三维反蛋白石结构在介观钙钛矿太阳电池中的应用

李林杰, 余龙, 白雪, 熊艳*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (11) : 176 -179.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (11) : 176-179. DOI: 10.19817/j.cnki.issn1006-3536.2023.11.015
科学研究

三维反蛋白石结构在介观钙钛矿太阳电池中的应用

    李林杰, 余龙, 白雪, 熊艳*
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Application of three-dimensional inverse opal in mesoscopic perovskite solar cells

  • Li Linjie, Yu Long, Bai Xue, Xiong Yan
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摘要

介观钙钛矿太阳电池具有稳定性好、成本低和可产业化等优点而备受关注,电池结构中作为活性层的钙钛矿敏化的多孔TiO2层对于器件性能具有较大的影响。以聚苯乙烯(PS)微球作为模板制备了三维反蛋白石TiO2,并将其应用于碳基介观钙钛矿太阳电池,探究了采用不同尺寸的PS微球制备的反蛋白石TiO2对碳基介观钙钛矿太阳电池光电性能的影响。结果表明:采用直径为800nm的PS微球作为模板制备的电池器件在可见光范围内具有良好的吸收,获得了2.10%的光电转换效率。

Abstract

Mesoscopic perovskite solar cells have attracted much attention due to their good stability,low cost and ease of industrialization.As the active layer in the solar cell,the perovskite-sensitized porous TiO2 layer plays an important role in the performance of the devices.Three-dimensional inverse opal TiO2 was prepared using polystyrene (PS) microspheres as template,and it was applied to carbon-based mesoscopic perovskite solar cells.The effect of TiO2 inverse opal prepared with PS microspheres of different sizes on the photoelectric properties of the solar cells was investigated.The results indicated that the cell device prepared using PS microspheres with a diameter of 800nm as template had relatively high absorption in the visible light range,and the photoelectric conversion efficiency was 2.10%.

关键词

钙钛矿太阳电池 / 模板法 / 介孔二氧化钛 / 电子传输层

Key words

perovskite solar cell / template method / mesoporous titanium dioxide / electron transport layer

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三维反蛋白石结构在介观钙钛矿太阳电池中的应用[J]. 化工新型材料, 2023, 51(11): 176-179 DOI:10.19817/j.cnki.issn1006-3536.2023.11.015

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基金资助

湖北省高等学校优秀中青年科技创新团队计划项目(T2020008)

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