纳米纤维素是一种新型的生物高分子功能材料,具有高强度、大比表面积、高透明性等优良性能,已成为目前纳米材料领域研究的热点。综述了纳米纤维素的分类、制备和纳米纤维素在药物载体、特种纸张、透光材料和食品包装中的应用,并对纳米纤维素的应用前景进行了展望。
Cellulose nanocrystals is a new biomolecular functional material with high strength,large specific surface area,high transparency and other excellent properties,which has become the focus of research in the field of nanomaterials.The classification,preparation and applications of cellulose nanocrystals in drug carrier,special paper,translucent material and food packaging were reviewed,and the application prospect of cellulose nanocrystals was discussed.
[1] Chen Q J,Zhou L L,Zou J Q,et al.The preparation and characterization of nanocomposite film reinforced by modified cellulose nanocrystals[J].International Journal of Biological Macromolecules,2019,132:1115-1162.
[2] Geueke B,Groh K,Muncke J.Food packaging in the circular economy:overview of chemical safety aspects for commonly used materials[J].Journal of Cleaner Production,2018,193:491-505.
[3] Hussein Y,Loutfy S A,Kamoun E,et al.Enhanced anti-cancer activity by localized delivery of curcumin form PVA/CNCs hydrogel membranes:preparation and in vitro bioevaluation[J].International Journal of Biological Macromolecules,2021,170:107-122.
[4] 何孝清.纳米纤维素的制备及其在造纸领域的应用[J].中国造纸,2019,38(10):68-74.
[5] 明思逸,陈港,严俊芳,等.纳米纤维素分散的高稳定性单片层黏土分散液的制备及其在透明柔性薄膜的应用[J].复合材料学报,2018,35(9):2573-2578.
[6] De Oliveira J P,Bruni G P,Halal S L M,et al.Cellulose nanocrystals from rice and oat husks and their application in aerogels for food packaging[J].International Journal of Biological Macromolecules,2019,124:175-184.
[7] Julie C C S,Neena G,Sunil K N.Isolation and characterization of cellulose nanofibrils from arecanut husk fibre[J].Carbohydrate Polymers,2016,142:158-166.
[8] 杨陈,林燕萍,李永贵.纳米纤维素材料研究进展[J].化工新型材料,2020,48(10):232-235.
[9] 朱亚崇,吴朝军,于冬梅,等.纳米纤维素制备方法的研究现状[J].中国造纸,2020,39(9):74-83.
[10] 许凯瑞,宫庆华,周国伟.纳米纤维素的分类制备及其在电化学应用中的研究进展[J].高分子通报,2020(10):12-20.
[11] 冉琳琳,谢帆钰,王封丹,等.纳米纤维素的制备及应用研究进展[J].广州化工,2021,49(6):1-5,10.
[12] 张思航,付润芳,董立琴,等.纳米纤维素的制备及其复合材料的应用研究进展[J].中国造纸,2017,36(1):67-74.
[13] Chen L H,Wang Q Q,Hirth K,et al.Tailoring the yield and characteristics of wood cellulose nanocrystals (CNC) using concentrated acid hydrolysis[J].Cellulose,2015,22(3):1753-1762.
[14] Kuramae R,Saito T,Isogai A.TEMPO-oxidized cellulose nanofibrils prepared from various plant holocelluloses[J].Reactive and Functional Polymers,2014,85:126-133.
[15] Sun B,Zhang M,Hou Q X,et al.Further characterization of cellulose nanocrystal (CNC) preparation from sulfuric acid hydrolysis of cotton fibers[J].Cellulose,2016,23(1):439-450.
[16] 马海珠,周天文,薛国新,等.超低浓度酸水解制备纤维素纳米纤丝的初步研究[J].中国造纸,2020,39(1):17-25.
[17] Neves R M,Lopes K S,Zimmermann M G V,et al.Cellulose nanowhiskers extracted from tempo-oxidized curaua fibers[J].Journal of Natural Fibers,2020,17(9):1355-1365.
[18] Azrina Z A Z,Beg M D H,Rosli M Y,et al.Spherical nanocrystalline cellulose (NCC) from oil palm empty fruit bunch pulp via ultrasound assisted hydrolysis[J].Carbohydrate Polymers,2017,162:115-120.
