角蛋白分子结构中有丰富的氨基酸,分布在氨基酸分子链表面的氨基、羧基、羟基等官能团可作为染料和重金属的吸附位点,此结构特点赋予了角蛋白去除有毒物质的条件,由于角蛋白自身成膜性较差,研究人员将其与其他助剂混合制备了海绵状、膜状、絮凝剂、水凝胶等其他角蛋白基复合材料在染料以及重金属吸附方面进行研究。综合阐述了角蛋白的结构以及对染料和重金属的吸附机理,总结归纳了当前研究人员通过对角蛋白进行改性制备出的角蛋白基复合材料,并在染料废水和重金属废水中的研究进展,为角蛋白基复合材料在水处理方面的研究提供借鉴和研究方向。
Keratin molecular structure is rich in amino acids,and amino,carboxyl,hydroxyl and other functional groups distributed on the surface of amino acid molecular chain can be used as adsorption site for dyes and heavy metals.This structural feature endows keratin with the ability to remove toxic substances.Due to the poor film-forming of keratin itself,researchers have mixed it with other additives to prepare sponge-like,film-like,flocculant,hydrogel and other keratin-based composites in dyes and heavy metal adsorption for research.The structure of keratin and the adsorption mechanism of dyes and heavy metals were comprehensively elaborated.The research progress of keratin-based composites prepared by modifying keratin,and their application in dye wastewater and heavy metal wastewater was summarized,which provided reference and research direction for the research of keratin-based composites in water treatment.
[1] Khot S N,LaScala J J,Can E,et al.Development and application of triglyceride-based polymers and composites[J].Journal of Applied Polymer Science,2001,82(3):703-723.
[2] 何明,窦瑶,陈智鹏,等.角蛋白膜材料的制备及改性研究进展[J].化工进展,2016,35(9):2839-2844.
[3] 刘让同,李小倩,刘静芳,等.黏胶纤维弹性恢复的角蛋白改性与实践机理[J].中原工学院学报,2020,31(4):5-10.
[4] Mckittrick J,Chen P Y,Bodde S G,et al.The structure,functions,and mechanical properties of keratin[J].JOM,2012,64(4):449-468.
[5] 刘让同,李亮,刘淑萍,等.硫化钠溶剂体系对羊毛角蛋白的溶解研究[J].毛纺科技,2017,45(7):41-44.
[6] 汤佳鹏,刘希文,葛彦.人发角蛋白复合纳米纤维膜的制备及其染料吸附性能[J].化工新型材料,2021,49(10):133-137.
[7] 郑顺姬,曹向禹,隋智慧.角蛋白膜的制备及应用研究进展[J].化工新型材料,2021,49(4):251-256.
[8] Zhe J,Yuan J,Ping W,et al.Dissolution and regeneration of wool keratin in the deep eutectic solvent of choline chloride-urea[J].International Journal of Biological Macromolecules,2018,119:423-430.
[9] 张祎鹏. 羊毛微/纳米角蛋白粒子的制备和应用[D].无锡:江南大学,2021.
[10] 李戎. 低共熔溶剂辅助羊毛角蛋白提取及其应用[D].上海:东华大学,2021.
[11] 米翔. 废弃角蛋白绿色改性及其再生纤维的开发[D].上海:东华大学,2020.
[12] 陆晨,袁久刚,王强,等.基于巯基-烯点击反应的PEG性角蛋白膜的制备及其性能研究[J].化工新型材料,2018,46(11):260-264.
[13] Cardamone J M.Investigating the microstructure of keratin extracted from wool:peptide sequence (MALDI-TOF/TOF) and protein conformation (FT-IR)[J].Journal of Molecular Structure,2010,969(1-3):97-105.
[14] Zhang Y,Tu H,Wu R,et al.Programing performance of silk Fibroin superstrong scaffolds by mesoscopic regulation among hierarchical structures[J].Biomacromolecules,2020,21(10):4169-4179.
[15] 孙丽莹,高文伟,李珊,等.角蛋白提取方法进展及提取技术应用选择建议[J].皮革科学与工程,2020,30(3):20-27.
[16] 郭清兵,莫瑞奕,何明,等.羽毛角蛋白的提取与应用研究进展[D].仲恺农业工程学院学报,2017,30(2):6.
[17] Ghosh A,Collie S R.Keratinous materials as novel absorbent systems for toxic pollutants[J].Defence Science Journal,2014,64(3):209-221.
[18] 郭菊花,李涛,赵婷婷,等.角蛋白改性材料及其应用研究进展[J].高分子通报,2014(4):16-23.
[19] Su C,Gong J S,Qin J,et al.Glutathione enables full utilization of wool wastes for keratin production and wastewater decolorization[J].Journal of Cleaner Production,2020,doi:10.1016/j.jclepro.2020.122092.
