Composites Science and Technology,2022,221:109-136.
[31] Zhang L,Xu W,Luo X G,et al.High performance carbon nanotube based composite film from layer-by-layer deposition[J].Carbon,2015,90:215-221.