锌空气电池(ZABs)因其能量密度较大、对环境友好的特性,受到了学者的广泛研究。其空气电极是催化反应的重要场所,是整个锌空气电池的研究重点。近年来,制备高效稳定氧还原(ORR)和氧析出(OER)的电催化剂仍面临着挑战。碳基材料拥有较高的比表面积、多的表面活性位点和缺陷位点含量,是一类极具潜力的催化材料。针对碳基催化剂在锌空气电池中的应用,综述了近几年碳基催化剂的应用进展,并对未来碳基催化剂的发展进行了展望。
Zn-air batteries (ZABs) have garnered widespread concern because of the high energy density and environmental friendliness.As the core site of the catalytic reaction,the air electrode is the research focus of the entire Zn-air battery.In recent years,the preparation of highly efficient and stable electrocatalysts for oxygen reduction (ORR) and oxygen evolution (OER) still faces challenges.Carbon-based materials have large specific surface area,numerous surface-active sites and defect sites content,and are potential catalytic materials.For the application of carbon-based catalysts in Zn-air batteries,the application progress of carbon-based catalysts in recent years was reviewed,and the future development of carbon-based catalysts was prospected.
[1] Wang H F,Xu Q.Materials design for rechargeable metal-air batteries[J].Matter,2019,1(3):565-595.
[2] 季东晓.氧催化电纺碳纤维的设计和制备及其在柔性锌空气电池中的应用[D].上海:东华大学,2018.
[3] ul Hasan Israr Masood,Peng Luwei,Mao Jianfeng,et al.Carbon-based metal-free catalysts for electrochemical CO2 reduction:activity,selectivity,and stability[J].Carbon Energy,2021,3(1):24-49.
[4] 翁晓琳,刘佩佩,刘江,等.锌空气电池研究进展[J].电源技术,2019,43(4):716-719.
[5] Kim S W,Yun J H,Son B,et al.Graphite/silicon hybrid electrodes using a 3D current collector for flexible batteries[J].Advanced Materials,2014,26(19):2977-2982.
[6] Zhang Y,Deng Y P,Wang J,et al.Recent progress on flexible Zn-air batteries[J].Energy Storage Materials,2021,35:538-549.
[7] Pan J,Xu Y Y,Yang H,et al.Advanced architectures and relatives of air electrodes in Zn-air batteries[J].Advanced Science,2018,5(4):1700691.
[8] 许可,王保国.锌-空气电池空气电极研究进展[J].储能科学与技术,2017,6(5):924-940.
[9] 武巍,田艳艳,高军,等.碳材料在锂空气电池中的应用及研究进展[J].电源技术,2012,36(4):581-586.
[10] Fang W,Zhao J,Zhang W,et al.Recent progress and future perspectives of flexible Zn-Air batteries[J].Journal of Alloys and Compounds,2021,869:158918.
[11] 邹小康,何建橙,郭雷,等.锌-空气电池的研究现状及发展前景[J].山东化工,2019,48(2):66-67,69.
[12] Jiang L,Cheng X B,Peng H J,et al.Carbon materials for traffic power battery[J].ETransportation,2019,2:100033.
[13] 吴雷,彭犇,周军,等.碳基非贵金属电催化剂研究进展[J].材料导报,2020,34(23):23009-23019.
[14] 杜亚东,孟祥桐,汪珍,等.石墨烯基二氧化碳电化学还原催化剂的研究进展[J].物理化学学报,2022,38(2):84-100.
[15] 李小娟,叶兰妹,廖凤珍,等.杂原子掺杂碳材料活化过硫酸盐技术的研究进展[J].化工进展,2021,40(1):273-281.
[16] 翟作昭,许跃龙,任斌,等.氮掺杂多孔炭材料的研究进展[J].炭素技术,2021,40(2):6-11.
[17] Zhang Z,Yu L,Tu Y,et al.Unveiling the active site of metal-free nitrogen-doped carbon for electrocatalytic carbon dioxide reduction[J].Cell Reports Physical Science,2020,1(8):100145.
[18] Ayala P,Arenal R,Loiseau A,et al.The physical and chemical properties of heteronanotubes[J].Reviews of Modern Physics,2010,82(2):1843.
[19] 刘京,宋平,阮明波,等.氮掺杂的碳材料中石墨化氮和吡啶氮对氧还原反应的催化特性(英文)[J].催化学报,2016,37(7):1119-1126.
[20] Yang D,Chen D,Jiang Y,et al.Carbon-based materials for all-solid-state zinc-air batteries[J].Carbon Energy,2021,3(1):50-65.
[21] 赵国庆,袁钊,王连,等.磷化镍/氮硫双掺杂石墨烯复合材料的制备及电催化析氢性能[J].高等学校化学学报,2020,41(7):1575-1581.
[22] 吕梁.碳基电催化剂的可控制备及其锌——空气电池性能研究[D].呼和浩特:内蒙古大学,2021.
[23] 于永信.过渡金属—氮共掺杂碳材料的制备及其在氧还原和超级电容器方面的应用[D].昌吉:昌吉学院,2018.
[24] Liu H,Wang S,Long L,et al.Carbon-nanotube-entangled Co,N-codoped carbon nanocomposite for oxygen reduction reaction[J].Nanotechnology,2021,32(20):205402.
[25] Han S,Chen Y,Hao Y,et al.Multi-dimensional hierarchical CoS2@MXene as trifunctional electrocatalysts for zinc-air batteries and overall water splitting[J].Science China Materials,2021,64(5):1127-1138.
[26] Li L,Chen J,Wang S,et al.MOF-derived CoN/CoFe/NC bifunctional electrocatalysts for zinc-air batteries[J].Applied Surface Science,2022,582:152375.
[27] Li X,Wu Z,Tao X,et al.Gentle one-step co-precipitation to synthesize bimetallic CoCu-MOF immobilized laccase for boosting enzyme stability and Congo red removal[J].Journal of Hazardous Materials,2022,438:129525.
[28] Li Z,Yang J,Ge X,et al.Self-assembly of colloidal MOFs derived yolk-shelled microcages as flexible air cathode for rechargeable Zn-air batteries[J].Nano Energy,2021,89:106314.
[29] Liu Y,Chen Z,Zhao N,et al.Ultra-small cobalt nanoparticles embedded into N-doped hierarchical porous carbon derived from ion-exchange MOFs as high-efficient bifunctional catalysts for rechargeable Zn-air battery[J].Chemical Engineering Journal,2022,433:134469.
[30] Ma L,Svec F,Lv Y,et al.Engineering of the filler/polymer interface in metal-organic framework-based mixed-matrix membranes to enhance gas separation[J].Chemistry-An Asian Journal,2019,14(20):3502-3514.
[31] Yao Z,Chen D,Li Y,et al.MOF-derived multi-metal embedded N-doped carbon sheets rich in CNTs as efficient bifunctional oxygen electrocatalysts for rechargeable ZABs[J].International Journal of Hydrogen Energy,2022,47(2):984-992.
[32] Ge L,Lin R,Zhu Z,et al.A nitrogen-doped electrocatalyst from metal-organic framework-carbon nanotube composite[J].Journal of Materials Research,2018,33(5):538-545.
基金资助
新疆维吾尔自治区研究生科研创新项目(XJ2022GO44)