化工新型材料

化工新型材料 ›› 2023, Vol. 51 ›› Issue (11) : 238-245. DOI: 10.19817/j.cnki.issn1006-3536.2023.11.038

开发与应用

CO₂光热催化还原材料的进展

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Advances in photothermal catalytic materials for CO₂ reduction

Zhu Zihe¹, Li Qinghao¹, Cheng Chuanhui², Wu Kai¹, Zhou Jun¹

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文章历史 +

Received		Published
2022-07-13		2023-11-20
Issue Date	Revised Date
2023-11-29	2022-07-13

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摘要

光热催化还原CO₂作为符合国家“双碳”政策的减碳技术,将温室气体CO₂转化为重要的化学燃料和工业原料有望促进“双碳”目标早日实现。光热催化还原CO₂利用表面等离子体共振将光能转化为热能,或通过将光能和热能耦合,从而提高太阳光利用率,来催化CO₂在较为温和的条件下高效转化为碳氢燃料或工业原料,因而受到碳捕获与转化领域研究人员的高度关注。对目前光热催化还原CO₂的研究进展进行了综述,介绍了设计用于CO₂转化反应的光热催化剂的最新进展,包括CO₂加氢生成CO、CH₄、CH₃OH或C²⁺、CH₄的CO₂重整(CRM)、CO₂环加成反应等,最后分析了现阶段光热催化还原CO₂催化剂的制约因素,并对其发展前景以及面临的挑战进行了展望。

Abstract

As a carbon reduction technology in line with the national “double carbon” policy,the photothermal catalytic reduction of CO₂ is expected to contribute to the early realization of the “double carbon” goal by converting CO₂,a greenhouse gas,into important chemical fuel and industrial raw materials.Photothermal catalytic reduction of CO₂ is of great interest to researchers in the field of carbon capture and conversion because it uses surface plasmon resonance to convert light energy into heat energy,or couples light and heat energy to improve the utilization of sunlight to catalyze the efficient conversion of CO₂ into hydrocarbon fuels or industrial feedstocks under relatively mild conditions.This paper reviewed the current research progress of photothermal catalytic reduction of CO₂,introduced the latest progress of photothermal catalysts designed for CO₂ conversion reactions,including CO₂ hydrogenation to CO,CH₄,CH₃OH or C²⁺,CO₂ reforming (CRM) of CH₄,and CO₂ cycloaddition reactions,etc.Finally,it analyzed the constraints of photothermal catalytic CO₂ reduction catalysts at the present stage,and gave an outlook on their development prospects and challenges they faced.

关键词

光热催化 / CO₂还原 / 催化剂 / CH₄的CO₂重整 / 环加成

Key words

photothermal catalysis / CO₂ reduction / catalyst / CRM / cycloaddition

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CO₂光热催化还原材料的进展[J]. 化工新型材料, 2023, 51(11): 238-245 DOI:10.19817/j.cnki.issn1006-3536.2023.11.038

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