为了减少白色污染带来的环境伤害,可生物降解的环境友好材料是目前的研究热点。淀粉具有来源广、价格低、可再生、生物相容性高和成膜性强等优势,在食品包装领域中展现出巨大的应用前景。传统淀粉基材料在机械性能方面的不足可以通过新型制备技术或复合其他材料来改善。综述了淀粉基可生物降解材料的制备方法、用于改善性能的添加剂和在食品包装中的应用进展。最后,对淀粉基可生物降解材料的未来发展方向进行了展望。
In order to reduce the environmental damage caused by white pollution,biodegradable and environmentally friendly materials are the current research focus.Starch has the advantages of wide source,low price,renewability,high biocompatibility and strong film-forming ability,and has shown great application prospects in the field of food packaging.Traditional starch-based materials are insufficient in terms of mechanical properties,which can be improved by novel preparation techniques or by compounding other materials.The preparation methods of starch-based biodegradable materials,the additives used for improving performance and application progress in food packaging were reviewed.Finally,the future development direction of starch-based biodegradable materials was prospected.
[1] Beikzadeh S,Khezerlou A,Jafari S M,et al.Seed mucilages as the functional ingredients for biodegradable films and edible coatings in the food industry[J].Advances in Colloid and Interface Science,2020,280:102164.
[2] Issa A T,Schimmel K A,Worku M,et al.Sweet potato starch-based nanocomposites:development,characterization,and biodegradability[J].Starch-Stärke,2018,70(7-8):1700273.
[3] Cheng H,Chen L,Mcclements D J,et al.Starch-based biodegradable packaging materials:a review of their preparation,characterization and diverse applications in the food industry[J].Trends in Food Science & Technology,2021,114:70-82.
[4] Aghazadeh M,Karim R,Abdul Rahman R,et al.Effect of glycerol on the physicochemical properties of cereal starch films[J].Czech Journal of Food Sciences,2018,36(5):403-409.
[5] Do Val Siqueira L,Arias C I L F,Maniglia B C,et al.Starch-based biodegradable plastics:methods of production,challenges and future perspectives[J].Current Opinion in Food Science,2021,38:122-130.
[6] Gao W,Wu W,Liu P,et al.Preparation and evaluation of hydrophobic biodegradable films made from corn/octenylsuccinated starch incorporated with different concentrations of soybean oil[J].International Journal of Biological Macromolecules,2020,142:376-383.
[7] Liu P,Wang R,Kang X,et al.Effects of ultrasonic treatment on amylose-lipid complex formation and properties of sweet potato starch-based films[J].Ultrasonics Sonochemistry,2018,44:215-222.
[8] Zhang C,Chen F,Meng W,et al.Polyurethane prepolymer-modified high-content starch-pbat films[J].Carbohydrate Polymers,2021,253:117168.
[9] 陈雪华,徐欣东,王清,等.木薯淀粉基膜材料的研究进展[J].食品科学,2021,42(9):254-263.
[10] Chen W,Ma S,Wang Q,et al.Fortification of edible films with bioactive agents:a review of their formation,properties,and application in food preservation[J].Critical Reviews in Food Science and Nutrition,2021,20:1-27.
[11] Domene-Lopez D,Garcia-Quesada J C,Martin-Gullon I,et al.Influence of starch composition and molecular weight on physicochemical properties of biodegradable films[J].Polymers (Basel),2019,11(7):103390.
[12] 毛文英,杜俊民,刘婷.蒙脱土改性聚乳酸/热塑性淀粉环保食品包装材料的研究[J].化工新型材料,2021,49(8):178-181.
[13] Ortega-Toro R,Lopez-Cordoba A,Avalos-Belmontes F.Epoxidised sesame oil as a biobased coupling agent and plasticiser in polylactic acid/thermoplastic yam starch blends[J].Heliyon,2021,7(2):e06176.
[14] Fonseca-Florido H A,Soriano-Corral F,Yanez-Macias R,et al.Effects of multiphase transitions and reactive extrusion on in situ thermoplasticization/succination of cassava starch[J].Carbohydrate Polymers,2019,225:115250.
[15] Herniou-Julien C,Mendieta J R,Gutiérrez T J.Characterization of biodegradable/non-compostable films made from cellulose acetate/corn starch blends processed under reactive extrusion conditions[J].Food Hydrocolloids,2019,89:67-79.
[16] Fishman M L,Coffin D R,Onwulata C I,et al.Two stage extrusion of plasticized pectin/poly(vinyl alcohol) blends[J].Carbohydrate Polymers,2006,65(4):421-429.
[17] Kouhi M,Prabhakaran M P,Ramakrishna S.Edible polymers:an insight into its application in food,biomedicine and cosmetics[J].Trends in Food Science & Technology,2020,103:248-263.