[20] 张慧敏,唐亚丽,卢立新,等.鸡毛角蛋白海绵垫的制备及对丙酮的吸附性能[J].材料科学与工艺,2017,25(4):38-43.
[21] 刘畅,高品,曹张军,等.羽毛角蛋白海绵材料对亚甲基蓝的吸附去除[J].环境工程学报,2014,8(10):4379-4385.
[22] Aluigi A,Rombaldoni F,Tonetti C,et al.Study of methylene blue adsorption on keratin nanofibrous membranes[J].Journal of Hazardous Materials,2014,268:156-165.
[23] Kavitha Kadirvelu,Nishter Nishad Fathima.Keratin functionalized electrospun PEI/PAN microfiltration system as a simple and sustainable approach for anionic dye removal[J].Journal of Environmental Chemical Engineering,2022,doi:10.1016/J.JECE.2022.107791.
[24] 钱迅南,朱笑吉,朱卫明,等.CNC/角蛋白复合膜的制备及其染料吸附性能[J].功能高分子学报,2020,33(2):200-206.
[25] Song Kaili,Xu Helan,Xu Lan,et al.Cellulose nanocrystal-reinforced keratin bioadsorbent for effective removal of dyes from aqueous solution[J].Production Technologies,2017,232:254-262.
[26] 陈碧,王雪燕,孟宪东.改性鸡毛角蛋白脱色剂K-D用于印染废水的脱色研究[J].印染助剂,2008,25(1):41-44.
[27] 徐绚绚,王雪燕.改性鸡毛角蛋白脱色剂对印染废水絮凝脱色性能的研究[J].印染助剂,2010,27(12):11-13.
[28] 葛乃维. 兔毛角蛋白膜的制备及其对重金属离子吸附的研究[D].天津:天津工业大学,2021.
[29] Hussain F S,Memon N,Khatri Z,et al.Solid waste-derived biodegradable keratin sponges for removal of chromium:a circular approach for waste management in leather industry[J].Environmental Technology & Innovation,2020,20(1-3):101120.
[30] Mahmoud M A.Separation of Cd(Ⅱ) from aqueous solution by keratin magnetic froth carbon in the batch and continuous system[J].Chemical Engineering Research and Design,2021,170(1):339-349.
[31] 庄媛,吴小倩,曹张军,等.羽毛不可溶角蛋白海绵膜对Cr(Ⅵ)的吸附性能[J].环境工程学报,2013,7(11):4264-4268.
[32] 李刘倩,王闻宇,金欣,等.角蛋白/聚乙烯醇复合膜对铜离子的吸附性能[J].化工新型材料,2018,46(8):198-201.
[33] Xin J,Hwb C,Xu J,et al.Preparation of keratin/PET nanofiber membrane and its high adsorption performance of Cr(Ⅵ)[J].Science of The Total Environment,2020,710:135546.
[34] 张明月. 羊毛角蛋白/丝胶/水性聚氨酯共混膜的制备及对重金属吸附研究[D].上海:东华大学,2020.
[35] 沈洪祥. 尼龙56/羊毛角蛋白共混纤维膜的制备[D].北京:北京服装学院,2021.
[36] Zahara I,Arshad M,Naeth M A,et al.Feather keratin derived sorbents for the treatment of wastewater produced during energy generation processes[J].Chemosphere,2020,273:128545.
[37] Mashreghi M,Peiravi Rivash O.Producing bacterial nano-cellulose and keratin from wastes to synthesize keratin/cellulose nanobiocomposite for removal of dyes and heavy metal ions from waters and wastewaters[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2023,656:130355.
[38] Tatiana N,Vladimir K,Mikhail I.Sorption of d-metal cations by keratin from aqueous solutions[J].Journal of Environmental Chemical Engineering,2019,7(5):103417.
[39] Cao H,Ma X,Wei Z,et al.Behavior and mechanism of the adsorption of lead by an eco-friendly porous double-network hydrogel derived from keratin[J].Chemosphere,2022,289:133086.
[40] 孙小娟,李宏伟,张梅.羊毛角蛋白/氧化石墨烯复合材料的制备及其吸附性能[J].毛纺科技,2021,49(1):21-26.
[41] Touaibia D,Benayada B.Removal of mercury(Ⅱ) from aqueous solution by adsorption on keratin powder prepared from Algerian sheep hooves[J].Desalination,2005,186(1-3):75.
[42] 孔娇娇. 角蛋白基吸附剂的制备,表征及吸附性能研究[D].济南:山东大学,2016.
[43] Donner M W,Arshad M,Ullah A,et al.Unravelled keratin-derived biopolymers as novel biosorbents for the simultaneous removal of multiple trace metals from industrial wastewater[J].Science of the Total Environment,2018,647:1539-1546.
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