油水混合物不仅对生态环境造成破坏,同时也危及人类身体健康。针对油水混合物进行高效分离,不仅可以实现油、水资源的重复使用,还可有效地避免其直接排放所造成的严重环境污染问题。因此开发高效油水分离材料对于资源节约,实现双碳目标和践行习近平总书记“绿水青山就是金山银山”理念具有重要意义。特殊润湿性因其对油水两相的响应不同在油水分离领域中显示出良好的应用前景,具备该特性的油水分离膜材料分离效率高、分离速度快、能耗低、可扩展性好、操作简单且可回收利用,因此针对油水分离膜材料制备过程中基底材料选择的不同,详细介绍了以金属、聚合物、生物质和无机物为基底材料制备油水分离膜材料及其应用研究进展,并对油水分离膜材料领域研究进行展望。
Oil-water mixtures are not only damaging to the ecological environment,but also posing risks to human health.The efficient separation of oil-water mixtures can not only enable the reuse of oil and water resources,but also effectively avoid the serious environmental pollution caused by their direct discharge.Therefore,the development of highly efficient oil-water separation materials is of great importance for the conservation of resources,the realisation of the double carbon goal and the implementation of general secretary Xi's concept of “green water and green mountains are the silver and gold mountains”.The special wettability shows good application prospects in the field of oil-water separation due to its different response to oil and water phases,and the oil-water separation membrane materials with this characteristic have high separation efficiency,fast separation speed,low energy consumption,good scalability,simple operation and can be recycled.In this paper,the preparation of oil-water separation membrane materials based on different substrate materials such as metals,polymers,biomass,and inorganic substances,as well as their research and application progress were presented in detail,and an outlook on the research directions in the field of oil-water separation membrane materials was given.
[1] 彭华乔,石涛,薛森,等.用于油水分离超疏水材料的研究进展[J].化工新型材料,2021,49(7):39-41,51.
[2] 李孝建,张海军,李赛赛,等.超亲水疏油材料的制备及其油水分离性能[J].化学进展,2020,32(6):851-860.
[3] Yan X H,Xiao X,Au C,et al.Electrospinning nanofibers and nanomembranes for oil/water separation[J].Journal of Materials Chemistry A,2021,9(38):21659-84.
[4] 龚自强.超疏水材料的制备及其油水分离性能研究[D].天津:天津大学,2020.
[5] 刘辉,陈天弟,苏思丝,等.磁性超疏水材料在油水分离中的应用进展[J].应用化工,2020,49(2):493-499.
[6] 姜晓峰,于维钊,王继乾.油水分离用天然材料表面化学研究进展[J].化学通报,2021,84(4):290-304,21.
[7] Yang D,Feng Y G,Wang B Q,et al.An asymmetric AC electric field of triboelectric nanogenerator for efficient water/oil emulsion separation[J].Nano Energy,2021,90:10664.
[8] Zhang S,Li W,Wang W,et al.Paper-based dual-mode liquid manipulation system:oil/water separation and time-lapse droplet switch[J].Chemical Engineering Journal,2022,427:131606.
[9] He N N,Li L L,Chen J Q,et al.Extraordinary superhydrophobic polycaprolactone-based composite membrane with an alternated micro-nano hierarchical structure as an eco-friendly oil/water separator[J].ACS Applied Materials & Interfaces,2021,13(20):24117-24129.
[10] Yin Z C,Pan Y P,Bao M T,et al.Superhydrophobic magnetic cotton fabricated under low carbonization temperature for effective oil/water separation[J].Separation and Purification Technology,2021,266:118535.
[11] Sun Y X,Liu Y,Xu B W,et al.Simultaneously achieving high-effective oil-water separation and filter media regeneration by facile and highly hydrophobic sand coating[J].Science of the Total Environment,2021,800:149488.
[12] 李桂水,王庆港,陈皓,等.用于油水分离过程中的膜材料及其制备与改性的综述[J].天津科技大学学报,2021,36(4):1-7.
[13] 叶泽权,吴青芸,顾林.纤维素基油水分离材料研究进展[J].化工进展,2022,41(6):3038-3050.
[14] Deng Y Y,Dai M,Wu Y N,et al.High-efficient novel super-wetting HKUST-1 membrane for oil-water separation:development,characterization and performance[J].Journal of Cleaner Production,2022,333:130109.
[15] Barthwal S,Lim S H.A durable,fluorine-free,and repairable superhydrophobic aluminum surface with hierarchical micro/nanostructures and its application for continuous oil-water separation[J].Journal of Membrane Science,2021,618:118716.
[16] 赵昕,任宝娜,胡苗苗,等.特殊浸润性纳米纤维膜材料在油水分离中的研究进展[J].材料工程,2021,49(10):43-54.
[17] 罗许颖,未碧贵.特殊润湿性表面的油水分离研究进展[J].应用化工,2021,50(3):765-768.
