The polydopamine-coated magnetic platanus fruit fiber adsorbents (PDA@CoFe2O4-PFs) were synthesized by a two-step approach.The as-synthesized materials were characterized and analyzed by SEM,TG/DTA,XRD,FT-IR,VSM and water contact angle analyzer,respectively.More specifically,the performance of the adsorbents was investigated by taking Safranine T (ST) as the target pollutant,and the effects of CoFe2O4 loading ratio,solution pH,adsorbent dosage and contact time on the adsorption performance were explored.The adsorption data were fitted and analyzed using adsorption kinetic model and adsorption isotherm model.The experimental results revealed that PDA@CoFe2O4-PFs had good hydrophilicity and magnetism,which could realize the adsorption and removal of ST from wastewater and the rapid separation of the adsorbent from the solution under the action of an applied magnetic field.The theoretical maximum adsorption capacity of the product reached up to 54.32mg/g when 35mg of adsorbent with CoFe2O4 of 20% loading ratio was added to the ST solution at pH 8.0.The adsorption process fitted well to the pseudo-second-order model and the Langmuir model,indicating that the adsorption was a single molecular layer chemisorption.
[1] Yeo K F H,Dong Y,Yang Y,et al.Fast arsenate As(Ⅴ) adsorption and removal from water using aluminium Al(Ⅲ) fixed on Kapok fibres[J].Environmental Pollution,2022,314(10):120236.
[2] 马金珍,王芷薇,廖翊芳,等.荔枝果皮的胺基改性及对水中Cr(Ⅵ)的吸附去除特性[J].化工新型材料,2022,50(5):274-280.
[3] Aruna,Bagotia N,Sharma A K,et al.A review on modified sugarcane bagasse biosorbent for removal of dyes[J].Chemosphere,2021,268(7):143-148.
[4] Chen H F,Zhou Y,Wang J Y,et al.Polydopamine modified cyclodextrin polymer as efficient adsorbent for removing cationic dyes and Cu2+[J].Journal of Hazardous Materials,2020,389(8):46-51.
[5] Değermenci G D,Değermenci N,Ayvaoğlu V,et al.Adsorption of reactive dyes on lignocellulosic waste; characterization,equilibrium,kinetic and thermodynamic studies[J].Journal of Cleaner Production,2019,225(7):1220-1229.
[6] Wu P K,Feng Y R,Xu J,et al.Ultralight N-doped platanus acerifolia biomass carbon microtubes/RGO composite aerogel with enhanced mechanical properties and high-performance microwave absorption[J].Carbon,2023,202:194-203.
[7] Yang K,Ren J,Cui Y,et al.Fabrication of porous tubular carbon fibers from the fruits of Platanus orientalis and their high oil adsorption properties[J].Journal of Environmental Chemical Engineering,2021,9(4):94-103.
[8] 孙二强,王昭旭,刘佳莉,等.贻贝仿生化学聚多巴胺改性纳米吸附材料研究进展[J].化工新型材料,2022,50(12):61-67.
[9] Hu C,Jiang J Y,Li Y F,et al.Eco-friendly poly(dopamine)-modified glass microspheres as a novel self-floating adsorbent for enhanced adsorption of tetracycline[J].Separation and Purification Technology,2022,292(6):182-186.
[10] Fu J W,Xin Q Q,Wu X C,et al.Selective adsorption and separation of organic dyes from aqueous solution on polydopamine microspheres[J].Journal of Colloid and Interface Science,2016,461:292-304.
[11] Farnad N,Farhadi K,Voelcker N H.Polydopamine nanoparticles as a new and highly selective biosorbent for the removal of copper(Ⅱ) ions from aqueous solutions[J].Water,Air,& Soil Pollution,2012,223(6):3535-3544.
[12] Zhou K M,Yan L P,Zhang R,et al.Easily separated and sustainable cellulose-based adsorbent using a facile two-step modification for highly efficient methylene blue removal[J].Biomass Conversion and Biorefinery,2023,13(3):432-442.
[13] Abu Alwan R,Zhuman B,Kumar M,et al.Mussel-inspired polydopamine functionalized with ionic liquid as a novel,eco-efficient adsorbent for the selective removal of anionic pollutants from aqueous solutions[J].Chemical Engineering Journal,2023,454:140498.
[14] Yang N N,Shin C H,Kim D,et al.Synthesis,characterization,and mercury removal application of surface modified kapok fibers with dopamine(DA):investigation of bidentate adsorption[J].Environmental Earth Sciences,2020,79(11):620-627.
[15] Tan H,Wang X N,Jia D D,et al.Structure-dependent electrode properties of hollow carbon micro-fibers derived from Platanus fruit and willow catkins for high-performance supercapacitors[J].Journal of Materials Chemistry A,2017,5(6):2580-2591.
[16] Xiong M H,Sun Y,Chai B,et al.Efficient peroxymonosulfate activation by magnetic CoFe2O4 nanoparticle immobilized on biochar toward sulfamethoxazole degradation:performance,mechanism and pathway[J].Applied Surface Science,2023,615(2):56-63.
[17] Tariq A,Gull M,Shaikh A J,et al.Grafting the ferrites of cobalt and zinc on MWCNTs for adsorption of crystal violet[J].International Journal of Environmental Science and Technology,2023,3(3):78-89.
[18] Li C F,Qi Y H,Li Q R,et al.Preparation and fluorescence properties of 6-carboxyfluorescein/hydrotalcite nanocomposites[J].Journal of Luminescence,2014,147:273-277.
[19] Chen S S,Cao Y W,Feng J C.Polydopamine As an efficient and robust platform to functionalize carbon fiber for high-performance polymer composites[J].ACS Applied Materials & Interfaces,2014,6(1):349-356.
[20] Lei T,Jiang X,Zhou Y,et al.A multifunctional adsorbent based on 2,3-dimercaptosuccinic acid/dopamine-modified magnetic iron oxide nanoparticles for the removal of heavy-metal ions[J].Journal of Colloid and Interface Science,2023,636:153-166.
[21] Kamran U,Bhatti H N,Noreen S,et al.Chemically modified sugarcane bagasse-based biocomposites for efficient removal of acid red 1 dye:kinetics,isotherms,thermodynamics,and desorption studies[J].Chemosphere,2022,291(2):132796.
[22] 高明,张同庆,李建军,等.磁性壳聚糖/Fe3O4/氧化石墨烯吸附剂的制备及其多染料吸附性能[J].无机化学学报,2023,39(4):723-734.
基金资助
国家自然科学基金(22202016);陕西基础科学研究院(化学、生物学)基础科学研究计划青年项目(22JHQ006);中央高校基本科研业务费资助项目(300102293204);长安大学国际教育教学改革项目(300108231136)