PPO/SEBS/SEBS-g-MAH共混物的阻燃性能研究

陶宇, 陆红霞, 邵为, 肖雨婷, 高炜斌*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 145 -148.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 145-148. DOI: 10.19817/j.cnki.issn1006-3536.2023.07.026
新材料与新技术

PPO/SEBS/SEBS-g-MAH共混物的阻燃性能研究

    陶宇, 陆红霞, 邵为, 肖雨婷, 高炜斌*
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Study on flame retardant properties of PPO/SEBS/SEBS-g-MAH blends

  • Tao Yu, Lu Hongxia, Shao Wei, Xiao Yuting, Gao Weibing
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摘要

以苯乙烯-乙烯/丁二烯-苯乙烯嵌段共聚物(SEBS)为弹性体改性剂,SEBS-g-MAH为相容剂,红磷和Mg(OH)2作为阻燃剂,采用双螺杆挤出技术,制备了阻燃聚苯醚(PPO)/SEBS/SEBS-g-MAH共混物。结果表明:当红磷用量为15份时,Mg(OH)2仅用80份,PPO/弹性体共混物的极限氧指数(LOI)就能达到28%,燃烧等级达UL94 V-0级,同时燃烧时的热释放速率(HRR)及生烟速率(SPR)均大幅降低。

Abstract

Flame retardant PPO/SEBS/SEBS-g-MAH blends were prepared by twin-screw extrusion with styrene ethylene/butadiene styrene block copolymer (SEBS) as elastomer,SEBS-g-MAH as compatibilizer,and red phosphorus and Mg(OH)2 as flame retardant.When the amount of red phosphorus was 15 phr and Mg(OH)2 was only 80 phr,the limiting oxygen index (LOI) of PPO/elastomer blend could reach 28% and the combustion grade could reach UL94V-0 level.At the same time,the heat release rate (HRR) and smoke generation rate (SPR) during combustion were greatly reduced.

关键词

聚苯醚 / 苯乙烯-乙烯/丁二烯-苯乙烯嵌段共聚物 / 复配 / 阻燃性能

Key words

PPO / SEBS / compound / flame retardant properties

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PPO/SEBS/SEBS-g-MAH共混物的阻燃性能研究[J]. 化工新型材料, 2023, 51(7): 145-148 DOI:10.19817/j.cnki.issn1006-3536.2023.07.026

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