随着工业和农业高水平的发展,工业废气的过量排放,对全球气候和环境产生了重大影响。开发一种灵敏度高、操作简单的检测方法,对于环境监测具有重要意义。后修饰MOF材料兼具了MOF的孔隙率高、比表面积大、孔径可调、化学稳定性等优点和光致发光特性,同时在荧光传感方面展现出易于诱导发光、结构和功能成分多样以及检测机制多样等优点,因而在工业废气荧光检测领域表现出良好的应用前景。主要介绍了金属有机框架材料的改性策略及方法,评述近年来后修饰MOF材料对工业有毒气体和挥发性有机物的荧光传感的研究进展,并对后修饰MOF材料面临的问题与挑战和未来的发展方向进行了展望。
With the development of high-level industry and agriculture,excessive emission of industrial exhaust gases has had a significant impact on the global climate and environment.Developing a highly sensitive and operationally simple detection method is of great significance for environmental monitoring.Post-synthetic modification MOF materials have the advantages of high porosity,large specific surface area,tunable pore size,chemical stability,and luminescence properties,while exhibiting diverse advantages in terms of inducible fluorescence,structural and functional diversity and diverse detection mechanisms,thus making them ideal for fluorescence detection industrial exhaust gases.This paper mainly introduced the modification strategies and methods of metal-organic framework (MOF) materials,and then reviewed the research progress of post-synthetic modification MOF materials for fluorescence sensing of industrial toxic gases and volatile organic compounds in recent years,and prospected the problems,challenges and future development directions of post-synthetic modification MOF materials.
[1] Woellner M,Hausdorf S,Klein N,et al.Adsorption and detection of hazardous trace gases by metal-organic frameworks[J].Advanced Materials,2018,30:1704679.
[2] Yang G D,Wu L Y,Jiang B,et al.H2S as a Physiologic vasorelaxant:hypertension in mice with deletion of cystathionine γ-lyase[J].Science,2008,322:587-590.
[3] Wang H,Lustig W P,Li J.Sensing and capture of toxic and hazardous gases and vapors by metal-organic frameworks[J].Chemical Society Reviews,2018,47:4729-4756.
[4] Barea E,Montoro C,Navarro J A R.Toxic gas removal metal-organic frameworks for the capture and degradation of toxic gases and vapours[J].Chemical Society Reviews,2014,43:5419-5430.
[5] Yaghi O M,Li H L,Eddaoudi M,et al.Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J].Nature,1999,402:276-279.
[6] Zhang Y,Yuan S,Day G,et al.Luminescent sensors based on metal-organic frameworks[J].Coordination Chemistry Reviews,2018,354:28-45.
[7] Ding M,Cai X,Jiang H L.Improving MOF stability:approaches and applications[J].Chemical Science,2019,10:10209-10230.
[8] Halper S R,Do L,Stork J R,et al.Topological control in heterometallic metal-organic frameworks by anion templating and metalloligand design[J].Journal of the American Chemical Society,2006,128:15255.
[9] Yu Q Y,Li Z,Cao Q,et al.Advances in luminescent metal-organic framework sensors based on post-synthetic modification[J].Trends in Analytical Chemistry,2020,129:115939.
[10] Figueroa-Quintero L,Villalgordo-Hernández D,Delgado-Marín J J,et al.Post-synthetic surface modification of metal-organic frameworks and their potential applications[J].Small Methods,2023,7(4):e2201413.
[11] Tanabe K K,Cohen S M.Postsynthetic modification of metal-organic frameworks-a progress report[J].Chemical Society Reviews,2011,40:498.
[12] Qu S M,Cao Q,Ma J T,et al.A turn-on fluorescence sensor for creatinine based on the quinoline-modified metal organic frameworks[J].Talanta,2020,219:121280.
[13] 龚文朋,田超强,杜晓刚,等.H6P2Mo18O62/Zn(BDC)(Bipy)0.5复合材料的合成、表征及对亚甲基蓝的吸附[J].高等学校化学学报,2016,37(9):1596-1604.
[14] Deng J J,Wang K,Wang M,et al.Mitochondria targeted nanoscale zeolitic imidazole framework-90 for ATP imaging in live cells[J].Journal of the American Chemical Society,2017,139:5877-5882.
[15] Du Y,Li X,Lv X,et al.Highly sensitive and selective sensing of free bilirubin using metal-organic frameworks-based energy transfer process[J].ACS Applied Materials & Interfaces,2017,9:30925-30932.
