溶胶-凝胶法制备锂离子电池正极材料研究进展

曾金波, 孙世平, 任秀峰*, 海春喜, 孙艳霞, 申月, 李翔

化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 1 -7.

PDF
化工新型材料 ›› 2023, Vol. 51 ›› Issue (7) : 1-7. DOI: 10.19817/j.cnki.issn1006-3536.2023.07.001
综述与专论

溶胶-凝胶法制备锂离子电池正极材料研究进展

    曾金波, 孙世平, 任秀峰*, 海春喜, 孙艳霞, 申月, 李翔
作者信息 +

Research progress on preparation of cathode materials for lithium-ion batteries by sol-gel method

  • Zeng Jinbo, Sun Shiping, Ren Xiufeng, Hai Chunxi, Sun Yanxia, Shen Yue, Li Xiang
Author information +
文章历史 +
PDF

摘要

随着社会的迅速发展,能源短缺和环境恶化两大问题严重制约了全球社会文明发展以及经济发展。锂离子电池具有能量密度高、自放电率小、无记忆效应、循环性能好等诸多优点,广泛应用于各种电子设备、新能源汽车、储能系统等领域。锂离子电池的正极材料直接决定了电池的性能,研究正极材料的制备方法至关重要。综述了溶胶-凝胶法制备锂离子电池正极材料的研究进展以及溶胶-凝胶法改性正极材料的制备,并对溶胶-凝胶法制备锂离子电池正极材料未来的研究方向进行展望。

Abstract

With the rapid development of society,the two major problems of energy shortage and environmental degradation have seriously restricted the development of global social civilization and economic development.Lithium-ion batteries have many advantages such as high energy density,low self-discharge rate,no memory effect,and good cycle performance,and have been widely used in various electronic devices,new energy vehicles,energy storage systems and other fields.The cathode material of lithium-ion battery directly determines the performance of the battery,and it is very important to study the preparation method of cathode material.This paper reviewed the research progress on the preparation of cathode materials for lithium-ion batteries by sol-gel method,as well as the modification method based on the preparation of sol-gel method.Finally,the future direction of preparation of cathode materials for lithium batteries by sol-gel method was discussed.

关键词

溶胶-凝胶法 / 锂离子电池 / 正极材料 / 制备方法 / 改性研究

Key words

sol-gel method / lithium-ion battery / cathode material / preparation method / modification research

引用本文

引用格式 ▾
溶胶-凝胶法制备锂离子电池正极材料研究进展[J]. 化工新型材料, 2023, 51(7): 1-7 DOI:10.19817/j.cnki.issn1006-3536.2023.07.001

