层层自组装作为一种纳米表面图案化技术,具有操作过程简单、实施成本低、结构动态可控、适用材料广泛等特点,其中动态可控表面微结构赋予了材料独特的理化性能,是智能材料领域研究的热点。该技术在生物医药、传感器、信息存储、膜分离等领域具有广阔的应用前景。综述了基于层层自组装技术的智能表面材料及其在不同领域的应用进展,并对其发展前景进行了展望。
Layer-by-layer self-assembly technology,as a nano surface patterning technology,has the characteristics of simple operation process,low implementation cost,dynamically controllable structure and wide range of applicable materials.The dynamically controllable surface microstructure gives the material unique physical and chemical properties,which is a research hotspot in the field of smart materials.This technology has broad application prospects in biomedicine,sensors,information storage,membrane separation and other fields.In this paper,the progress of smart surface materials based on layer-by-layer self-assembly technology and their applications in different fields were reviewed,and their development prospects were discussed.
[1] 施政余,李梅,赵燕,等.润湿性可控智能表面的研究进展[J].材料研究学报,2008,22(6):561-571.
[2] Ma Q,Cao J,Gao Y,et al.Microfluidic-mediated nano-drug delivery systems:from fundamentals to fabrication for advanced therapeutic applications[J].Nanoscale,2020,12(29):15512-15527.
[3] Gharbavi M,Johari B,Eslami S S,et al.Cholesterol-conjugated bovine serum albumin nanoparticles as a tamoxifen tumor-targeted delivery system[J].Cell Biology International,2020,44(12):2485-2498.
[4] Brandt J V,Piazza R D,Carvalho C,et al.Synthesis of core@shell nanoparticles functionalized with folic acid-modified PCL-co-PEGMA copolymer for methotrexate delivery[J].Nano-Structures & Nano-Objects,2021,25:100675.
[5] Lucena G N,Santos C,Pinto G C,et al.Surface engineering of magnetic nanoparticles for hyperthermia and drug delivery[J].Medical Devices & Sensors,2020,3(6):10100.
[6] Chen X C,Huang W P,Hu M,et al.Controlling structural transformation of polyelectrolyte films for spatially encapsulating functional species[J].Small,2019,15(9):1804867.
[7] Dong Z,Zhang N,Wang Y,et al.Photopatternable nanolayered polymeric films with fast tunable color responses triggered by humidity[J].Advanced Functional Materials,2019,29(43):1904453.
[8] Huang W P,Qian H L,Wang J,et al.Periodic stratified po-rous structures in dynamic polyelectrolyte films through standing-wave optical crosslinking for structural color[J].Advanced Science,2021,8(15):2100402.
[9] Chen X C,Ren K F,Wang J,et al.Infusing lubricant onto erasable microstructured surfaces toward guided sliding of li-quid droplets[J].ACS Appl Mater Interfaces,2017,9(2):1959-1967.
[10] 赵亚梅,丁思奇,曹婷婷,等.超疏水材料的制备及其在海洋领域中应用的研究进展[J].化工新型材料,2022,50(1):34-38.
[11] Wolter K J,Gerlach G.Nano- and biotechniques in electronic packaging[J].IEEE Nanotechnology Magazine,2010,4(1):23-27.
[12] Decher G,Hong J D,Schmitt J,et al.Buildup of ultrathin multilayer films by a self-assembly process:Ⅲ.Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces[J].Thin Solid Films,1992,210-211(2):831-835.
[13] Borges J,Mano J F.Molecular interactions driving the layer-by-layer assembly of multilayers[J].Chemical Reviews,2014,114(18):8883-8942.
[14] Ning D,Hui Z,Yang D.One-dimensional hybrid nanostructures:synthesis via layer-by-layer assembly and applications[J].Nanoscale,2012,4(18):5517-5526.
[15] Pahal S,Gakhar R,Raichur A M,et al.Polyelectrolyte multilayers for bio-applications:recent advancements[J].Nanobiotechnology Let,2017,11(8):903-908.
