钠离子电池(SIB)是新兴的低成本储能技术,因其在大规模储能领域中具有较好的应用前景而受到科研工作者的广泛关注。硫化亚锡(SnS)因具有理论容量高、成本相对低、环境友好等优点,而被认为是SIB负极的潜在选择。然而,SnS负极材料的导电率较差,而且在充放电过程中伴随着巨大的体积膨胀,容易造成电极材料的结构坍塌。基于SnS材料目前存在的问题,主要从结构调控、与碳材料复合和构建异质结构这3个方面对相关研究工作进行了总结,以期为SnS负极材料的发展提供有益的认识。
Sodium-ion battery is currently an emerging battery in the field of low-cost energy storage,and has attracted enormous attention to research due to its promising potentiality for large-scale energy storage applications.As the key electrode materials for Na-ion batteries,tin monosulfide-based materials have been regarded as the potential choice for practical application due to their high sodium storage activity,low cost,and environmental friendliness.However,the tin monosulfide-based anode materials cannot meet the rate performance demand because of their low electrical conductivity and a huge volume expansion during the electrochemical cycling process,resulting in the crushing of the electrode and hindering the application of SnS materials.Herein,the recent progress of SnS anode materials was summarized,including structure modulation,composite with carbon material,and construction of SnS-based heterojunctions.,which was expected to provide references for the research of SnS anode materials for sodium storage.
[1] Kang W P,Wang Y Y,Xu J.Recent progress of layered metal dichalcogenide nanostructures as electrodes for high-performance sodium-ion batteries[J].Journal of Materials Chemistry A,2017,5:7667-7690.
[2] Zhang S G,Yue L C,Zhao H Q,et al.MWCNTs wrapped flower-like SnS composite as anode material for sodium-ion battery[J].Materials Letters,2017,209:212-215.
[3] Geng P,Zheng S,Tang H,et al.Transition metal sulfides based on graphene for electrochemical energy storage[J].Advanced Energy Materials,2018,8:1703259.
[4] Gao S N,Yang L T,Liu Z C,et al.Carbon-coated SnS nanosheets supported on porous microspheres as negative electrode material for sodiumIon batteries[J].Energy Technology,2020,8:2000258.
[5] Chen T,Liu Y,Pan L,et al.Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance[J].Journal of Materials Chemistry A,2014,2:4117-4121.
[6] Zhang B,Ghimbeu C M,Laberty C,et al.Correlation between microstructure and Na storage behavior in hard carbon[J].Advanced Energy Materials,2016,6:1501588.
[7] Xia J,Liu L,Jamil S,et al.Free-standing SnS/C nanofiber anodes for ultralong cycle-life lithium-ion batteries and sodium-ion batteries[J].Energy Storage Materials,2019,17:1-11.
[8] Kaur S,Sundarrajan S,Rana D,et al.Influence of electrospun fiber size on the separation[J].Journal of Membrane Science,2012,392:101-111.
[9] Yan H X,Yang M,Liu L,et al.Synthesis of SnS/C nanofibers membrane as self-standing anode for high-performance sodium-ion batteries by a smart process[J].Journal of Alloys and Compounds,2020,843:155899.
[10] Dresselhaus M S,Dresselhaus G,Eklund P C,et al.Science of fullerenes and carbon nanotubes:their properties and applications[M].San Diego,CA:Academic Press,1996,965.
[11] Baughman R H,Zakhidov A A,De Heer W A,et al.Carbon nanotubes-the route toward applications[J].Science,2002,297:787-792.
[12] Ruoff R S,Qian D,Liu W K.Mechanical properties of carbon nanotubes:theoretical predictions and experimental measurements[J].Comptes Rendus Physique,2003,4:993-1008.
[13] Qian D,Wagner G J,Liu W K,et al.Mechanics of carbon nanotubes[J].Applied Mechanics,2002,55:495-533.
[14] Balogun M S,Luo Y,Qiu W,et al.A review of carbon materials and their composites with alloy metals for sodiumIon battery anodes[J].Carbon,2016,98:162-178.
[15] Ren Y,Wang J,Huang X,et al.Three-dimensional SnS2 flowers/carbon nanotubes network:extraordinary rate capacity for sodium-ion battery[J].Materials Letters,2017,186:57-61.
[16] 翟传鑫.锡基纳米材料的制备及作为锂离子电池负极材料的应用[D].杭州:浙江大学,2012.
[17] Tian Z,Guo C,Zhao M,et al.Two-dimensional SnS:a phosphorene analogue with strong in-plane electronic anisotropy[J].ACS Nano,2017,11:2219-2226.
[18] Shi J,Wang Y,Su Q,et al.N-S co-doped C@SnS nanoflakes/graphene composite as advanced anode for sodium-ion batteries[J].Chemical Engineering Journal,2018,353:606-614.
[19] Chao D L,Ouyang B,Liang P,et al.C-plasma of hierarchical graphene survives SnS bundles for ultrastable and high volumetric Na-ion storage[J].Advanced Materials,2018,30:1804833.
[20] Zhang S P,Wang G,Zhang Z L,et al.3D graphene networks encapsulated with ultrathin SnS nanosheets@hollow mesoporous carbon spheres nanocomposite with pseudocapacitance-enhanced lithium and sodium storage kinetics[J].Small,2019,15:1900565.
[21] N J,Ma C L.The in-situ synthesis of a 3D SnS/N-doped graphene composite with enhanced electrochemical performance as a low-cost anode material in sodium ion batteries[J].Materials,2019,12:1996-1944.
[22] Ross J S,Rivera P,Schaibley J,et al.Interlayer exciton optoelectronics in a 2D heterostructure p-n junction[J].Nano Letters,2017,17:638-643.
[23] Lu J,Zhao S,Fan S,et al.Hierarchical SnS/SnS2 heterostructures grown on carbon cloth as binder-free anode for superior sodium-ion storage[J].Carbon,2019,148:525-531.
[24] Zhang S W,Lv W,Qiu D,et al.An ion-conducting SnS-SnS2 hybrid coating for commercial activated carbons enabling their use as high performance anodes for sodium-ion batteries[J].Journal of Materials Chemistry A,2019,7:10761-10768.
[25] Su X H,Su D,Sang Z Y,et al.Shielded SnS2/SnS heterostructures on three-dimensional graphene framework for high-rate and stable sodium-ion storage[J].Electrochimica Acta,2021,372:0013-4686.
[26] Hu M,Zhang H,Yang L,et al.Ultrahigh rate sodium-ion storage of SnS/SnS2 heterostructures anchored on S-doped reduced graphene oxide by ion-assisted growth[J].Carbon,2019,143:21-29.
[27] Ru J J,He T,Chen B J,et al.Covalent assembly of MoS2 nanosheets with SnS nanodots as linkages for lithium/sodium-Ion batteries[J].Angewandte Chemie International Edition,2020,59:14621-14627.
[28] Yan D,Yu C Y,Zhang X J,et al.Enhanced electrochemical performances of anatase TiO2 nanotubes by synergetic doping of Ni and N for sodium-ion batteries[J].Electrochimica Acta,2017,254:130-139.
[29] Zhang W F,Luo N J,Huang S P,et al.Sulfur-doped anatase TiO2 as an anode for high-performance sodium-ion batteries[J].ACS Applied Energy Materials,2019,2:3791-3797.
[30] Zhang Y,Su H,Wang C P.Heterostructured SnS/TiO2@C hollow nanospheres for superior lithium and sodium storage[J].Nanoscale,2019,11:12846-12852.
基金资助
中央高校基本科研业务费专项资金(2572022BU03);黑龙江省科学基金项目(ZD2021C001)
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