木材是一种绿色环保、成本较低的天然材料,木材功能化改性是目前的研究热点。介绍了木材脱除组分、冷冻处理、高温碳化和浸渍处理的功能化改性方法。阐述了以木材孔道结构为出发点,对其进行功能化处理,并应用于油水分离、海水淡化、储能器件领域。结合相关研究方法及内容,提出木材功能化改性应用中存在的问题,并对其应用前景进行展望。
Wood is a natural material with low cost and environmental protection.The functional modification of wood has become a research hotspot.The functional modification methods of wood including removing components,freezing treatment,high-temperature carbonization and impregnation were introduced.Taking the wood pore structure as a starting point to carry out the functional treatment of wood and application to the fields of oil-water separation,seawater desalination and energy storage devices.By combining the relevant research methods and contents,the existing problems in the application of wood functional modification were presented,and the application prospect was discussed.
[1] 张明,杜西领,时君友,等.功能化木材在水污染净化领域的研究进展[J].生物质化学工程,2021,55(2):60-70.
[2] Chen C J,Kuang Y D,Zhu S Z,et al.Structure-property-function relationships of natural and engineered wood[J].Nature Reviews Materials,2020,5(9):642-666.
[3] Chen C J,Hu L B.Ion transport and regulation:nanoscale ion regulation in wood-based structures and their device applications[J].Advanced Materials,2021,33(28):2002890.
[4] 杨鸿,赵鹏炜,牟洪波,等.脱木素木材衍生功能材料研究进展[J].世界林业研究,2022,35(3):50-55.
[5] 陆弘毅,丁春香,翟胜丞,等.透明木材的性能及其应用研究进展[J].高分子通报,2021(7):13-26.
[6] 徐永建,张娅倩,祝萌,等.透明木材及其功能化研究进展[J].中国造纸,2021,40(5):88-94.
[7] Tang Q,Fang L,Wang Y F,et al.Anisotropic flexible transparent films from remaining wood microstructures for screen protection and AgNW conductive substrate[J].Nanoscale,2018,10(9):4344-4353.
[8] 吴燕,韩岩,黄楠,等.脱木素工艺对透明木材性能的影响[J].林业工程学报,2019,4(6):98-104.
[9] Xiao S L,Chen C J,Xia Q,et al.Lightweight,strong,moldable wood via cell wall engineering as a sustainable structural material.[J].Science (New York,N.Y.),2021,374(6566):465-471.
[10] He Y,Li H,Guo X,et al.Delignified wood-based highly efficient solar steam generation device via promoting both water transportation and evaporation[J].Bioresources,2019,14(2):3758-3767.
[11] Tang J B,Zheng T,Song Z P,et al.Realization of low latent heat of solar evaporator via regulating water state in wood channels[J].ACS Applied Materials & Interfaces,2020,12(16):18504-18511.
[12] Peng X W,Zhang L,Chen Z X,et al.Hierarchically porous carbon plates derived from wood as bifunctional ORR/OER electrodes[J].Advanced Materials,2019,31(16):1900341.
[13] Guan H,Cheng Z Y,Wang X Q.Highly compressible wood sponges with a spring-like lamellar structure as effective and reusable oil absorbents.[J].ACS Nano,2018,12(10):10365-10373.
[14] Wu M B,Huang S,Liu C,et al.Carboxylated wood-based sponges with underoil superhydrophilicity for deep dehydration of crude oil[J].Journal of Materials Chemistry A,2020,8(22):11354-11361.
[15] 张耀丽,苗平,庄寿增,等.微波、冷冻预处理对改善尾巨桉木材干燥性能的影响[J].南京林业大学学报(自然科学版),2011,35(2):61-64.
[16] 韩颖.冷冻技术在木材加工中的应用探讨[J].林业机械与木工设备,2020,48(8):4-6.
[17] 李坚,高丽坤.新型木质基电催化析氧析氢材料的研究进展[J].森林与环境学报,2021,41(4):337-342.