[16] Ariga K,Yanauchci Y,Rydzek G,et al.Layer-by-layer nanoarchitectonics:invention,innovation,and evolution[J].Chemistry Letters,2014,43(1):36-68.
[17] Salom K M,Vinokurov I A,Kankare J.Effect of temperature on the buildup of polyelectrolyte multilayers[J].Langmuir the ACS Journal of Surfaces & Colloids,2005,21(24):11232-11240.
[18] Mengal N,Arbab A A,Memon A A,et al.A promising hybrid graphite counter electrode doped with fumed silica nano-spacers for efficient quasi-solid state dye sensitized solar cells[J].Electrochimica Acta,2017,261:246-255.
[19] Sun Y X,Ren K F,Wang J L,et al.Electrochemically controlled stiffness of multilayers for manipulation of cell adhesion[J].ACS Applied Materials & Interfaces,2013,5(11):4597-4602.
[20] Chang H,Ren K F,Wang J L,et al.Surface-mediated functional gene delivery:an effective strategy for enhancing competitiveness of endothelial cells over smooth muscle cells[J].Biomaterials,2013,34(13):3345-3354.
[21] Petrila L M,Bucatariu F,Mihai M,et al.Polyelectrolyte multilayers:an overview on fabrication,properties,and biomedical and environmental applications[J].Materials,2021,14(15):4152.
[22] Tulchinsky E,Demido O,Kriajevska M,et al.EMT:a mechanism for escape from EGFR-targeted therapy in lung cancer[J].Biochimica Et Biophysica Acta (BBA)-Reviews on Can-cer,2019,1871(1):29-39.
[23] Li C,Wang J,Lu X,et al.Hydrogen peroxide-response nanoprobe for CD44-targeted circulating tumor cell detection and H2O2 analysis[J].Biomaterials,2021,255:120071.
[24] Zhang X,Liang T,Ma Q.Layer-by-Layer assembled nano-drug delivery systems for cancer treatment[J].Drug Delivery,2021,28(1):655-669.
[25] Soleymani M,Khalighfard S,Khodayari S,et al.Effects of multiple injections on the efficacy and cytotoxicity of folate-targeted magnetite nanoparticles as theranostic agents for MRI detection and magnetic hyperthermia therapy of tumor cells[J].Scientific Reports,2020,10(1):1695.
[26] Dreaden E C,Morton S W,Shopsowitz K E,et al.Bimodal tumor-targeting from microenvironment responsive hyaluronan layer-by-layer (LbL) nanoparticles[J].ACS Nano,2014,8(8):8374-8382.
[27] Chen X C,Huang W P,Ren K F,et al.Self-healing label materials based on photo-cross-linkable polymeric films with dynamic surface structures[J].ACS Nano,2018,12(8):8686-8696.
[28] Chen X C,Huang W P,Ferreira L,et al.Spatially confining surface roughness on exponentially growing polyelectrolyte multilayer films[J].Advanced Materials Interfaces,2019,6(17):1900702.
[29] Sanjuan S,Tran Y.Stimuli-responsive interfaces using random polyampholyte brushes[J].Macromolecules,2008,41(22):861-866.
[30] Li D,He Q,Yang Y,et al.Two-stage pH response of poly(4-vinylpyridine) grafted gold nanoparticles[J].Macromolecules,2008,41(19):7254-7256.
[31] Motornov M,Sheparovych R,Katz E,et al.Chemical gating with nanostructured responsive polymer brushes:mixed brush versus homopolymer brush[J].ACS Nano,2008,2(1):41-52.
[32] Gu Y,Weinheimer E K,Ji X,et al.Response of swelling behavior of weak branched poly(ethylene imine)/poly(acrylic acid) polyelectrolyte multilayers to thermal treatment[J].Langmuir,2016,32(24):6020-6027.