[18] 高党鸽,李鹏宇,苏莹,等.特殊润湿性油水分离材料的研究进展[J].精细化工,2021,38(9):1746-1756.
[19] Rasouli S,Rezaei N,Hamedi H,et al.Superhydrophobic and superoleophilic membranes for oil-water separation application:a comprehensive review[J].Materials & Design,2021,204:109599.
[20] Shi R,Tian Y,Wang L Q.Bioinspired fibers with controlled wettability:from spinning to application[J].ACS Nano,2021,15(5):7907-7030.
[21] Jafari Gukeh M,Moitra S,Ibrahim A N,et al.Machine learning prediction of TiO2-coating wettability tuned via UV exposure[J].ACS Applied Materials & Interfaces,2021,13(38):46171-46179.
[22] Xie X W,Li S H,Wang X Q,et al.An effective and low-consumption foam finishing strategy for robust functional fabrics with on-demand special wettability[J].Chemical Engineering Journal,2021,426:131245.
[23] Baig U,Faizan M,Dastageer M A.Polyimide based super-wettable membranes/materials for high performance oil/water mixture and emulsion separation:a review[J].Advances in Colloid and Interface Science,2021,297:102525.
[24] Yu J C,Cao C Q,Pan Y X.Advances of adsorption and filtration techniques in separating highly viscous crude oil/water mixtures[J].Advanced Materials Interfaces,2021,8(16):2100061.
[25] Long C,Qing Y Q,An K,et al.Functional fluorination agents for opposite extreme wettability coatings with robustness,water splash inhibition,and controllable oil transport[J].Chemical Engineering Journal,2021,415:128895.
[26] Gu J C,Ji L T,Xiao P,et al.Recent progress in superhydrophilic carbon-based composite membranes for oil/water emulsion separation[J].ACS Applied Materials & Interfaces,2021,13(31):36679-36696.
[27] Fei B L,Li L Y,Wang P P,et al.Multifunctional novel rosin derivatives based on dehydroabietylamine with metal ion sensing and DNA/BSA binding activities[J].Journal of Molecular Liquids,2022,347:118273.
[28] Zuo J H,Zhou Y,Chen Z H,et al.A superwetting stainless steel mesh with Janus surface charges for efficient emulsion separation[J].Journal of Hazardous Materials,2022,430:128378.
[29] Zhu M,Liu Y C,Chen M Y,et al.Metal mesh-based special wettability materials for oil-water separation:a review of the recent development[J].Journal of Petroleum Science and Engineering,2021,205:108889.
[30] Zhang J X,Zhu L N,Zhao S Y,et al.A robust and repairable copper-based superhydrophobic microfiltration membrane for high-efficiency water-in-oil emulsion separation[J].Separation and Purification Technology,2021,256:117751.
[31] Wang M K,Zhang Z Z,Wang Y L,et al.Ultrafast fabrication of metal-organic framework-functionalized superwetting membrane for multichannel oil/water separation and floating oil collection[J].ACS Applied Materials & Interfaces,2020,12(22):25512-25520.
[32] Zhang Y Z,Wang H H,Wang X M,et al.An anti-oil-fouling and robust superhydrophilic MnCo2O4 coated stainless steel mesh for ultrafast oil/water mixtures separation[J].Separation and Purification Technology,2021,264:118435.
[33] Jiang Y Z,Liu C Y,Li Y H,et al.Stainless-steel-net-supported superhydrophobic COF coating for oil/water separation[J].Journal of Membrane Science,2019,587:117177.
[34] Al-saadi S,Singh Raman R K.A long aliphatic chain functional silane for corrosion and microbial corrosion resistance of steel[J].Progress in Organic Coatings,2019,127:27-36.
[35] Zhou Y Y,Gu X L,Yuan Z Z,et al.PDMS mesh with reversible super-wettability for oil/water separation[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,641:128462.
[36] Deng Y F,Zhang D,Zhang N,et al.Electrospun stereocomplex polylactide porous fibers toward highly efficient oil/water separation[J].Journal of Hazardous Materials,2021,407:124787.
[37] Xu Y,Wang G,Zhu L J,et al.Desert beetle-like microstructures bridged by magnetic Fe3O4 grains for enhancing oil-in-water emulsion separation performance and solar-assisted recyclability of graphene oxide[J].Chemical Engineering Journal,2022,427:130904.
[38] Baig U,Faizan M,Waheed A.A review on super-wettable porous membranes and materials based on bio-polymeric chitosan for oil-water separation[J].Advances in Colloid and Interface Science,2022,303:102635.
[39] Cao M,Xiao F,Yang Z J,et al.Construction of polytetrafluoroethylene nanofiber membrane via continuous electrospinning/electrospraying strategy for oil-water separation and demulsification[J].Separation and Purification Technology,2022,287:120575.