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 方锐,李子坤,周豪杰,等.锂离子电池镍钴铝酸锂正极材料研究进展[J].化工新型材料,2021,49(8):5.
[2] 涂康安. 锂离子电池三元正极材料现状及发展趋势[J].当代化工研究,2021(17):2.
[3] Kim J K,Vijaya,Zhu L,et al.Improving electrochemical pro-perties of porous iron substituted lithium manganese phosphate in additive addition electrolyte[J].Journal of Power Sources,2015,275:106-110.
[4] 董鹏,夏书标,张英杰,等.络合剂对溶胶-凝胶法制备Li Ni(0.80)Co(0.15)Al(0.05)O2正极材料电化学性能影响[J].硅酸盐学报,2016,44(10):1415-1420.
[5] Zhao T,Zhang X J,Li X,et al.Crystallinity dependence of electro-chemical properties for LiFePO4[J].Rare Metals,2015,34(5):334-337.
[6] 何冀川,王红,周天明,等.固相法合成LiNi0.8Co0.15Al0.05O2正极材料及其电化学性能研究[J].化工新型材料,2018,46(3):160-163;167.
[7] 史晋宜,肖春宝.共沉淀法制备锂离子电池的阴极材料LiNi(1/3)Co(1/3)Mn(1/3)O(2)及其性能研究[J].化学工程与装备,2020(12):2.
[8] 王丹凤,李益孝,王伟立,等.锂离子电池高镍正极材料掺铝的作用及掺铝方法的研究[J].电化学,2019(6):9.
[9] Wang J,Chen Li,Xu Bo.Basic principle,advance and current application situation of sol-gel method[J].Chemical Industry and Engineering,2009,26(30):273-277.
[10] Lu H,Zhou H,Svensson A M,et al.High capacity Li(Ni0.8Mn0.1Co0.1)O2 synthesized by sol-gel and co-precipitation methods as cathode materials for lithium-ion batteries[J].Solid State Ionics,2013,11:105-111.
[11] Han C J,Yoon J H,Cho W I,et al.Electrochemical properties of Li Ni0.8Co0.2-xAlxO2 prepared by a sol-gel method[J].Journal of Power Sources,2004,136(1):132-138.
[12] Xiao W,Nie Y,Miao C,et al.Structural design of high-performance Ni-rich LiNi0.83Co0.11Mn0.06O2 cathode materials enhanced by Mg2+ doping and Li3PO4 coating for lithium ion battery[J].Journal of Colloid and Interface Science,2022,607:1071-1082.
[13] Zhu J,Xiao G,Li X.Synthesis of Li(Ni0.6Co0.2Mn0.2)O2 by a modified sol-gel method for lithium-ion batteries[J].Synthetic Metals,2021,281:116905.
[14] Li T,Li D,Zhang Q,et al.Preparation and electrochemical performance of macroporous Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode material[J].Acta Chimica Sinica Chinese Edition,2021,79(5):678.
[15] Guo R,Kong J,Xu P,et al.Manganese-based oxide layer with oxygen vacancies to enable fast ion/charge mobility for durable LiNi0.8Co0.1Mn0.1O2 cathode[J].Ionics,2021,27(12):5009-5019.
[16] Hwang B J,Wu Y W,Venkateswarlu M,et al.Influence of synthesis conditions on electrochemical properties of high-voltage Li1.02Ni0.5Mn1.5O4 spinel cathode material[J].Journal of Power Sources,2009,193(2):828-833.
[17] Cui X,Tuo K,Dong H,et al.Modification of phosphorus-doped carbon coating enhances the electrochemical perfor-mance of LiFe0.8Mn0.2PO4 cathode material[J].Journal of Alloys and Compounds,2021,885:160946.
[18] 严丹林,曾瑛英.锂离子电池正极材料LiVO3的溶胶-凝胶法制备[J].广东化工,2019,46(14):15-16.
[19] 周小荣,李东林,张巍,等.锂离子电池正极材料LiVOPO4的制备及其长循环稳定性[J].功能材料,2020,51(5):5143-5147;5174.
[20] Perumal P,Abhilash K P,Selvin P C,et al.A short investigation on LiMn2O4 wrapped with MWCNT as composite cathode for lithium-ion batteries[J].Bulletin of Materials Science,2021,44(4):243.
[21] 许寒,刘慕霄,卢志威.锂离子电池磷酸钴锂正极材料制备及改性研究[J].电源技术,2021,45(5):566-568.
[22] Tuo K,Mao L,Ding H,et al.Boron and phosphorus dual-doped carbon coating improves electrochemical performances of LiFe0.8Mn0.2PO4 cathode materials[J].ACS Applied Energy Materials,2021,4(8):8003-8015.
[23] Ji X,Dai X,Wu F,et al.In situ Sr2+-doped spinel LiNi0.5Mn1.5O4 cathode material for Li-ion batteries with high electrochemical performance and its impact on morphology[J].Ceramics International,2021,47(22):32043-32052.
[24] Chen F,Ma X,Zhu X,et al.Investigation of Li3PO4 coating and Nb5+ doping effect on the crystal structure and electrochemical properties of Ni-rich LiNi0.85Co0.05Mn0.10O2 cathode[J].Journal of the Electrochemical Society,2021,168(9):90540.
[25] Mao Jing,Dai Kehua,Xuan Minjie,et al.Effect of chromium and niobium doping on morphology and electrochemical performance of high-voltage spinel Li Mn1.5Ni0.5O4 cathode material[J].ACS Applied Materials & interfaces,2016,8(14):9116-9124.