[18] 袁文波,张群华,刘媛,等.静电纺丝制备生物基食品活性包装纤维膜及其应用[J].包装工程,2021,42(5):13-22.
[19] Wang W,Jin X,Zhu Y,et al.Effect of vapor-phase glutaraldehyde crosslinking on electrospun starch fibers[J].Carbohydrate Polymers,2016,140:356-361.
[20] Fonseca L M,Cruxen C,Bruni G P,et al.Development of antimicrobial and antioxidant electrospun soluble potato starch nanofibers loaded with carvacrol[J].International Journal of Biological Macromolecules,2019,139:1182-1190.
[21] Liu G,Gu Z,Hong Y,et al.Electrospun starch nanofibers:recent advances,challenges,and strategies for potential pharmaceutical applications[J].Journal of Controlled Release,2017,252:95-107.
[22] Derossi A,Caporizzi R,Azzollini D,et al.Application of 3d printing for customized food.A case on the development of a fruit-based snack for children[J].Journal of Food Engineering,2018,220:65-75.
[23] 黄丽婕,王晓彤,周雷,等.3d打印在包装工业中的应用与前景[J].工程塑料应用,2016,44(4):122-126.
[24] Zheng L,Yu Y,Tong Z,et al.The characteristics of starch gels molded by 3d printing[J].Journal of Food Processing and Preservation,2019,43(7):13993.
[25] Yang Z,Chen X,Xu Z,et al.Anti-freezing starch hydrogels with superior mechanical properties and water retention ability for 3D printing[J].International Journal of Biological Macromolecules,2021,190:382-389.
[26] Chen Y,Zhang M,Sun Y,et al.Improving 3d/4d printing characteristics of natural food gels by novel additives:a review[J].Food Hydrocolloids,2022,123:107160.
[27] Maniglia B C,Lima D C,Matta Junior M D,et al.Hydrogels based on ozonated cassava starch:effect of ozone processing and gelatinization conditions on enhancing 3d-printing applications[J].International Journal of Biological Macromolecules,2019,138:1087-1097.
[28] Nordin N,Othman S H,Rashid S A,et al.Effects of glycerol and thymol on physical,mechanical,and thermal properties of corn starch films[J].Food Hydrocolloids,2020,106:105884.
[29] Leaw Z E,Kong I,Pui L P.3d printed corn starch-gelatin film with glycerol and hawthorn berry (crataegus pinnatifida) extract[J].Journal of Food Processing and Preservation,2021,45(9):15752.
[30] Boonsuk P,Sukolrat A,Kaewtatip K,et al.Modified cassava starch/poly(vinyl alcohol) blend films plasticized by glycerol:structure and properties[J].Journal of Applied Polymer Science,2020,137(26):48848.
[31] Saberi B,Vuong Q V,Chockchaisawasdee S,et al.Mechanical and physical properties of pea starch edible films in the presence of glycerol[J].Journal of Food Processing and Preservation,2016,40(6):1339-1351.
[32] Arrieta M P,Fortunati E,Dominici F,et al.Bionanocomposite films based on plasticized pla-phb/cellulose nanocrystal blends[J].Carbohydr Polym,2015,121:265-275.
[33] 董峰. 纳米纤维素负载金属纳米粒子复合材料的研究进展[J].化工新型材料,2022,50(1):12-14,19.
[34] Noshirvani N,Hong W,Ghanbarzadeh B,et al.Study of cellulose nanocrystal doped starch-polyvinyl alcohol bionanocomposite films[J].International Journal of Biological Macromolecules,2018,107(Pt B):2065-2074.
[35] Babaee M,Jonoobi M,Hamzeh Y,et al.Biodegradability and mechanical properties of reinforced starch nanocomposites using cellulose nanofibers[J].Carbohydrate Polymers,2015,132:1-8.
[36] Ciannamea E M,Castillo L A,Barbosa S E,et al.Barrier properties and mechanical strength of bio-renewable,heat-sealable films based on gelatin,glycerol and soybean oil for sustainable food packaging[J].Reactive and Functional Polymers,2018,125:29-36.
[37] Acosta S,Jiménez A,Cháfer M,et al.Physical properties and stability of starch-gelatin based films as affected by the addition of esters of fatty acids[J].Food Hydrocolloids,2015,49:135-143.
[38] Fakhouri F M,Martelli S M,Caon T,et al.Edible films and coatings based on starch/gelatin:film properties and effect of coatings on quality of refrigerated red crimson grapes[J].Postharvest Biology and Technology,2015,109:57-64.
[39] 徐幸,童群义.基于明胶硬胶囊性能评价的明胶—普鲁兰复合膜研究[J].食品与机械,2019,35(5):137-143.