[16] Wang Z,Cohen S M.Postsynthetic modification of metal-organic frameworks[J].Chemical Society Reviews,2009,38:1315-1329.
[17] Wang Z,Cohen S M.Tandem modification of metal-organic frameworks by a postsynthetic approach[J].Angewandte Chemie International Edition,2008,47:4699-4703.
[18] Mei Douchao,Yan Bing.Flumequine-mediated fluorescent zeolitic imidazolate framework functionalized by Eu3+ for sensitive and selective detection of UO2+2,Ni2+ and Cu2+ in nuclear wastewater[J].Journal of Hazardous Materials,2023,447:130822.
[19] Cogliano V J,Grosse Y,Baan R A,et al.Meeting report:summary of IARC monographs on formaldehyde,2-butoxyethanol,and 1-tert-butoxy-2-propanol[J].Environmental Health Perspectives,2005,113:1205-1211.
[20] Yang G D,Wu L Y,Jiang B,et al.H2S as a Physiologic vasorelaxant:hypertension in mice with deletion of cystathionine γ-lyase[J].Science,2008,322:587-590.
[21] Wang Y,Mu Q,Wang G,et al.Sensing characterization to NH3 of nanocrystalline Sb-doped SnO2 synthesized by a nonaqueous sol-gel route[J].Sensors and Actuators B-Chemical,2010,145:847-853.
[22] Hao J N,Yan B.A dual-emitting 4d-4f nanocrystalline metal-organic framework as a self-calibrating luminescent sensor for indoor formaldehyde pollution[J].Nanoscale,2016,8:12047-12053.
[23] Xu X Y,Yan B.Eu(ⅲ)-functionalized ZnO@MOF heterostructures:integration of pre-concentration and efficient charge transfer for the fabrication of a ppb-level sensing platform for volatile aldehyde gases in vehicles[J].Journal of Materials Chemistry A,2017,5:2215-2223.
[24] Min J,Qu X L,Yan B.Tb post-functionalized La(Ⅲ) metal organic framework hybrid probe for simple and highly sensitive detection of acetaldehyde[J].Sensors and Actuators B-Chemical,2019,300:126985-126994.
[25] Yang G D,Wu L Y,Jiang B,et al.H2S as a physiologic vasorelaxant:hypertension in mice with deletion of cystathionine γ-lyase[J].Science,2008,322:587-590.
[26] Zhu J,Tang Y,Yang Y,et al.Post-modified metal-organic framework as a turn-on fluorescent probe for potential diagnosis of neurological diseases[J].Microporous and Mesoporous Materials,2019,288:109610-109618.
[27] Zhang X,Fang L,Jiang K,et al.Nanoscale fluorescent metal-organic framework composites as a logic platform for potential diagnosis of asthma[J].Biosensors and Bioelectronics,2019,130:65-72.
[28] Zhang X,Hu Q,Xia T F,et al.Turn-on and ratiometric luminescent sensing of hydrogen sulfide based on metal-organic frameworks[J].ACS Applied Materials & Interfaces,2016,8:32259-32265.
[29] Buragohain A,Biswas S.Cerium based azide-and nitro-functionalized UiO-66 frameworks as turn-on fluorescent probes for the sensing of hydrogen sulphide[J].CrystEngComm,2016,18:4374-4381.
[30] Zhang X,Zhang J M,Hu Q,et al.Postsynthetic modification of metal-organic framework for hydrogen sulfide detection[J].Applied Surface Science,2015,355:814-819.
[31] Zhu Z,He Xiang,Wang W N.Unraveling the origin of the “Turn-On” effect of Al-MIL-53-NO2 during H2S detection[J].CrystEngComm,2020,22:195-204.
[32] Nagarkar S S,Desai A V,Ghosh S K.Metal-organic framework as a reaction-based fluorescence turn-on probe for rapid and selective H2S detection[J].Chemistry-A European Journal,2015,21:9994-9997.
[33] Nagarkar S S,Saha T,Desai A V,et al.Metal-organic framework based highly selective fluorescence turn-on probe for hydrogen sulphide[J].Scientific Reports,2014,4:7053-7068.
[34] Zhang X,Hu Q,Xia T F,et al.Turn-on and ratiometric luminescent sensing of hydrogen sulfide based on metal-organic frameworks[J].ACS Applied Materials & Interfaces,2016,8:32259-32265.
[35] Cao Y Y,Guo X F,Wang H.High sensitive luminescence metal-organic framework sensor for hydrogen sulfide in aqueous solution:a trial of novel turn-on mechanism[J].Sensors and Actuators,B:Chemical,2017,243:8-13.
