石墨烯/聚苯胺复合材料具有新颖的结构,并拥有优良的导电、防腐、机械等性能,一直是材料领域研究的热点。主要介绍了石墨烯/聚苯胺复合材料的发展现状、主要制备方法,以及该复合材料在超级电容器、传感器、防腐以及燃料电池等方面的应用,并对石墨烯/聚苯胺复合材料的不足以及发展前景进行了展望。
Graphene/polyaniline composites with novel structure have been a hot spot in the field of composite materials due to their excellent electro-conductibility,anti-corrosion,mechanical and other properties.This paper mainly introduced the development of graphene/polyaniline composites,the preparation methods and the applications of graphene/polyaniline composites in super capacitors,sensors,anti-corrosion and fuel cells,etc.Finally,the shortcomings and development of graphene/polyaniline composites were discussed.
[1] Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] Chen W,Jiang S,Xiao H,et al.Graphene modified polyaniline-hydrogel based stretchable supercapacitor with high capacitance and excellent stretching stability[J].ChemSusChem,2021,14(3):938-945.
[3] Zhang L,Huang D,Hu N,et al.Three-dimensional structures of graphene/polyaniline hybrid films constructed by steamed water for high-performance supercapacitors[J].Journal of Power Sources,2017,34:1-8.
[4] Mao H N,Wang X G.Use of in-situ polymerization in the preparation of graphene/polymer nanocomposites[J].New Carbon Materials,2020,35(4):336-343.
[5] Kumar N A,Choi H J,Shin Y R,et al.Polyaniline-grafted reduced graphene oxide for efficient electrochemical supercapacitors[J].ACS Nano,2012,6(2):1715-1723.
[6] Zhao Z,Liu Z,Zhong Q,et al.In situ synthesis of trifluoroacetic acid-doped polyaniline/reduced graphene oxide composites for high-performance all-solid-state supercapacitors[J].ACS Applied Energy Materials,2020,3(9):8774-8785.
[7] Jiang Y,Ji J,Huang L,et al.One-pot mechanochemical exfoliation of graphite andin situpolymerization of aniline for the production of graphene/polyaniline composites for high-performance supercapacitors[J].RSC Advances,2020,10(73):44688-44698.
[8] Borenstein A,Hanna O,Attias R,et al.Carbon-based composite materials for supercapacitor electrodes:a review[J].Journal of Materials Chemistry A,2017,5(25):12653-12672.
[9] Du Y,Wang X,Li B,et al.AQDS-guided growth of nanocilia-like polyaniline on graphene nanofiber as cathode material for high-performance asymmetric supercapacitors[J].Synthetic Metals,2021,272:116660.
[10] Ji J,Li R,Li H,et al.Phytic acid assisted fabrication of graphene/polyaniline composite hydrogels for high-capacitance supercapacitors[J].Composites Part B:Engineering,2018,155:132-137.
[11] Xuan C,Li X,Wang Z,et al.Highly efficient polyaniline trapping and covalent grafting within a three-dimensional porous graphene oxide/helical carbon nanotube skeleton for high-performance flexible supercapacitors[J].ACS Applied Energy Materials,2020,4(1):523-534.
[12] Kazemi F,Naghib S M,Zare Y,et al.Biosensing applications of polyaniline (PANI)-based nanocomposites:a review[J].Polymer Reviews,2020,61(3):553-597.
[13] George D,James G,Manjally J K,et al.Graphene/PANI electrode material characterization for supercapacitor application[J].Materials Today:Proceedings,2020,24:1734-1741.
[14] Shahid M U,Mohamed N M,Muhsan A S,et al.Few-layer graphene supported polyaniline (PANI) film as a transparent counter electrode for dye-sensitized solar cells[J].Diamond and Related Materials,2019,94:242-251.
[15] Hong X,Fu J,Liu Y,et al.Recent progress on graphene/polyaniline composites for high-performance supercapacitors[J].Materials (Basel),2019,12(9):1451.
[16] Li K,Liu J,Huang Y,et al.Integration of ultrathin graphene/polyaniline composite nanosheets with a robust 3D graphene framework for highly flexible all-solid-state supercapacitors with superior energy density and exceptional cycling stability[J].Journal of Materials Chemistry A,2017,5(11):5466-5474.
[17] Kim H C,Kim Y,Bando Y,et al.Shape-controlled Pd nanocrystal-polyaniline heteronanostructures with modulated polyaniline thickness for efficient electrochemical ethanol oxidation[J].Journal of Materials Chemistry A,2019,7(38):22029-22035.
[18] Puthiyedath Narayanan A,Narayanan Unni K N,Peethambharan Surendran K.Aerogels of V2O5 nanowires reinforced by polyaniline for electromagnetic interference shielding[J].Chemical Engineering Journal,2021,408:127239.