[18] Chen C J,Song J W,Zhu S Z,et al.Scalable and sustainable approach toward highly compressible,anisotropic,lamellar carbon sponge[J].Chem,2018,4(3):544-554.
[19] 卢芸,李景鹏,张燕,等.木基炭微纳功能骨架[J].化学进展,2020,32(7):906-916.
[20] 姚团威.含油废水性质及其处理技术[J].化工设计通讯,2018,44(12):214.
[21] 姜晓峰,于维钊,王继乾.油水分离用天然材料表面化学研究进展[J].化学通报,2021,84(4):290-304+321.
[22] 杜国勇,杨月,王永红.含油废水吸附处理技术研究综述[J].应用化工,2021,50(9):2490-2495.
[23] Blanco M,Fischer E J,Cabane E,Underwater superoleophobic wood cross sections for efficient oil/water separation[J].Advanced Materials Interfaces,2017,4(21):1700584.
[24] Yong J,Chen F,Huo J,et al.Green,biodegradable,underwater superoleophobic wood sheet for efficient oil/water separation[J].ACS Omega,2018,3(2):1395-1402.
[25] Fu Q L,Ansari F,Zhou Q,et al.Wood nanotechnology for strong,mesoporous,and hydrophobic biocomposites for selective separation of oil/water mixtures.[J].ACS Nano,2018,12(3):2222-2230.
[26] Wu M B,Huang S,Liu T Y,et al.Compressible carbon sponges from delignified wood for fast cleanup and enhanced recovery of crude oil spills by joule heat and photothermal effect[J].Advanced Functional Materials,2020,31(3):2006806.
[27] Zhu M W,Li Y J,Chen G,et al.Tree-inspired design for high-efficiency water extraction[J].Advanced Materials,2017,29(44):1704107.
[28] Kuang Y D,Chen C J,He S M,et al.A high-performance self-regenerating solar evaporator for continuous water desalination[J].Advanced Materials,2019,31(23):1900498.
[29] Lei Y H,Xie L J,Cao S J,et al.Application of wooden arrays in solar water evaporation and desalination[J].Materials Today Communications,2021,29:102819.
[30] Jia C,Li Y J,Yang Z,et al.Rich mesostructures derived from natural woods for solar steam generation[J].Joule,2017,1(3):588-599.
[31] He S,Chen C,Kuang Y,et al.Nature-inspired salt resistant bimodal porous solar evaporator for efficient and stable water desalination[J].Energy & Environmental Science,2019,12(5):1558-1567.
[32] Chen T J,Wu Z Z,Liu Z Y,et al.Hierarchical porous aluminophosphate-treated wood for high-efficiency solar steam generation[J].ACS Applied Materials & Interfaces,2020,12(17):19511-19518.
[33] Wang Z,Yan Y T,Shen X P,et al.Candle soot nanoparticle-decorated wood for efficient solar vapor generation[J].Sustainable Energy & Fuels,2019,4(1):354-361.
[34] Li D,Han D,Guo C,et al.Facile preparation of MnO2 deposited wood for high-efficiency solar steam generation[J].ACS Applied Energy Materials,2021,4(2):1752-1762.
[35] Chen C J,Hu L B.Nanocellulose toward advanced energy storage devices:structure and electrochemistry[J].Accounts of Chemical Research,2018,51(12):3154-3165.
[36] Teng S,Siegel G,Wang W.Carbonized wood for supercapacitor electrodes[J].ECS Solid State Letters,2014,3(5):25-28.
[37] 辛福恩,刘沛静.基于木材制备各向异性孔道结构的厚层碳电极材料的探究[J].化学工程师,2019,33(10):13-16,31.
[38] Chen C J,Zhang Y,Li Y J,et al.Highly conductive,lightweight,low-tortuosity carbon frameworks as ultrathick 3D current collectors[J].Advanced Energy Materials,2017,7(17):1700595.
[39] Chen C J,Zhang Y,Li Y J,et al.All-wood,low tortuosity,aqueous,biodegradable supercapacitors with ultra-high capacitance[J].Energy & Environmental Science,2017,10(2):538-545.
基金资助
国家自然科学基金(31971587)