[40] Luo Q,Hossen M A,Zeng Y,et al.Gelatin-based composite films and their application in food packaging:a review[J].Journal of Food Engineering,2022,313:110762.
[41] Ren L,Yan X,Zhou J,et al.Influence of chitosan concentration on mechanical and barrier properties of corn starch/chitosan films[J].International Journal of Biological Macromolecules,2017,105(3):1636-1643.
[42] Bonilla J,Atarés L,Vargas M,et al.Properties of wheat starch film-forming dispersions and films as affected by chitosan addition[J].Journal of Food Engineering,2013,114(3):303-312.
[43] Divsalar E,Tajik H,Moradi M,et al.Characterization of cellulosic paper coated with chitosan-zinc oxide nanocomposite containing nisin and its application in packaging of uf cheese[J].International Journal of Biological Macromolecules,2018,109:1311-1318.
[44] Tyagi P,Salem K S,Hubbe M A,et al.Advances in barrier coatings and film technologies for achieving sustainable packaging of food products-a review[J].Trends in Food Science & Technology,2021,115:461-485.
[45] Mina Hernandez J H.Effect of the incorporation of polycaprolactone (pcl) on the retrogradation of binary blends with cassava thermoplastic starch (tps)[J].Polymers (Basel),2020,13(1):103390.
[46] Bandehali S,Sanaeepur H,Ebadi Amooghin A,et al.Biodegradable polymers for membrane separation[J].Separation and Purification Technology,2021,269:118731.
[47] Kumar R,Ghoshal G,Goyal M.Effect of basil leaves extract on modified moth bean starch active film for eggplant surface coating[J].LWT,2021,145:111380.
[48] Zhou X,Yang R,Wang B,et al.Development and characterization of bilayer films based on pea starch/polylactic acid and use in the cherry tomatoes packaging[J].Carbohydrate Polymers,2019,222:114912.
[49] Chen M,Yan X,Cheng M,et al.Preparation,characterization and application of poly(lactic acid)/corn starch/eucalyptus leaf essential oil microencapsulated active bilayer degradable film[J].International Journal of Biological Macromolecules,2022,195:264-273.
[50] Moreno O,Atarés L,Chiralt A,et al.Starch-gelatin antimicrobial packaging materials to extend the shelf life of chicken breast fillets[J].Lwt,2018,97:483-490.
[51] Li S,Jiang Y,Zhou Y,et al.Facile fabrication of sandwich-like anthocyanin/chitosan/lemongrass essential oil films via 3d printing for intelligent evaluation of pork freshness[J].Food Chemistry,2022,370:131082.
[52] Baek S K,Kim S,Song K B.Cowpea starch films containing maqui berry extract and their application in salmon packaging[J].Food Packaging and Shelf Life,2019,22:100394.
[53] Zhang K,Huang T S,Yan H,et al.Novel ph-sensitive films based on starch/polyvinyl alcohol and food anthocyanins as a visual indicator of shrimp deterioration[J].International Journal of Biological Macromolecules,2020,145:768-776.
[54] Rammak T,Boonsuk P,Kaewtatip K.Mechanical and barrier properties of starch blend films enhanced with kaolin for application in food packaging[J].International Journal of Biological Macromolecules,2021,192:1013-1020.
[55] Engel J B,Ambrosi A,Tessaro I C.Development of biodegradable starch-based foams incorporated with grape stalks for food packaging[J].Carbohydrate Polymers,2019,225:115234.
[56] Yang S Y,Cao L,Kim H,et al.Utilization of foxtail millet starch film incorporated with clove leaf oil for the packaging of queso blanco cheese as a model food[J].Starch-Stärke,2018,70(3-4):1700171.
[57] Mustafa P,Niazi M B K,Jahan Z,et al.Pva/starch/propolis/anthocyanins rosemary extract composite films as active and intelligent food packaging materials[J].Journal of Food Safety,2019,40(1):12725.
[58] Cui C,Ji N,Wang Y,et al.Bioactive and intelligent starch-based films:a review[J].Trends in Food Science & Technology,2021,116:854-869.
[59] Talón E,Vargas M,Chiralt A,et al.Antioxidant starch-based films with encapsulated eugenol.Application to sunflower oil preservation[J].LWT,2019,113:108290.
[60] Vargas C G,Costa T M H,Rios A d O,et al.Comparative study on the properties of films based on red rice (oryza glaberrima) flour and starch[J].Food Hydrocolloids,2017,65:96-106.
[61] 张晓晓,黄丽婕,陈杰,等.淀粉基食品包装膜材料的研究进展[J].包装工程,2018,39(3):83-88.