[33] 雷红艳.表面修饰环境响应性聚合物及其对蛋白质吸附的调控[D].苏州:苏州大学,2014.
[34] Quinn J F,Caruso F.Facile tailoring of film morphology and release properties using layer-by-layer assembly of thermoresponsive materials[J].Langmuir,2004,20(1):20-22.
[35] Qian S,Nie H,Li S,et al.Synthesis and application of photo-responsive polymers[J].Scientia Sinica Chimica,2019,49(5):704-715.
[36] Uichi A,Daichi M,Jun-Ichi A.Photosensitive layer-by-layer assemblies containing azobenzene groups:synthesis and biomedical applications[J].Polymers,2017,9(11):553.
[37] 江兵兵,宋琼芳,陈明,等.层层自组装功能化涂层及其生物应用研究进展[J].湖北大学学报(自然科学版),2017,39(6):639-645.
[38] Fan F,Wang L,Li F,et al.Stimuli-responsive layer-by-layer tellurium-containing polymer films for the combination of chemotherapy and photodynamic therapy[J].ACS Appl Mater Interfaces,2016,8(26):17004-17010.
[39] Priya A P,Mohan R R,Vasanthakumar A V,et al.Curcumin-loaded layer-by-layer folic acid and casein coated carboxymethyl cellulose/casein nanogels for treatment of skin cancer-science direct[J].Arabian Journal of Chemistry,2020,13(1):694-708.
[40] Li Z,Yuan D,Jin G,et al.Facile layer-by-layer self-assembly toward enantiomeric poly(lactide) stereocomplex coated magnetite nanocarrier for highly tunable drug deliveries[J].ACS Appl Mater Interfaces,2016,8(3):1842-1853.
[41] Han U,Seo Y,Hong J.Effect of pH on the structure and drug release profiles of layer-by-layer assembled films containing polyelectrolyte,micelles,and graphene oxide[J].Rep,2016,6:24158.
[42] Deng Z J,Morton S W,Ben-akiva E,et al.Layer-by-layer nanoparticles for systemic codelivery of an anticancer drug and siRNA for potential triple-negative breast cancer treatment[J].ACS Nano,2013,7(11):9571-9584.
[43] Ronevi I K,Krivi D,Buljac M,et al.Polyelectrolytes assembly:a powerful tool for electrochemical sensing application[J].Sensors,2020,20(11):3211.
[44] Miyazaki C M,Pereira T P,Mas Ca Gni D,et al.Monoamine oxidase B layer-by-layer film fabrication and characterization toward dopamine detection[J].Materials Science & Engineering C,2016,58(1):310-315.
[45] Caselli M.Porphyrin-based electrostatically self-assembled multilayers as fluorescent probes for mercury(Ⅱ) ions:a study of the adsorption kinetics of metal ions on ultrathin films for sensing applications[J].RSC Advances,2015,5(2):1350-1358.
[46] Zhang X,Li Y,Zhang R,et al.Reversible visualization from exponentially growing polyelectrolyte assemblies with regionally confined dynamic structures[J].Chemical Engineering Journal,2021,425:131445.
[47] Li S,Wang D,Xiao H,et al.Ultra-low pressure cellulose-based nanofiltration membrane fabricated on layer-by-layer assembly for efficient sodium chloride removal[J].Carbohydrate Polymers,2020,255(1):117352.
[48] Suwaileh W,Johnson D,Khodabakhshi S,et al.Development of forward osmosis membranes modified by cross-linked layer by layer assembly for brackish water desalination[J].Journal of Membrane Science,2019,583:267-277.
[49] Heo J,Choi M,Chang J,et al.Highly permeable graphene oxide/polyelectrolytes hybrid thin films for enhanced CO2/N2 separation performance[J].Scientific Reports,2017,7(1):456.
基金资助
河南省科技攻关项目-面板用高端光刻胶研发及规模化制备(212102210211)
PDF
