超疏水低红外发射率涂层的制备及性能表征

吕丹丹, 赵曼婷, 张伟钢*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 100 -105.

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化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 100-105. DOI: 10.19817/j.cnki.issn1006-3536.2023.07.018
新材料与新技术

超疏水低红外发射率涂层的制备及性能表征

    吕丹丹, 赵曼婷, 张伟钢*
作者信息 +

Preparation and characterization of super-hydrophobic low infrared emissivity coating

  • Lyu Dandan, Zhao Manting, Zhang Weigang
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摘要

以纳米SiO2为微纳结构改性剂、含氢硅油(HQGY)共混改性聚氨酯(PU)为树脂基体、片状黄铜粉为功能颜料,采用玻璃棒刮涂法制备得到了一种具有超疏水特性的低红外发射率涂层。系统研究了HQGY和PU质量比、总填料(黄铜粉+纳米SiO2)添加量、黄铜粉和纳米SiO2质量比对涂层性能的影响规律。结果表明:HQGY和PU质量比可明显影响涂层的表面能和活性基团含量,从而影响涂层综合性能。总填料添加量的增加可明显增加涂层表面的乳突状微纳粗糙结构,从而使涂层发射率升高、光泽度降低、水接触角增大。黄铜粉和纳米SiO2质量比的降低,可使涂层中片状黄铜粉的绝对含量降低,纳米SiO2的绝对含量升高,进而使涂层发射率升高、光泽度降低、水接触角增大。当HQGY和PU的质量比为1∶9、总填料添加量为50%、黄铜粉和纳米SiO2的质量比为6.5∶3.5时,涂层同时具备最优的发射率(0.738)、光泽度(1.8)、附着力(1级)和超疏水(水接触角152°,滚动角8°)性能。

Abstract

A low infrared emissivity coating with super-hydrophobic properties was prepared by glass rod coating method using nano-SiO2 as the micro-nano structural modifier,hydrogen-containing silicone oil (HQGY) blending modified polyurethane (PU) as the resin matrix,and flake brass powder as the functional pigment,respectively.The influence of the mass ratio of HQGY to PU,the total filler (brass powder+nano SiO2) addition,and the mass ratio of brass powder to nano SiO2 on the coating properties was systematically studied.The results showed that the mass ratio of HQGY to PU could significantly affect the surface energy and active group content of the coating,thereby affecting the overall performance of the coating.The increase of the total filler addition could obviously increase the papillary micro-nano rough structure of the coating surface,thereby increasing the emissivity of the coating,reducing the glossiness,and increasing the water contact angle.The reduction of the mass ratio of brass powder to nano-SiO2 could reduce the absolute content of flake brass powder and increase the absolute content of nano-SiO2 in the coating,which in turn increased the emissivity of the coating,reduced the glossiness,and increased the water contact angle.When the mass ratio of HQGY to PU was 1∶9,the total filler content was 50%,and the mass ratio of brass powder to nano-SiO2 was 6.5∶3.5,the coating had the best emissivity (0.738),glossiness (1.8),adhesion strength (level 1),and super-hydrophobic performance (water contact angle 152°,rolling angle 8°) at the same time.

关键词

复合涂层 / 红外发射率 / 超疏水 / 附着力

Key words

composite coating / infrared emissivity / super-hydrophobic / adhesion strength

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引用格式 ▾
超疏水低红外发射率涂层的制备及性能表征[J]. 化工新型材料, 2023, 51(7): 100-105 DOI:10.19817/j.cnki.issn1006-3536.2023.07.018

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