[40] Li Y J,Yuan D,Geng Q,et al.MOF-embedded bifunctional composite nanofiber membranes with a tunable hierarchical structure for high-efficiency PM0.3 purification and oil/water separation[J].ACS Applied Materials & Interfaces,2021,13(33):39831-39843.
[41] Huang Y F,Gancheva T,Favis B D,et al.Hydrophobic porous polypropylene with hierarchical structures for ultrafast and highly selective oil/water separation[J].ACS Applied Materials & Interfaces,2021,13(14):16859-16868.
[42] Gao J K,Wang J Q,Xu Q Y,et al.Regenerated cellulose strongly adhered by a supramolecular adhesive onto the PVDF membrane for a highly efficient oil/water separation[J].Green Chemistry,2021,23(15):5633-5646.
[43] Amjith L R,Bavanish B.A review on biomass and wind as renewable energy for sustainable environment[J].Chemosphere,2022,293:133579.
[44] Bolivar Caballero J J,Zaini I N,Yang W H.Reforming processes for syngas production:a mini-review on the current status,challenges,and prospects for biomass conversion to fuels[J].Applications in Energy and Combustion Science,2022,10:100064.
[45] Zhang H L,Ou J F,Fang X Z,et al.Robust superhydrophobic fabric via UV-accelerated atmospheric deposition of polydopamine and silver nanoparticles for solar evaporation and water/oil separation[J].Chemical Engineering Journal,2022,429:132539.
[46] Kong W T,Li F,Pan Y L,et al.Hygro-responsive,photo-decomposed superoleophobic/superhydrophilic coating for on-demand oil-water separation[J].ACS Applied Materials & Interfaces,2021,13(29):35142-35152.
[47] Li F,Kong W T,Zhao X Z,et al.Multifunctional TiO2-based superoleophobic/superhydrophilic coating for oil-water separation and oil purification[J].ACS Applied Materials & Interfaces,2020,12(15):18074-18083.
[48] Xue J L,Li N N,Xiao X F,et al.Durable hydrophobic enteromorpha design for controlling oil spills in marine environment prepared by organosilane modification for efficient oil-water separation[J].Journal of Hazardous Materials,2022,421:126824.
[49] Lu H Y,Hanandeh A E.Quantitative systematic review of life cycle assessment studies of woody biomass as an energy feedstock[J].Comprehensive Renewable Energy,2022,5:405-425.
[50] Mottaghi M,Bairamzadeh S,Pishvaee M S.A taxonomic review and analysis on biomass supply chain design and planning:new trends,methodologies and applications[J].Industrial Crops and Products,2022,180:114747.
[51] Udayakumar K V,Gore P M,Kandasubramanian B.Foamed materials for oil-water separation[J].Chemical Engineering Journal Advances,2021,5:100076.
[52] Su Z P,Yang Y,Huang Q B,et al.Designed biomass materials for “green” electronics:a review of materials,fabrications,devices,and perspectives[J].Progress in Materials Science,2022,125:100917.
[53] Tezer Ö,Karabag N,Öngen A,et al.Biomass gasification for sustainable energy production:a review[J].International Journal of Hydrogen Energy,2022,2:158.
[54] Wang M,Tsai H S,Zhang C F,et al.Effective purification of oily wastewater using lignocellulosic biomass:a review[J].Chinese Chemical Letters,2021,11:060.
[55] Ejeta D D,Wang C F,Kuo S W,et al.Preparation of superhydrophobic and superoleophilic cotton-based material for extremely high flux water-in-oil emulsion separation[J].Chemical Engineering Journal,2020,402:126289.
[56] Huang L,Zhang L L,Song J L,et al.Superhydrophobic nickel-electroplated carbon fibers for versatile oil/water separation with excellent reusability and high environmental stability[J].ACS Applied Materials & Interfaces,2020,12(21):24390-24402.
[57] Zhang S,Huang X W,Wang D,et al.Flexible and superhydrophobic composites with dual polymer nanofiber and carbon nanofiber network for high-performance chemical vapor sensing and oil/water separation[J].A ACS Applied Materials & Interfaces,2020,12(41):47076-47089.
[58] Sun T C,Hao S,Fan R Q,et al.Hydrophobicity-adjustable MOF constructs superhydrophobic MOF-rGO aerogel for efficient oil-water separation[J].ACS Applied Materials & Interfaces,2020,12(50):56435-56444.
[59] Banerjee S,Chakraborty R,Das R,et al.Advances in oil-water separation[M].Netherlands:Elsevier,2022,489-510.
[60] Zhao Y,Gu Y N,Gao G D.Piezoelectricity induced by pulsed hydraulic pressure enables in situ membrane demulsification and oil/water separation[J].Water Research,2022,215:118245.
基金资助
湖南省自然科学基金项目(2022jj40864);广西林产化学与工程重点实验室开放课题资助项目(GXFK2201);湖南省教育厅优秀青年项目(21B0239);长沙市自然科学基金项目(kq2202277)