[26] Lin F,Wu H,Chen T,et al.The Cu-Y co-doping LiNi0.5Mn1.5O4 with modified morphology and enhanced electrochemical property for a 5 V lithium-ion battery[J].Journal of Materials Science:Materials in Electronics,2022,33(1):283-297.
[27] Laisa C P,Kumar A K,Chandrasekaran S S,et al.A comparative study on electrochemical cycling stability of lithium rich layered cathode materials Li1.2Ni0.13M0.13Mn0.54O2 where M=Fe or Co[J].Journal of Power Sources,2016,324:462-474.
[28] Kong J Z,Zhai H F,Ren C,et al.Synthesis and electrochemical performance of macroporous LiNi0.5Co0.2Mn0.3O2 by a modified sol-gel method[J].Journal of Alloys and Compounds,2013,577:507-510.
[29] Bhuvaneswari D,Gangulibabu,Kalaiselvi N.Surfactant-coassisted sol-gel synthesis to prepare LiNiyMnyCo1-2yO2 with improved electrochemical behavior[J].Journal of Solid State Electrochemistry,2012,16(11):3667-3674.
[30] Zhang Y,Wu X,Lin Y,et al.Synthesis of Li Ni1/3Co1/3Mn1/3O2 cathode material by a modifiedsol-gel method for lithium-ion battery[J].Journal of Sol-Gel Science and Technology,2013,68(2):169-174.
[31] Jin X,Xu Q J,Yuan X L,et al.Synthesis,characterization and electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode materials for lithium-ion batteries[J].Electrochim Acta,2013,114:605-610.
[32] Li X,Li Y,Yang Y.Enhanced electrochemical performances of Li2Ni0.03Mn0.985O3 cathode materials by polyvinyl alcohol allocating[J].Ionics,2022,28(2):533-541.
[33] Lee S W,Kim H,Kim M S,et al.Improved electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode material synthesized by citric acid assisted sol-gel method for lithium ion batteries[J].Journal of Power Sources,2016,315:261-268.
[34] Zhang X,Liu W,Zhao C,et al.Synthesis of Li1.05MxMn2-xO4(M=Co3+ and Cr3+,x=0.1 or 0.2) and their application as cathode materials for lithium-ion batteries[J].International Journal of Electrochemical Science,2021,16(6):21069.
[35] Xie Z,Zhang Y,Min X,et al.One-step bulk and surface co-modification of LiNi0.8Co0.15Al0.05O2 cathode material towards excellent long-term cyclability[J].Electrochimica Acta,2021,379:138124.
[36] Zhao T L,Chen S,Li L,et al.Organic-acid-assisted fabrication of low-cost Li-rich cathode material (Li[Li1/6Fe1/6Ni1/6Mn1/2]O2) for lithium-ion battery[J].ACS Appl Mater Interfaces,2014,6(24):22305-22315.
[37] Chen C,Wu H,Zhou D F,et al.Sol-gel synthesis of nano Li1.2Mn0.54Ni0.13Co0.13O2 cathode materials using DL-lactic acid as chelating agent-science direct[J].Ceramics International,2020,47(5):6270-6278.
[38] Lobo L S,Kumar A R.Synthesis,structural and electrical properties of spinel LiNi0.5Mn1.5O4 synthesized by sol-gel method[J].Journal of Sol-Gel Science and Technology,2016,80(3):821-826.
[39] Umair Nisar,Sara Ahmad J A Al-Hail,Petla R K,et al.Fast and scalable synthesis of LiNi0.5Mn1.5O4 cathode by sol-gel assisted microwave sintering[J].Energy Technology,2021,9(7):1-9.
[40] Santhanam R,Rambabu B.High rat cycling performance of Li1.05Ni1/3Co1/3Mn1/3O2 materials prepared by sol-gel and co-precipitation methods for lithium-ion batteries[J].Journal of Power Sources,2010,195(13):4313-4317.
[41] Luo Wenbin,Zheng Baolin.Improved electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode material by double-layer coating with graphene oxide and V2O5 for lithium-ion batteries[J].Applied Surface Science,2017,404:310-317.
[42] Cho W,Kim S M,Lee K W,et al.Investigation of new manganese orthophosphate Mn3(PO4)2 coating for nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode and improvement of its thermal properties[J].Electrochimica Acta,2016,198:77-83.
[43] Dong X,Yao J,Zhu W,et al.Enhanced high-voltage cycling stability of Ni-rich cathode materials via the self-assembly of Mn-rich shells[J].Journal of Materials Chemistry A,2019,7(35):20262-20273.
AI Summary AI Mindmap
PDF

673

访问

0

被引

导航
相关文章

AI思维导图

/