玉米秸秆颗粒对环氧树脂/咪唑体系性能的影响

周永丽1, 娄春华2,3*, 闫安1, 刘扬2, 赵云鹏2

化工新型材料 ›› 2022, Vol. 50 ›› Issue (12) : 204 -208.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (12) : 204-208. DOI: 10.19817/j.cnki.issn1006-3536.2022.12.039
科学研究

玉米秸秆颗粒对环氧树脂/咪唑体系性能的影响

    周永丽1, 娄春华2,3*, 闫安1, 刘扬2, 赵云鹏2
作者信息 +

Effect of corn straw particles on properties of epoxy resin/imidazole system

  • Zhou Yongli1, Lou Chunhua2,3, Yan An1, Liu Yang2, Zhao Yunpeng2
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摘要

以双酚A型环氧树脂(E-51)为基体,硅烷偶联剂γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)表面处理的玉米秸秆颗粒(KHCS)为改性剂,2-甲基咪唑(2-MI)为固化剂,制备了环氧树脂复合材料。通过傅里叶红外光谱仪、扫描电子显微镜、差示扫描量热仪对环氧树脂复合材料进行表征分析,结果表明,与未经表面处理的玉米秸秆颗粒(CS)相比,经KH560表面处理的玉米秸秆颗粒与环氧树脂(E-51)的界面作用力增强,两相之间相容性提高,且表面处理后的秸秆颗粒可以明显提高环氧树脂的韧性。

Abstract

Using bisphenol A epoxy resin (E-51) as the matrix,silane coupling agent γ-(2,3-epoxypropoxy) propyltrimethoxysilane (KH560) surface-treated corn straw particles (KHCS) as modifier,and 2-methylimidazole (2-MI) as curing agent,epoxy resin composites were prepared.With the help of Fourier Transform Infrared (FT-IR),Scanning Electron Microscope (SEM),and Differential Scanning Calorimeter (DSC),the properties of epoxy resin composites were characterized and analyzed.The results showed that,compared with corn straw particles without surface treatment,the interface force between corn straw particles and E51 treated with KH560 was enhanced,and the compatibility between the two phases was improved;furthermore,the toughness of epoxy resin was obviously improved by surface treated straw particles.

关键词

玉米秸秆 / 环氧树脂 / 硅烷偶联剂 / 表面处理

Key words

corn stalk / epoxy resin / silane coupling agent / surface treatment

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玉米秸秆颗粒对环氧树脂/咪唑体系性能的影响[J]. 化工新型材料, 2022, 50(12): 204-208 DOI:10.19817/j.cnki.issn1006-3536.2022.12.039

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参考文献

[1] Ayman M,Atta H A,Al-Lohedan A M,et al.Salt-controlled self-healing nanogel composite embedded with epoxy as environmentally friendly organic coating[J].Journal ofCoatings Technology and Research,2017,14(5):1225-1236.
[2] Reza A H,Roghani M M,Gholipour M.Grafting poly (amidoamine) dendrimer-modified silica nanoparticles to grapheneoxide for preparation of a composite and curing agent for epoxy resin[J].Polymer,2017,126,152-161.
[3] Huang Z P,Zhao W J,Zhao W C,et al.Tribological and anti-corrosion performance of epoxy resin composite coatings reinforced with differently sized cubic boron nitride (CBN) particles[J].Friction,2021,9(1):104-118.
[4] 徐晓娟,卢立新,王立军,等.农作物秸秆废弃物材料化利用现状及进展[J].包装工程,2017,38(1):156-162.
[5] 孙娇.我国农作物秸秆综合利用分析[J].农业牧区机械化,2015,(1):19-21.
[6] 李连辉.秸秆收获粉碎压捆机的研制及推广应用前景[J].现代农村科技,2019,(11):99.
[7] 聂孙建.麦秸秆纤维改性及其对复合材料性能的影响[D].西安:西安理工大学,2019.
[8] 董研.功能性环氧树脂固化剂评述[J].热固性树脂,1997,12(2):55-57.
[9] Wang N,Cheng K Q,Wu H,et al.Effect of nano-sized mesoporous silica MCM-41 and MMT on corrosion properties of epoxy coating[J].Prog Org Coat,2012,75(4):386-391.
[10] Ahmer H S,Xiao L,Xiao D X.Evaluation of mechanical and thermal properties of modifified epoxy resin by using acacia catechu particles[J].Mater Chem Phys,2019,225,239-246.
[11] González M G,Cabanelas J C,Baselga J.Applications of FT-IR on epoxy resins-identification,monitoring the curing process,phase separation and water uptake[J].Infrared Spectroscopy Materials Science,Engineering and Technology,2011,6(13):261-284.
[12] Li L,Wu Q L,Li S J,et al.Study of the infrared spectral features of an epoxy curing mechanism[J].Applied Spectroscopy,2008,62(10):1129-1136.
[13] 龙宇飞,王鹏,李瑞,等.硅烷偶联剂改性空心玻璃微珠/环氧树脂固体浮力材料的制备及性能研究[J].全面腐蚀控制,2016,30(10):17-22.
[14] 申艳平,李俊仪,陈忠红,等.KH560表面改性纳米BaTiO3/环氧树脂压电复合材料[J].有机硅材料,2018,32(3):172-177.
[15] Farkas A,Strohm F.Imidazole catalysis in the curing of epoxy resins[J].Appl Polym Sci,1968,12(1):159-168.
[16] Domínguez J C,Grivel J C,Madsen B.Study on the nonisothermal curing kinetics of a polyfuryl alcohol bioresin by DSC using different amounts of catalyst[J].Thermochim Acta,2012,529,29-35.
[17] Barton J M.The application of differential scanning calorimetry(DSC) to the study of epoxy resin curing reactions[J].Adv Polyrm Sci,1985,72,111-154.
[18] 张进.CMC/环氧树脂固化动力学及工艺优化研究[D].哈尔滨:哈尔滨工程大学,2013.

基金资助

黑龙江省省属高等学校基本科研业务费科研项目(135309437、YSTSXK201861);黑龙江省自然科学基金面上项目(E2018058)

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