[36] Dalapati R,Balaji S N,Trivedi V,et al.A dinitro-functionalized Zr(Ⅳ)-based metal-organic framework as colorimetric and fluorogenic probe for highly selective detection of hydrogen sulphide[J].Sensors and Actuators,B:Chemical,2017,245:1039-1049.
[37] Li Y,Zhang X,Zhang L,et al.A nanoscale Zr-based fluorescent metal-organic framework for selective and sensitive detection of hydrogen sulfide[J].Journal of Solid State Chemistry,2017,255:97-101.
[38] Zhang X,Zhang Q,Yue D,et al.Flexible metal-organic framework-based mixed-matrix membranes:a new platform for H2S sensors[J].Small,2018,14:1801563-1801569.
[39] Pan M,Liao W M,Yin S Y,et al.Single-phase white-light-emitting and photoluminescent color-tuning coordination assemblies[J].Chemical Reviews,2018,118:8889-8935.
[40] Yu H Z,Liu C Y,Li Y H,et al.Functionalized metal-organic framework UiO-66-NH-BQB for selective detection of hydrogen sulfide and cysteine[J].ACS Applied Materials & Interfaces,2019,11(45):41972-41978.
[41] Gong W P,Zhang L,Yu Y,et al.A novel fluorescent strategy based on double modifications of metal organic framework material CAU-10-NH2 for low background and high sensitivity determination of H2S[J].Talanta,2021,229:122271.
[42] Gibson L E,Wright D W.Sensitive method for biomolecule detection utilizing signal amplification with porphyrin nanoparticles[J].Analytical Chemistry,2016,88:5928-5938.
[43] Tang Y,Chen J,Wu H,et al.A highly fluorescent post-modified metal organic framework probe for selective,reversible and rapid carbon dioxide detection[J].Dyes Pigments,2020,172:107798.
[44] Sen A,Desai A V,Samanta P,et al.Post-synthetically modified metal-organic framework as a scaffold for selective bisulphite recognition in water[J].Polyhedron,2018,156:1-5.
[45] Wang P,Liu J,Lv X,et al.A naphthalimide-based glyoxal hydrazone for selective fluorescence turn-on sensing of cys and hcy[J].Organic Letters,2012,14(2):520-523.
[46] Zhu S Y,Yan B.A novel sensitive fluorescent probe of S2O2-8 and Fe3+ based on covalent post-functionalization of a zirconium(Ⅳ) metal-organic framework[J].Dalton Transactions,2018,47:11586-11592.
[47] Li H Y,Zhao S N,Zang S Q,et al.Functional metal-organic frameworks as effective sensors of gases and volatile compounds[J].Chemical Society Reviews,2020,49:6364-6401.
[48] Du Y,Li X,Zheng H,et al.Design of a calix[4]arene-functionalized metal-organic framework probe for highly sensitive and selective monitor of hippuric acid for indexing toluene exposure[J].Analytica Chimica Acta,2018,1001:134-142.
[49] Sun N,Yan B.Ag+-induced photoluminescence enhancement in lanthanide post-functionalized MOFs and Ag+ sensing[J].Physical Chemistry Chemical Physics,2017,19:9174-9180.
[50] Chen B L,Wang L B,Zapata F,et al.A luminescent microporous metal-organic framework for the recognition and sensing of anions[J].Journal of the American Chemical Society,2008,130:6718-6719.
[51] Gao N,Huang J,Wang L,et al.Ratiometric fluorescence detection of phosphate in human serum with a metal-organic frameworks-based nanocomposite and its immobilized agarose hydrogels[J].Applied Surface Science,2018,459:686-692.
[52] Li Y,Jiang K,Zhang J,et al.A turn-on fluorescence probe based on post-modified metal-organic frameworks for highly selective and fast-response hypochlorite detection[J].Polyhedron,2018,148:76-80.
[53] Zhou Z,Li X,Tang Y,Z,et al.Oxidative deoximation reaction induced recognition of hypochlorite based on a new fluorescent lanthanide-organic framework[J].Chemical Engineering Journal,2018,351:364-370.
[54] Zeng Y N,Zheng H Q,Gu J F,et al.Dual-emissive metal-organic framework as a fluorescent “switch” for ratiometric sensing of hypochlorite and ascorbic acid[J].Inorganic Chemistry,2019,58:13360-13369.
基金资助
黄冈师范学院博士基金项目(2042021036)
PDF