[19] Im S,Park Y R,Park S,et al.Nanoparticle intercalation-induced interlayer-gap-opened graphene-polyaniline nanocomposite for enhanced supercapacitive performances[J].Applied Surface Science,2017,412:160-169.
[20] Martinaiou I,Monteverde Videla A H A,Weidler N,et al.Activity and degradation study of an Fe-N-C catalyst for ORR in direct methanol fuel cell (DMFC)[J].Applied Catalysis B:Environmental,2020,262:118217.
[21] Mangisetti S R,Kamaraj M,Ramaprabhu S.N-doped 3D porous carbon-graphene/polyaniline hybrid and N-doped porous carbon coated g-C3N4 nanosheets for excellent energy density asymmetric supercapacitors[J].Electrochimica Acta,2019,305:264-277.
[22] Yang C,Zhang L,Hu N,et al.Rational design of sandwiched polyaniline nanotube/layered graphene/polyaniline nanotube papers for high-volumetric supercapacitors[J].Chemical Engineering Journal,2017,309:89-97.
[23] Zhang J M,Zhang Y,Yuan J,et al.High rate capability electrode from a ternary composite of nanodiamonds/reduced graphene oxide@PANI for electrochemical capacitors[J].Chemical Physics,2019,526:110461.
[24] Huang Z,Li L,Wang Y,et al.Polyaniline/graphene nanocomposites towards high-performance supercapacitors:a review[J].Composites Communications,2018,8:83-91.
[25] Wang X,Wu D,Song X,et al.Review on carbon/polyaniline hybrids:design and synthesis for supercapacitor[J].Molecules,2019,24(12):2263.
[26] Kumari P,Khawas K,Nandy S,et al.A supramolecular approach to polyaniline graphene nanohybrid with three dimensional pillar structures for high performing electrochemical supercapacitor applications[J].Electrochimica Acta,2016,190:596-604.
[27] Çıplak Z,Yıldız A,Yıldız N.Green preparation of ternary reduced graphene oxide-au@polyaniline nanocomposite for supercapacitor application[J].Journal of Energy Storage,2020,32:101846.
[28] Wang Z,Jiang L,Wei Y,et al.In-situ polymerization to prepare reduced graphene oxide/polyaniline composites for high performance supercapacitors[J].Journal of Energy Storage,2020,32:101742.
[29] Zheng X,Yu H,Xing R,et al.Multi-growth site graphene/polyaniline composites with highly enhanced specific capacitance and rate capability for supercapacitor application[J].Electrochimica Acta,2018,260:504-513.
[30] Yu H,Ge X,Bulin C,et al.Facile fabrication and energy storage analysis of graphene/PANI paper electrodes for supercapacitor application[J].Electrochimica Acta,2017,253:239-247.
[31] Maddu A,Nugroho R A,Rustami E,et al.Synthesis of graphene/polyaniline nanocomposite for supercapacitor electrodes[J].Journal of Physics:Conference Series,2019,1171:012043.
[32] Yang F,Xu M,Bao S J,et al.Self-assembled hierarchical graphene/polyaniline hybrid aerogels for electrochemical capacitive energy storage[J].Electrochimica Acta,2014,137:381-387.
[33] Zou Y,Zhang Z,Zhong W,et al.Hydrothermal direct synthesis of polyaniline,graphene/polyaniline and N-doped graphene/polyaniline hydrogels for high performance flexible supercapacitors[J].Journal of Materials Chemistry A,2018,6(19):9245-9256.
[34] Moyseowicz A,Gryglewicz G.Hydrothermal-assisted synthesis of a porous polyaniline/reduced graphene oxide composite as a high-performance electrode material for supercapacitors[J].Composites Part B:Engineering,2019,159:4-12.
[35] Wang H,Yu Z,El-kady M F,et al.Graphene/oligoaniline based supercapacitors:towards conducting polymer materials with high rate charge storage[J].Energy Storage Materials,2019,19:137-147.
[36] Mensing J P,Wisitsoraat A,Phokharatkul D,et al.Novel surfactant-stabilized graphene-polyaniline composite nanofiber for supercapacitor applications[J].Composites Part B:Engineering,2015,77:93-99.
[37] Souza V H R,Oliveira M M,Zarbin A J G.Bottom-up synthesis of graphene/polyaniline nanocomposites for flexible and transparent energy storage devices[J].Journal of Power Sources,2017,348:87-93.
[38] Li J,Xiao D,Ren Y,et al.Bridging of adjacent graphene/polyaniline layers with polyaniline nanofibers for supercapacitor electrode materials[J].Electrochimica Acta,2019,300:193-201.