[19] Yang T T,Guo Y J,Gao N,et al.Modification of a cellulase system by engineering Penicilliumoxalicum to produce cellulose nanocrystal[J].Carbohydrate Polymers,2020,234(5):115862.
[20] 金浩.酶解-研磨二步法制备竹浆纳米纤维素工艺优化[J].森林与环境学报,2021,41(1):104-111.
[21] 祁明辉,易锬,莫琪,等.硫酸水解辅助高压均质法制备小麦秸秆纳米纤维素[J].中国造纸学报,2020,35(3):1-8.
[22] 张欢,戴宏杰,陈媛,等.离子液体-球磨法制备柠檬籽纤维素纳米纤丝及其结构表征[J].食品科学,2021,42(7):120-127.
[23] 沈慧颖,吕子豪,庄粟裕,等.表面沉积铜纳米颗粒的细菌纤维素/壳聚糖交联复合膜的制备及其抗菌性能研究[J].化工新型材料,2021,49(3):168-172.
[24] 金克霞,江泽慧,马建锋,等.纤维素纳米晶基导电复合材料的应用进展[J].材料导报,2020,34(S2):1521-1524.
[25] Tang L R,Hong B Y,Li T,et al.Development of bilayer films based on shellac and esterified cellulose nanocrystals for buccal drug delivery[J].Springer Netherlands,2019,26(2):1157-1167.
[26] Anirudhan T S,Nima J,Divya P L.Synthesis,characterization and in vitro cytotoxicity analysis of a novel cellulose based drug carrier for the controlled delivery of 5-fluorouracil,an anticancer drug[J].Applied Surface Science,2015,355:64-73.
[27] Long W,Ouyang H,Zhou C Q,et al.Simultaneous surface functionalization and drug loading:a novel method for fabrication of cellulose nanocrystals-based pH responsive drug delivery system[J].International Journal of Biological Macromolecules,2021,182(5):2066-2075.
[28] 张凯丽,陈广学.高透明纳米导电纸的制备及纸基电容器的构建[J].影像科学与光化学,2020,38(5):790-794.
[29] Cha R T,Wang C Y,Cheng S L,et al.Using carboxylatednanocrystalline cellulose as an additive in cellulosic paper and poly (vinyl alcohol) fiber paper[J].Carbohydrate Polymers,2014,110:298-301.
[30] 陈嘉艾,丁玮.细菌纳米纤维素的制备及其在造纸中的应用[J].黑龙江造纸,2019,47(3):19-22+25.
[31] Chi K,Jeffrey M.Improved eco-friendly barrier materials based on crystalline nanocellulose/chitosan/carboxymethyl cellulose polyelectrolyte complexes[J].Food Hydrocolloids,2018,80(5):195-205.
[32] 蔡琪.纤维素纳米粒子增强光学透明复合材料的研究[D].哈尔滨:东北林业大学,2014.
[33] Lin M Q,Raghuwanshi V S,Browne C,et al.Modulating transparency and colour of cellulose nanocrystal composite films by varying polymer molecular weight[J].Journal of Colloid and Interface Science,2021,584:216-224.
[34] Zheng S Y,Liu S Y,Xiao B,et al.Integrate nanoscale assembly and plasmonic resonance to enhance photoluminescence of cellulose nanocrystals for optical information hiding and reading[J].Carbohydrate Polymers,2021,253(5):117260.
[35] Jin K,Tang Y,Zhu X,et al.Polylactic acid based biocomposite films reinforced with silanizednanocrystalline cellulose[J].International Journal of Biological Macromolecules,2020,162:1109-1117.
[36] Mu R J,Hong X,Ni Y S,et al.Recent trends and applications of cellulose nanocrystals in food industry[J].Trends in Food Science & Technology,2019,93:136-144.
[37] Sandra R L,Klara N,Jon T,et al.Faba bean protein films reinforced with cellulose nanocrystals as edible food packaging material[J].Food Hydrocolloids,2021,121:107019.
基金资助
贵州省科学技术基金重点项目——黔科合基础(20171414);贵州省科技计划项目:黔科合支撑(20201Y143);湖南省教育厅优秀青年项目(19B015);湖南省重点研发项目(2020SK2100);湖南省教育厅优秀青年项目(19B015)
PDF