[39] Hong X,Zhang B,Murphy E,et al.Three-dimensional reduced graphene oxide/polyaniline nanocomposite film prepared by diffusion driven layer-by-layer assembly for high-performance supercapacitors[J].Journal of Power Sources,2017,343:60-66.
[40] Li S,Gao A,Yi F,et al.Preparation of carbon dots decorated graphene/polyaniline composites by supramolecular in-situ self-assembly for high-performance supercapacitors[J].Electrochimica Acta,2019,297:1094-1103.
[41] Guo R,Jiang Y,Jia Q,et al.Improved electrocatalytic performance from graphene quantum dots/three-dimensional graphene/polyaniline doped powder to layer-by-layer self-assembled membrane materials[J].Materials Today Communications,2020,25:101426.
[42] Luo J,Ma Q,Gu H,et al.Three-dimensional graphene-polyaniline hybrid hollow spheres by layer-by-layer assembly for application in supercapacitor[J].Electrochimica Acta,2015,173:184-192.
[43] Wang H,Hao Q,Yang X,et al.Graphene oxide doped polyaniline for supercapacitors[J].Electrochemistry Communications,2009,11(6):1158-1161.
[44] Li T,Wang X,Liu P,et al.Synthesis of graphene/polyaniline copolymer for solid-state supercapacitor[J].Journal of Electroanalytical Chemistry,2020,860:113908.
[45] Yu J,Xie F,Wu Z,et al.Flexible metallic fabric supercapacitor based on graphene/polyaniline composites[J].Electrochimica Acta,2018,259:968-974.
[46] Liu Y,Ma Y,Guang S,et al.Polyaniline-graphene composites with a three-dimensional array-based nanostructure for high-performance supercapacitors[J].Carbon,2015,83:79-89.
[47] Tanguy N R,Arjmand M,Yan N.Nanocomposite of nitrogen-doped graphene/polyaniline for enhanced ammonia gas detection[J].Advanced Materials Interfaces,2019,6(16):1900552.
[48] Tanguy N R,Wiltshire B,Arjmand M,et al.Highly sensitive and contactless ammonia detection based on nanocomposites of phosphate-functionalized reduced graphene oxide/polyaniline immobilized on microstrip resonators[J].ACS Applied Materials & Interfaces,2020,12(8):9746-9754.
[49] Hashemi Karouei S F,Milani Moghaddam H,Saadat Niavol S.Characterization and gas sensing properties of graphene/polyaniline nanocomposite with long-term stability under high humidity[J].Journal of Materials Science,2020,56(6):4239-4253.
[50] 郭晓蒙,青芳竹,李雪松.石墨烯在金属表面防腐中的应用[J].物理学报,2021,70(9):7-19.
[51] 杨小刚,王传洁,李斌.石墨烯/聚苯胺纳米复合材料的制备及防腐应用研究进展[J].微纳电子技术,2020,57(4):282-291.
[52] Yang S,Zhu S,Hong R.Graphene oxide/polyaniline nanocomposites used in anticorrosive coatings for environmental protection[J].Coatings,2020,10(12):1215.
[53] Kim S,Le T H,Park C S,et al.A solution-processable,nanostructured,and conductive graphene/polyaniline hybrid coating for metal-corrosion protection and monitoring[J].Scientific Reports,2017,7(1):15184.
[54] Arukula R,Vinothkannan M,Kim A R,et al.Cumulative effect of bimetallic alloy,conductive polymer and graphene toward electrooxidation of methanol:an efficient anode catalyst for direct methanol fuel cells[J].Journal of Alloys and Compounds,2019,771:477-488.
[55] Wang Y,Li Z,Xu S,et al.Highly dispersive platinum nanoparticles supporting on polyaniline modified three dimensional graphene and catalyzing methanol oxidation[J].Materials Research Bulletin,2018,102:172-179.
[56] Oskueyan G,Mansour Lakouraj M.Electrodeposition of nanostructured Pt-Pd bimetallic catalyst on polyaniline-camphorsulfonic acid/graphene nanocomposites for methanol electrooxidation[J].Journal of Applied Electrochemistry,2019,49(8):755-765.
[57] He B,Tang Q,Wang M,et al.Robust polyaniline-graphene complex counter electrodes for efficient dye-sensitized solar cells[J].ACS Applied Materials & Interfaces,2014,6(11):8230-8236.
[58] Zhou Y,Zhang W,Pan Z,et al.Graphene-doped polyaniline nanocomposites as electromagnetic wave absorbing materials[J].Journal of Materials Science:Materials in Electronics,2017,28(15):10921-10928.
基金资助
安徽省自然科学基金项目(1808085ME157)